• 한국지하수토양환경학회지:지하수토양환경
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• 제17권6호
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• pp.33-42
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• 2012

This study was performed to find the problems according to interference factors (organic matter, pH, Cr, Mn, Fe, clay, and etc.) when we analyzed the hexavalent chromium [Cr(VI)] in soils using UV/VIS spectrometer (US EPA 7196A), attempted to evaluate the domestic applicability of analytical method (US EPA 7199) using IC-UV/VIS spectrometer as alternative method. The recovery rate of certified reference materials was 75.0% (US EPA 7196A) and 101.4% (US EPA 7199) by the analytical methods. As the results of performing QA/QC about US EPA 7199, method detection limit (MDL) and limit of quantification (LOQ) were 0.062 mg/kg, 0.196 mg/kg, respectively. The LOQ of US EPA 7199 was lower than that of the current soil official testing method in Korea (0.5 mg/kg). Cr(VI) contents in 23 soil samples were compared by the analytical methods of EPA 7196A and 7199. Cr(VI) was detected in 13 of 23 soil samples by EPA 7196A, while EPA 7199 was not detected in any soil samples. The Cr(VI) content in 23 soil samples by EPA 7196A was not clearly correlated with Cr, Fe, Mn and clay content in the soil samples. However, the contents of Cr(VI) and organic matter of the soil samples had the highest coefficient of determination ($R^2$) of 0.80. In order to evaluate the correlation between the recovery rates of Cr(VI) and organic matter contents in the soil samples, the recovery rates of 5 soil samples added Cr(VI) standard solution were analyzed by the analytical methods. According to the results, the higher the organic matter contents in soil samples, the lower the recovery rates of Cr(VI) by US EPA 7196, while in case of US EPA 7199, the recovery rates were stable regardless of the organic matter contents.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 1993년도 가을 학술발표회 논문집
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• pp.23-28
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• 1993

Shearing properties of soil reinforced with discrete randomly oriented inclusions depend on soil density, particle size, grading, fiber length, tensile strength and stiffness of fiber, mixing ration of fiber, confining stress, etc.. In this paper the effects of those various factors on shear strength of the fiber-reinforced soil was evaluated through triaxial tests and uniaxial tests. Tests were performed on two sandy soils and one silty soil with inclusions in varing lengths, contents and tensile strengths and tested at different confining stresses in triaxial test. From the experimental results, it was investigated if there is an optimal range of fiber lengths and fiber contents for the tested soils.

• Preventive Nutrition and Food Science
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• 제12권1호
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• pp.35-39
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• 2007

This study was conducted to investigate the effects of soil selenium (Se) supplementation level on Se contents of green tea and milk vetch. Four different concentrations of sodium selenite ($Na_2SeO_3$) solutions (0.0, 3.3, 33.0 and 165.0${\mu}g/mL$) were prepared and one liter of each solution was well mixed with 10 kg of compost (cowpea soil) to give four different levels of Se-containing soil: $T_1$, 0; $T_2$, 33; $T_3$, 330; $T_4$, and 1,650${\mu}g$/100 g soil. Green tea plants and milk vetch were individually cultivated in those soils for 60 days. Se contents of freeze-dried green tea leaves were 6.87, 10.40, 12.04, and 20.19 ${\mu}g/g$, respectively; all of which were significantly different (p<0.05) from the others except for $T_2$ and $T_3$. The results showed that Se-contents of green tea leaves were increased 1.5$\sim$2.9 times as the Se level in the soil increased. Regression equation between Se contents in green tea (Y) and soil Se supplementation level (X) was: Y=0.007X＋8.857. However, Se contents in the milk vetch were increased significantly (p<0.05) more with the same treatments $T_3$ (74 ${\mu}g/g$) and $T_4$ (187$\mu$g/g) in comparison to those at $T_1$ (5.0 ${\mu}g/g$) and $T_2$ (12.0$\mu$g/g). The increases ranged from approximately between 2.4 to 37.4 times that of the control group. Regression equation between Se contents in milk vetch (Y) and soil Se supplementation level (X) was: Y=0.1063X＋15.989. The large difference of Se contents between green tea leaves and milk vetch would be attributed by the difference of protein contents between the 30% or higher protein-content of legumes and 15$\sim$20% protein of shrubs. The present study clearly indicates that green tea leaves and milk vetch can be enriched in selenium by supplementing the soil with Se. Therefore, Se-enriched green tea or milk vetch powder could be utilized as functional foods in Se-fortified green tea drinks or salads, or as food additives to enhance the daily intake of Se.

• 한국토양비료학회지
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• 제44권6호
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• pp.1042-1047
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• 2011

조사한 시설재배지 토양의 Cu와 Zn 전함량은 평균이 각각 39.3과 $137mg\;kg^{-1}$로 Cu와 Zn의 집적 현상을 볼 수 있었다. 이동태 함량 평균은 0.18과 $0.47mg\;kg^{-1}$로 작물 생육 저해를 일으킬 수 있는 일반적인 함량 $1mg\;kg^{-1}$ (Cu)과 $2mg\;kg^{-1}$ (Zn)을 Zn이 한 농가에서 초과하였다. 상추 잎과 뿌리의 Cu 평균함량은 9.20과 $17.2mg\;kg^{-1}$로 주로 뿌리에 집적되어 있었고, Zn 평균함량은 각각 54.5와 $56.7mg\;kg^{-1}$로 잎과 뿌리에 균일하게 분포했다. Cu와 Zn의 토양 전함량-식물 이동계수는 0.1~1이었고, 토양 이동태-식물 이동계수는 10~1000이었다. Zn의 이동계수는 Cu의 이동계수 보다 높아, Zn이 Cu보다 이동성이 높음을 알 수 있었다. 상추 잎과 뿌리의 Cu와 Zn 흡수는 토양 전함량, 유기물 함량 보다는 토양 이동태 함량과 pH에 의해 강하게 영향을 받았고, 다중회귀방정식에 의해 고도의 유의관계를 설명할 수 있었다.

• 한국토양비료학회지
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• 제29권3호
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• pp.236-242
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• 1996

논토양에 무연탄회와 유연탄회를 토양무게의 0%, 15%, 30%로 pot에 첨가하고 수도를 재배하면서 침투수 중 중금속의 용탈량을 조사 분석한 결과는 다음과 같다. 침출수 중의 철의 용탈은 재배 후기에 높았으며 수도 재배로 철의 용탈은 증가되나 석탄회 처리간에는 뚜렷한 차이가 없었다. 침투수중의 Mn의 용탈량은 재배에 따라 증가되는 경향으로 재배구의 용탈량이 높았으며 석탄회 처리간에는 뚜렷한 차이가 없었다. 아연의 용탈은 수도 재배 20-25일 경이 가장 높았고 그 이후는 감소되는 경향으로 석탄회 시용으로 용탈량이 증가되지는 않았다. Cu의 침투수중 용탈량은 재배와 더불어 감소되는 경향을 나타냈으며, 석탄회 시용으로 Cu의 용탈량은 증가되지 않았으며 수도재배의 영향도 뚜렷하지 않았다. 침투수중 Pb의 용탈은 재배와 더불어 감소되는 경향이었으며 석탄회 처리로 크게 영향을 받지 않았고 7월 중순 이후는 거의 용탈이 되지 않았다. 침투수 중의 Cd 용탈량은 재배 15일 경에 가장 높았으며 그 이후 감소하여 재배 40일 이후 거의 용탈되지 않는 경향이었으며 석탄회 처리의 영향은 크지 않았다. 석탄회를 처리한 수도재배 조건하에서 투수중 중금속의 용탈량은 대조구에 비하여 우려할 양은 아니었다. 이것은 원래 석탄회 중의 중금속 함량이 낮았고, 또 토양의 pH가 비교적 높기 때문에 중금속의 용해도가 감소되어 가용성 중금 속의 침출량이 적었던 것으로 판단된다.

• 한국농공학회논문집
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• 제58권5호
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• pp.81-90
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• 2016

Due to droughts and water shortages causing severe damage to crops and other vegetations, much attention has been given to efficient irrigation for upland farming. However, little information has been known to measure soil moisture levels in a field scale and apply their spatial variability for proper irrigation scheduling. This study aimed to characterize the spatial variability and temporal stability of soil water contents at depths of 10 cm, 20 cm and 30 cm on flat (loamy soil) and hill-slope fields (silt-loamy soil). Field monitoring of soil moisture contents was used for variogram analysis using GS+ software. Kriging produced from the structural parameters of variogram was applied for the means of spatial prediction. The overall results showed that the surface soil moisture presented a strong spatial dependence at the sampling time and space in the field scale. The coefficient variation (CV) of soil moisture was within 7.0~31.3 % in a flat field and 8.3~39.4 % in a hill-slope field, which was noticeable in the dry season rather than the rainy season. The drought assessment analysis showed that only one day (Dec. 21st) was determined as dry (20.4 % and 24.5 % for flat and hill-slope fields, respectively). In contrary to a hill-slope field where the full irrigation was necessary, the centralized irrigation scheme was appeared to be more effective for a flat field based on the spatial variability of soil moisture contents. The findings of this study clearly showed that the geostatistical analysis of soil moisture contents greatly contributes to proper irrigation scheduling for water-efficient irrigation with maximal crop productivity and environmental benefits.

• Journal of Plant Biology
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• 제20권1호
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• pp.7-14
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• 1977

The seeds of bean(Glycine max M.) and corn(Zea mays L.) soaked in 5000ppm lead solution for 24 hours were sowed in the flowerpots being placed sandy-clay soil under the field condition. The fixed concentrations of various anions and 2000 ppm lead were supplied alternately in the sandy-clay soi of the flowerpots at two days interval from May to July in 1976. After the plants were harvested prior to the flowering stage, the lead contents of plnat and soil were analyzed by atomic absorption spectrophotometer. The lead contents absorbed by the plant roots showed the highest in an weak acid soil of the best suitable condition of plant growth. The absorption of lead by the plant roots was inhibited by the various anions, especially divalent anions of the soil. Some phosphate anions inhibited lead absorption more than otehr various anions in the soil. The more various anions were in the soil, the more plants could be protected from the lead toxicity. In the case of lead supply in the soil, 99.5% of lead was accumulated in the upper layer of the soil(0-10cm), and 0.5% of lead accumulated in the lower layer (10-20cm). Therefore, the yellow-brown and white symptoms on the leaves and the inhibition of root growth by lead toxicity was increased in the early stage of the germination, however decreased in accordance with the progress of the growing stage becuase of the root growth toward beneath the lower layer of the soil. In spite of the contents of 3773ppm lead in the soil, the symptoms of lead toxicity was not found in the grown plants. At that time the lead contents of the plants absorbed from the soil were minimum 0.78ppm and maximum 3.64ppm through the growing stage.

• 한국토양비료학회지
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• 제30권1호
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• pp.72-83
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• 1997

Korean lespedeza의 자생지에 대한 작물의 생육상황, 작물에 함유된 무기영양상태, 자생지 및 자생지 부근의 토양의 화학 및 물리성에 관한 기초자료를 얻고져 총 46개 군락지역을 조사하였으며 얻은 자료를 분석한 결과는 다음과 같다. Korean lespedeza의 초장 및 건물중은 조사시기 및 지역에 따라서 큰 차이를 보여, 조사일이 늦은 8월 하순의 수치가 높았다. Korean lespedeza의 무기함량은 사료작물로서 가장 우수한 Alfafa에 비하여 Fe와 Mn함량은 많으나 P와 Zn함량은 비슷하였고, K, Ca, Mg, Cu등 함량은 적었다. Korean lespedeza의 자생지 토양을 우리나라 전체 토양과 자생지 부근의 농경지 밭토양과 비교하였을 때 자생지 토양의 화학적 특성은 pH와 Ca함량은 높은 반면, Mg함량은 비슷하였고, 유효 $P_2O_5$, 치환성K, OM의 함량은 낮았으며, 자생지 토양의 물리적 특성은 모래함량이 많은 대신 미사와 점토함량은 적었다. Korean lespedeza는 대체적으로 일반작물이 잘 자라지 못하는 물리-화학적 특성이 불량한 토양에서도 잘 자라며, 대체적으로 나지상태에 가까운 사양토나 양질사토에서 많이 자생하는 것으로 보아, 토양의 유실방지에 의한 토양보전에 큰 역할을 하고 있는 것으로 생각된다.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2002년도 학술발표회 발표논문집
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• pp.405-408
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• 2002

The electrical conductivity, EC is a major indicator of soil salinity. Measuring EC of saturation-paste extract of soil, ECe, is the standard way to evaluate soil salinity. However much of the data on soil salinity have been obtained by measuring the EC of the 1:5 soil-to-water extract, EC(1:5) or salts contents(%) which multiplied by conversion factor. And, thus we attempted to collect and analysis 90 soil samples at 9 reclaimed tidelands in Korea and to derive a relationship between ECe and dilution factor at ECe and EC(1:5), $DF_{1:5}$ of 3 soil textural conditions and 6 salinity conditions. Regression equations between ECe and $DF_{1:5}$ were obtained $ECe=1.4701ln(DF_{1:5})+5.0974(r^2=0.97^{**})$ in case of more than 50% silt contents, $ECe=2.1399ln(DF_{1:5})+5.3462 (r^2=0.99^{***})$ in case of below 50% silt contents, and $ECe=1.5927ln(DF_{1:5})+5.2486 (r^2=0.98^{***})$ in all cases, and then we suggested the $DF_{1:5}\;and\;DF_%$ of 3 soil textural conditions and 6 salinity conditions.

• 한국대기환경학회지
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• 제23권2호
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• pp.225-241
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• 2007

A closed flux chamber system was used for measuring major greenhouse gas (GHG) emission from tideland and/or wetland soils in estuarine area at Saemankum, Kunsan in southwestern Korea during from months of February to June 2006. Hourly averaged GHG soil emissions were measured two to three times a day during the ebb tide hours only. Site soils were analyzed for soil parameters (temperature, pH, total organic contents, N and C contents in soil) in the laboratory. Soil GHG fluxes were calculated based on the GHG concentration rate of change measured inside a closed chamber The analysis of GHG was conducted by using a Gas Chromatography (equipped with ECD/FID) at laboratory. Changes of daily, monthly GHGs' fluxes were examined. The relationships between the GHG emissions and soil chemical contents were also scrutinized with respect to gas production and consumption mechanism in the soil. Soil pH was pH $7.47{\pm}0.49$ in average over the experimental period. Organic matter contents in sample soil was $6.64{\pm}4.98\;g/kg$, and it shows relatively lower contents than those in agricultural soils in Kunsan area. Resulting from the soil chemistry data, soil nitrogen contents seem to affect GHG emission from the tidal land surface. The tidal soil was found to be either source or sink for the major GHG during the experimental periods. The annual average of $CH_{4}\;and\;CO_{2}$ fluxes were $0.13{\pm}0.86\;mg\;m^{-2}h^{-1}\;and\;5.83{\pm}138.73\;mg\;m^{-2}h^{-1}$, respectively, which will be as a source of these gases. However, $N_{2}O$ emission showed in negative flux, and the value was $-0.02{\pm}0.66\;mg\;m^{-2}h^{-1}$, and it implies tidal land surface act as a sink of $N_{2}O$. Over the experimental period, the absolute values of gas fluxes increased with soil temperature in general. Averages of the ambient gas concentration were $86.8{\pm}6.\;ppm$ in $CO_{2},\;1.63{\pm}0.34\;ppm\;in\;CH_{4},\;and\;0.59{\pm}0.15\;ppm\;in\;N_{2}O$, respectively. Generally, under the presence of gas emission from agricultural soils, decrease of gas emission will be observed as increase in ambient gas concentration. We, however, could not found significant correlation between the ambient concentrations and their emissions over the experimental period. There was no GHG compensation points existed in tide flat soil.