• The Korean Journal of Pesticide Science
• /
• v.4 no.3
• /
• pp.1-6
• /
• 2000

In order to elucidate the degradation of the herbicide dicamba, the degradabilities of dicamba under sunlight and in soils were investigated. The photodegradation rate of the authentic dicamba under sunlight condition was only 3.3% after 9 weeks. 4-Hydroxy dicamba turned out to be the major product, and 5-hydroxy dicamba was also identified. Dicamba was degraded to 3,6-dichlorosalicylic acid by demethylation in the viable soil, which resulted in 14.7 to 23.2% degradation of the applied amount during 8 weeks of incubation. Meanwhile, the degradation was quite slow in the sterilize soil, which revealed that the soil microbes played a major role in dicamba degradation.

• Journal of Korean Society of Environmental Engineers
• /
• v.29 no.8
• /
• pp.938-943
• /
• 2007

Anaerobic degradation of petroleum hydrocarbons in a soil artificially contaminated with 10,000 mg/kg soil of diesel fuel was tested by adding an anaerobic sludge taken from a sludge digestion tank. Treatments of soil(50 g) with 15 mL/kg soil and 30 mL/kg soil of the digestion sludge(2,000 mg/L of vss(volatile suspended solids)) showed 37.2% and 58.0% of total petroleum hydrocarbons(TPH) removal during 90 days incubation, respectively. In evaluation of several anaerobic conditions including nitrate reducing, sulfate reducing, methanogenic, and mixed electron accepters condition, treatments with the digested sludge showed significant degradation of diesel fuel under all anaerobic conditions compare to a control treatment of soil without the sludge and a treatment of autoclaved soil treatment with autoclaved digestion sludge. The rate of diesel fuel degradation was the highest in the treatment with the sludge and mixed electron accepters (75% removal of TPH) for 120 days incubation followed in order by sulfate reducing, nitrate reducing, methanogenic condition as 67%, 53%, 43%, respectively. However, the removal rate of non-biodegradable isoprenoid was the highest in the sulfate reducing condition. These results suggest that anaerobic degradation of diesel fuel in soil with digested sludge is effective for practical remediation of soil contaminated with petroleum hydrocarbons.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2001.04a
• /
• pp.136-139
• /
• 2001

In this study, we have examined potential degradation of MTBE (methy1 tert-butyl ether) by pure culture ENV425 and mixed culture isolated from gasoline contaminated soil using n-butane as the sources of carbon and energy. The results described in this study suggest that MTBE is degraded cometabolically by ENV425 and mixed culture grown n-butane, and the disappearance of TBA after complete degradation of MTBE suggest the further degradation of TBA. Butane and MTBE degradation was completely inhibited by acetylene, which indicated that both substrates were degraded by butane-utilizing bacteria. MTBE was degraded ENV425 and mixed culture grown n-butane, and TBA (tert-butyl alcohol) was produced as product of MTBE oxidation. TBA production was accounted 54.7% and 58.6% for MTBE oxidation by ENV425 and mixed culture, respectively. The observed maximal transformation yield (T$_{y}$) were 44.7 and 34.0 (nmol MTRE degraded/$\mu$mol n-butane Utilized) by ENV425 and mixed culture, respectively.y.

• Korean Journal of Weed Science
• /
• v.17 no.2
• /
• pp.214-219
• /
• 1997

The influence of manure, chemical fertilizers, heavy metals and cleaner on the rate of degradation of alachlor in soil was studied. The degradation rate of alachlor in the soil followed first-order reaction kinetics. The half-life was 6.4 days. The degradation was accelerated by the amendment of manure. Adding chemical fertilizers to the soil enhanced alachlor degradation more in the presence of nitrogen than potassium. On the other hand, adding heavy metals or cleaner to the soil decreased the degradation rate. The half-life of alachlor in soil treated with Cd, Cr, Ni, Zn and Cu was 11.0, 8.3, 7.9, 7.2 and 6.7 days, respectively, and that of the cleaner is 7.5 days. The microbial biomass and the respiration rate in the soil were promoted by the amendment of manure and chemical fertilizers, and inhibited by the addition of heavy metals and cleaner. The degradation rate correlate positively with the microbial biomass and the respiration rate.

• Applied Biological Chemistry
• /
• v.33 no.2
• /
• pp.138-142
• /
• 1990

The effects of heavy metals Cd, Cu, Cr, Ni, and Zn on the degradation of the insecticide fenitrothion (O, O-dimethyl O-4-nitro-m-tolyl phosphorothioate), the fungicide IBP (5-benzyl O, O-diisopropyl phosphorothioate), and the herbicide butachlor (N-butoxymetyl-2-chloro-2', 6'-diethylacetanilide) in flooded soils were examined in the laboratory. The degradation of the 3 pesticides in soil was greatly inhibited by the amendment of the 5 heavy metals. The inhibition rate was high in the order of butachlor>IBP>fenitrothion. Populations of fenitrothion-and butachlor-degrading microbes, which were counted by the MPN method, were lower in heavy metals added soil than in the control soil. The effect of heavy metals on the degradation of the 3 pesticides in soil varied with the kind and concentration of heavy metals and the kind of pesticides.

• Structural Engineering and Mechanics
• /
• v.45 no.6
• /
• pp.741-758
• /
• 2013

In this study, inelastic displacement ratios are investigated for existing systems with known lateral strength considering soil structure interaction. For this purpose, SDOF systems for period range of 0.1-3.0 s with different hysteretic behaviors are considered for a number of 18 earthquake motions recorded on soft soil. The effect of stiffness degradation on inelastic displacement ratios is investigated. The Modified Clough model is used to represent structures that exhibit significant stiffness degradation when subjected to reverse cyclic loading and the elastoplastic model is used to represent non-degrading structures. Soil structure interaction analyses are conducted by means of equivalent fixed base model effective period, effective damping and effective ductility values differing from fixed-base case. For inelastic time history analyses, Newmark method for step by step time integration was adapted in an in-house computer program. A new equation is proposed for inelastic displacement ratio of system with SSI with elastoplastic or degrading behavior as a function of structural period ($\tilde{T}$), strength reduction factor (R) and period lengthening ratio ($\tilde{T}$/T). The proposed equation for $\tilde{C}_R$ which takes the soil-structure interaction into account should be useful in estimating the inelastic deformation of existing structures with known lateral strength.

• Proceedings of the Earthquake Engineering Society of Korea Conference
• /
• 2000.04a
• /
• pp.357-366
• /
• 2000

Longitudinal dynamic behaviors of a bridge system under seismic excitations are examined with various magnitudes of peak ground accelerations. The stiffness degradation due to abutment-soil interaction is considered in the bridge model which may play the major role upon the global dynamic characteristics. The idealized mechanical model for the whole ridge system is proposed by adopting the multiple-degree-of-freedom system which can consider components such as pounding phenomena friction at the movable supports rotational and translational motions of foundations and the nonlinear pier motions. The abutment-soil interaction is simulated by utilizing the one degree-of-freedom system with nonlinear spring. The stiffness degradation of the abutment-soil system is found to increase the relative displacement under moderate seismic excitations.

• Journal of Korea Soil Environment Society
• /
• v.5 no.1
• /
• pp.85-96
• /
• 2000

The purpose of this study was to Investigate the effect of environmental conditions on the degradation of total petroleum hydrocarbons(TPH) in soil. The soil used for this study was sandy loam. Target contaminant, diesel oil, was spiked at 10.000mgTPH/kg dry soil. Moisture content was controlled to 50%, 70%, and 90% of field capacity of the soil. Temperature was controlled to $5^{\circ}C$, $10^{\circ}C$, $20^{\circ}C$, and $30^{\circ}C$. The active degradation of TPH was observed at the moisture contents of 50% and 70% of field capacity, and temperature of $10^{\circ}C$ to $30^{\circ}C$. Degradation rate of n-alkanes was about two times greater than that of TPH. Volatilization loss of TPH was about 2% of initial concentration. Biocide control and no aeration experiments indicated that removal of TPH was primarily occurred by biodegradation under aerobic condition.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2001.04a
• /
• pp.128-131
• /
• 2001

We evaluated natural attenuation of petroleum hydrocarbons in a shallow aquifer using a modeling study. The studied shallow aquifer was severely contaminated with petroleum hydrocarbons, especially toluene, ethylbenzene and xylenes (i.e, TEX). The exact spill history was not known. Therefor we used a contaminant level in May 1999 (the first sampling date of our integrated study) as an initial contaminant concentration. we calibrated required transport parameters using the contamination levels obtained from groundwater analyses in September of 1999. For fate and transport of the petroleum contaminants, five case 2 with sorption and degradation. case 3 with sorption and degradation (half decay constant compared with case 2), case 4 with degradation but no sorption, and case 5 with sorption but no degradation. For sorption and degradation, a linear sorption isotherm and first order irreversible decay was assumed, respectively and no additional contamination source to groundwater is also assumed.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2001.04a
• /
• pp.53-56
• /
• 2001

The degradation of tetrachloroethene (PCE) and trichloroethene (TCE) by vitamin B$_{12}$, an electron mediator was examined when zero valent metals (ZVMs) were used as built electron donors. Dechlorination of PCE and TCE by iron and zinc in the presence of vitamin B$_{12}$ showed that the zinc and vitamin B$_{12}$ combination greatly enhances the reaction rates for both PCE and TCE, but iron and vitamin B$_{12}$ result in an increase in reactivity only for PCE degradation, not for TCE degradation in comparing with meta]s only. This result indicates vitamin B$_{12}$(I) Is active towards both PCE and TCE degradation while vitamin B$_{12}$(II) is active towards both PCE. Calculated activation energies for the dechlorination of PCE in the presence of Vitamin B$_{12}$ showed that vitamin B$_{12}$ lowered the activation energy about 40-60 kJ/㏖ for the both metals.the both metals.