• Title/Summary/Keyword: Soil breakdown

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Ionization Behaviors by Types of Soil due to Lightning Impulse Voltages in a Hemishperical Electrode System (반구형 전극계에서 뇌임펄스전압에 의한 토양의 종류별 이온화 특성)

  • Lee, Kyu-Sun;Park, Geon-Hun;Kim, Hoe-Gu;Lee, Bok-Hee
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.1
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    • pp.119-125
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    • 2009
  • This paper deals with the characteristics of soil ionization affecting the dynamic performance of grounding systems under lightning impulse voltage. A concentric hemispherical electrode system was employed in order to facilitate the field calculation and analysis of the experimental results. The parameters such as the ionization threshold and breakdown field intensity, the pre-ionization and the post ionization resistances, the time-lag to ionization, the transient impedance, the equivalent ionized radius for various soil media were measured and analyzed. The dynamic characteristics of ionization processes under lightning impulse voltage are strongly dependent on the types of soil and water content. As a result, a soil ionization reduces the ground resistance and there is a little effect of applied impulse polarity on the soil ionization threshold field intensity. Although the ionization threshold field intensity of wet clay with 30% water content is the highest, its ionized zone was found to be the smallest amongst the test samples.

Application of Laser-Induced Breakdown Spectroscopy (LIBS) for In-situ Detection of Heavy Metals in Soil (토양내 중금속 실시간 탐지를 위한 레이저 유도붕괴 분광법의 활용에 대한 소개)

  • Ko, Eun-Joung;Hamm, Se-Yeong;Kim, Kyoung-Woong
    • Economic and Environmental Geology
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    • v.40 no.5
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    • pp.563-574
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    • 2007
  • Laser induced breakdown spectroscopy (LIBS) is a recently developed analytical technique that is based upon the measurement of emission lines generated by atomic species close to the surface of the sample, thus allowing their chemical detection, identification and quantification. With powerful advantages of LIBS compared to the conventional analytical methodology, this technique can be applied in the detection of heavy metals in the field. LIBS allows the rapid analysis by avoiding laborious chemical steps. LES have already been applied for the determination of element concentration in a wide range of materials in the solid, liquid and gaseous phase with simplicity of the instrument and diversity of the analytical application. These feasibility of rapid multi elemental analysis are appealing proprieties for the in-situ analytical technique in geochemical investigation, exploration and environmental analysis. There remain still some limitations to be solved for LIBS to be applied in soil environment as an in-situ analytical technology. We would like to provide the basic principle related to the plasma formation and laser-induced breakdown of sample materials. In addition, the matrix effect, laser properties and the various factors affecting on the analytical signal of LIBS was dealt with to enhance understanding of LIBS through literature review. Ultimately, it was investigated the feasibility of LIBS application in soil environment monitoring by considering the basic idea to enhance the data quality of LIBS including the calibration method for the various effects on the analytical signal of LIBS.

Elemental Composition of the Soils using LIBS Laser Induced Breakdown Spectroscopy

  • Muhammad Aslam Khoso;Seher Saleem;Altaf H. Nizamani;Hussain Saleem;Abdul Majid Soomro;Waseem Ahmed Bhutto;Saifullah Jamali;Nek Muhammad Shaikh
    • International Journal of Computer Science & Network Security
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    • v.24 no.6
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    • pp.200-206
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    • 2024
  • Laser induced breakdown spectroscopy (LIBS) technique has been used for the elemental composition of the soils. In this technique, a high energy laser pulse is focused on a sample to produce plasma. From the spectroscopic analysis of such plasma plume, we have determined the different elements present in the soil. This technique is effective and rapid for the qualitative and quantitative analysis of all type of samples. In this work a Q-switched Nd: YAG laser operating with its fundamental mode (1064 nm laser wavelength), 5 nanosecond pulse width, and 10 Hz repetition rate was focused on soil samples using 10 cm quartz lens. The emission spectra of soil consist of Iron (Fe), Calcium (Ca), Titanium (Ti), Silicon (Si), Aluminum (Al), Magnesium (Mg), Manganese (Mn), Potassium (K), Nickel (Ni), Chromium (Cr), Copper (Cu), Mercury (Hg), Barium (Ba), Vanadium (V), Lead (Pb), Nitrogen (N), Scandium (Sc), Hydrogen (H), Strontium (Sr), and Lithium (Li) with different finger-prints of the transition lines. The maximum intensity of the transition lines was observed close to the surface of the sample and it was decreased along the axial direction of the plasma expansion due to the thermalization and the recombination process. We have also determined the plasma parameters such as electron temperature and the electron number density of the plasma using Boltzmann's plot method as well as the Stark broadening of the transition lines respectively. The electron temperature is estimated at 14611 °K, whereas the electron number density i.e. 4.1 × 1016 cm-3 lies close to the surface.

Studies on the soil freezing depth and change of moisture contents in evergreen plants upon subzero temperature in (강원도지역의 토양동결심 및 상록식물의 함수량 추이에 관한연구 (1))

  • 홍종운;허범양;원경열;임병춘;이기철;하상건
    • Asian Journal of Turfgrass Science
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    • v.4 no.1
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    • pp.42-48
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    • 1990
  • Experiments were conducted to investigate the soil freezing depth and pattern with freezing measuring instruments during 1988-l989 winter season in Kangwon province. Freezing measuring instrument was made with acrylic pipes which were consisted of inner and outer parts. Inner pipe was filled with 0.01 % methylene blue solution and rubber hose to protect pipe breakdown by solution freezing. Freezing measurements were carried out by observing discoloration of methylene blue solution. Moisture content of evergreen trees and ground cover plants was also examined in the winter season. The observed results are as follows: 1.In the land of I OOM above sea level, soil freezing depth became deeper as the sum of Accumulated degree-days of temperature below 0˚C(0˚C . day) increased: Soil freezing depth was 30-40cm at l00˚C, 42-43cm at 150˚C, and 47cm at 200˚C day 2.Soil freezing with vinyl mulching was less developed by l3cm at l00˚C with sum of subzero temperature, by l7cm at 200˚C than that of the bare ground. Soil of rich hulls mulching with 4Ocm was not frozen until soil freezing at the bare ground was developed to 25cm depth. 3.Cashmeron mulching was more effective than felt mulching in the heat insulation of soil. 4.Thawing of soil was done from the lowest part of the frozen in the ground to upward in the beginning and after that it was done from the surface of frozen soil to downward. Finally thawing was completed at the middle of frozen soil.

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Infection Mechanism of Pathogenic Exduate by Soil-Borne Fungal Pathogens : A Review

  • Lim, You-Jin;Kim, Hye-Jin;Song, Jin-A;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.622-627
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    • 2012
  • The processes to determine the composition, dynamics, and activity of infection mechanisms by the rhizosphere microflora have attracted the interest of scientists from multiple disciplines although considerable progress of the infection pathways and plant-pathogen interactions by soil borne fungal pathogens have been made. Soilborne pathogens are confined within a three-dimensional matrix of mineral soil particles, pores, organic matter in various stages of decomposition and a biological component. Among the physical and chemical properties of soils soil texture and matric water potential may be the two most important factors that determine spread exudates by soil borne fungal pathogens, based on the size of the soil pores. Pathogenic invasion of plant roots involves complex molecular mechanisms which occur in the diffuse interface between the root and the soil created by root exudates. The initial infection by soilborne pathogens can be caused by enzymes which breakdown cell wall layers to penetrate the plant cell wall for the fungus. However, the fate and mobility of the exudates are less well understood. Therefore, it needs to develop methods to control disease caused by enzymes produced by the soilborne pathogens by verifying many other possible pathways and mechanisms of infection processes occurring in soils.

A Study on the Evolution of 3,4-DCA and TCAB in Some Selected Soils(Part II) -Degradation of $^{14}C-3,4-DCA\;and\;^{14}C-TCAB$- (수종토양중(數種土壤中)에서 3,4-DCA 및 TCAB의 변화(變化)에 관(關)한 연구(硏究)(제2보(劑二報)) -$^{14}C-3,4-DCA$$^{14}C-TCAB$ 의 분해(分解)-)

  • Lee, Jae-Koo;Fournier, J.C.
    • Applied Biological Chemistry
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    • v.21 no.2
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    • pp.71-80
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    • 1978
  • In an attempt to elucidate the fate of 3,4-DCA and TCAB in various French soils, uniformly $^{14}C-ring-labeled$ 3,4-DCA and TCAB mere utilized and the following results obtained. 1) The rate of breakdown of $^{14}C-3,4-DCA$ into $^{14}CO_2$ was relatively higher in the early stage than that in the later stage. In 6 months of incubation in alkaline soil (pH 7.9), the rate was as high as 6.5% at dose 1 (1.5 ppm) and as low as 1.92% at dose 2(94 ppm), whereas in organic acid soil (pH 5.5) the rate was 4.91% at dose 1 and 4.24% at dose 2, respectively, without making any great difference between the two levels. 2) At dose 1, 47.70% of the initial radioactivity of $^{14}C-3,4-DCA$ was bound to soil in organic acid soil and 29.49% bound in alkaline soil, whereas at dose 2, 38.40% in organic acid soil and 20.30% in alkaline soil, respectively. 3) The amount of formation of $^{14}C-TCAB$ from $^{14}C-3,4-DCA$ seems to depend largely on the concentration of 3,4-DCA applied rather than on soil types. At dose 2, the amount was 50% of the total radioactivity extracted in organic acid soil and 30% in alkaline soil, corresponding to 1.8% and 1.4% of the initial radioactivity applied to soil, respectively. Cis-TCAB also seemed to be formed at dose 2 in both soils. Meanwhile, at dose 1, even though $^{14}C-TCAB$ was detected in trace on tlc and glc in both soils, the amount does not exceed 2 to 3% of the radioactivity extracted, corresponding to 0.05 to 0.1% of the initial radioactivity. 4) The rate of breakdown of $^{14}C-TCAB$ into $^{14}CO_2$ ranged from 0.05 to 0.20% in all the four soils. Most of the applied $^{14}C-TCAB$ remained intact after 3 months, not producing any detectable metabolites. 5) The fact that much more $^{14}C-TCAB$ was adsorbed to alkaline soil than to the other soils strongly indicates that in alkaline condition trans-isomer was converted tocisisomer which has the higher adsorption affinity than the former.

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A Study on Anaerobic Biodegradation of MTBE and BTEX by Indigenous Microorganisms (토착 미생물을 이용한 MTBE와 BTEX의 혐기성 생분해 연구)

  • Chung, Woo-Jin;Chang, Soon-Woong
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.88-94
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    • 2016
  • The simultaneous biodegradation between MTBE (Gasoline additives) and BTEX (Benzene, Toluene, Ethyl-benzene, o-Xylene, m-Xylene, p-Xylene) was achieved within a competitive inter-relationship, with not only electron accepters such as nitrate, sulfate, and iron(III) without oxygen, but also with electron donors such as MTBE and BTEX. Preexisting indigenous microorganisms from a domestic sample of gasoline contaminated soil was used for a lab-scale batch test. The result of the test showed that the biodegradation rate of MTBE decreased when there was co-existing MTBE and BTEX, compared to having just MTBE present. The growth of indigenous microorganisms was not affected in the case of the MTBE treatment, whereas the growth of the microorganisms was decreased in combined MTBE and BTEX sample. This may indicate that an inhibitor related to biodegradation when BTEX and MTBE are mixed will be found. This inhibitor may be found to retard the anaerobic conditions needed for efficient breakdown of these complex carbon chain molecules in-situ. Moreover, it is also possible that an unknown competitive reaction is being imposed on the interactions between MTBE and BTEX dependent on conditions, ratios of mixture, etc.

The preliminary batch study for evaluating biobarrier application on sequential degradation of TCE products

  • 이재선;이시진;장순웅
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.454-457
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    • 2003
  • A new approach for groundwater treatment combines a permeable Fe(0) barrier to breakdown higher chlorinated solvents like PCE and TCE with a downgradient aerobic biological treatment system to biotransform less chlorinated solvents, such as DCE and vinyl chloride (VC). The expected bacterial performance downgradient of an Fe(0) barrier was evaluated through laboratory batch experiments with a toluene-degrading mixed culture that cometabolically transforms cis-1,2-DCE and VC. The amount of cis-1,2-DCE (initially at 2,000 ppb) and VC (initially at 2,000 ppb) transformed was controlled by the initial toluene (20,000 ppb) concentration. VC was removed much more effectively than Cis-1,2-DCE, and a higher toluene concentration in comparison to the co-substrate concentrations was needed for complete co-substrate removal. Overall, the coupling of an Fe(0) barrier and subsequent biodegradation appears feasible for remediation of complex mixtures of chlorinated solvents and petroleum hydrocarbons in groundwater

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Analysis on the Seepage Behavior of Organic Contaminants in Soil (토양에서 유기화합물질의 침투 거동 연구)

  • Lee, Jun Ho;Han, Sun Hyang;Park, Kap Song
    • Journal of Korean Society on Water Environment
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    • v.29 no.4
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    • pp.489-496
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    • 2013
  • Ground water underlying soil is vulnerable to pollution by organic chemicals through their percolation through the soil system. This study was conducted to provide information on the seepage behavior of organic chemical contaminants in clay, silty and sandy soils. Chloroform, 1,1,1-trichloroethane and trichloroethylene are readily transported through the soil; their percolated mass were 4.6-19.2 percent of the total mass applied. Tetrachloroethylene, 1,2-dichlorobenzene and 1,3-dichlorobenzene were retarded by soils due to sorption. Between 0.6 and 4.8 percent of the material applied to the surface percolated within the experimental period. Carbon tetrachloride was attenuated considerably by passage through soils. Only 0.1-0.4 percent of the mass reached the groundwater. Significant degradation of bromoform was observed. Apparent breakdown of intermediates of the brominated compounds were detected. Transformations of the brominated compounds appear to be the result of both biological and chemical processes. The effect of soil type on the mobility of organic chemical contaminants was considerable. The organic contaminants moved faster in sandy soil than in either clay or silty soils.

Potential Reduction and Energy Dispersion Due to Ionization Around the Submerged Ground Rod (수중에 잠긴 접지전극 주변에서의 이온화에 의한 전위저감 및 에너지방출)

  • Choi, Jong-Hyuk;Ahn, Sang-Duk;Yang, Soon-Man;Lee, Bok-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.1
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    • pp.92-99
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    • 2009
  • Deeply-driven ground rod in the rainy season may contact with rainwater and ground water. When surge voltages are applied to the submerged ground rods, the ionization around the ground rods are occurred. Ionization in soil and/or water is affected in dynamic performance of ground rod systems. This work aims at studying the transient performance of ground rod system under impulse voltage using scale model in an electrolytic tank. The potential reduction and energy dispersion caused by ionization were treasured and quantitatively analyzed using the Matlab Program. As a result, the peak voltage at the terminal of ground rod was varied with water resistivity and charging voltage of Marx generator. The potential at the terminal of the ground rod was approximately reduced to a half of the applied voltage just below breakdown voltage. Also the energy more than half of the applied energy was dispersed through the ground rod due to ionization just below breakdown voltage.