• Title/Summary/Keyword: Soil and Groundwater

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이액상 시스템에서 토양으로부터 비수용성 액체로의 PAHs의 이동특성

  • 양지원;이재영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.247-249
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    • 2002
  • The transfer behaviors of three Polyarmatic hydrocarbons (PAHs) from soil to non-aqueous phase liquid (NAPL) were investigated. The three different PAHs were phenanthrene, anthracene, and pyrene. The used NAPLs were silicone oil and paraffine oil. The percentage of the remained PAHs into soil were similar without the relation to kinds of NAPLs. And the transfer of PAHs into NAPLs was fastened until 1 day as the increase of mixing rate but in the case of 450 rpm, the remained PAHs into soil was increased after 1 day because NAPLs was emulsified.

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Calculation of Radius of Influence and Evaluation of Applicability of Air Sparging/Soil Vapor Extraction system for the Remediation of Petroleum Contaminated Rail Site (유류로 오염된 철로지역의 지중정화를 위한 영향반경 산정과 공기주입법/토양증기추출법의 적용성 평가)

  • Cho, Chang-Hwan;Park, Joung-Ku;Kim, Yong-Deok;Seo, Chang-Il;Jin, Hai-Jin;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.20 no.1
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    • pp.1-6
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    • 2015
  • The objectives of this study were to calculate the radius of influence (ROI) of well for an air-sparging (AS)/soil vapor extraction (SVE) system and to evaluate the applicability of the system applied for the remediation of the petroleum contaminated rail site. For air permeability test, three monitoring wells were installed at a location of 1.3 m, 2.3 m, 3.0 m from the extraction well. And the pressure of each monitoring well was measured by extracting air from the extraction well with the pressure and flow of $(-)2,600mmH_2O$ and $1.58m^3/min$. The ROI for an extraction well was calculated as 4.31 m. Air was injected into the injection well with the pressure and flow of $3,500mmH_2O$ and $0.6m^3/min$ to estimate the radius of influence for oxygen transfer. Oxygen concentrations of air from three monitoring wells were measured. The ROI of an injection well for oxygen transfer was calculated as 3.46 m. The 28 extraction wells and 19 injection wells were installed according to the ROI calculated. The AS/SVE system was operated eight hours a day for five months. The rail site was contaminated with the petroleum and concentrations of benzene, toluene, and xylene were over the 'Worrisome Standard' of the 'Soil Environment Conservation Act'. The contaminated area was estimated as $732m^2$ and contaminants were dispersed up to (-)3 m from the ground. During the operation period, soil samples were collected from 5 points and analyzed periodically. With the AS/SVE system operation, concentrations of benzene, toluene, and xylene were decreased from 7.5 mg/kg to 2.0 mg/kg, from 32.0 mg/kg to 23.0 mg/kg, from 35.5 mg/kg to 23.0 mg/kg, respectively. The combined AS/SVE system applied to the rail site contaminated with volatile organic compounds (VOCs) exhibited a high applicability. But the concentration of contaminants in soil were fluctuated due to the heterogeneous of soil condition. Also the effect of the remediation mechanisms was not clearly identified.

EFFECT OF SOIL TEXTURE ON SURFACTANT-BASED REMEDIAT10N OF HYDROPHOBIC ORGANIC-CONTAMINATED SOIL

  • Lee, Dal-Heui;Robert D. Cody;Kim, Dong-Ju
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.22-25
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    • 2001
  • 본 연구는 소수성 유기물로 오염된 토양의 계면 활성제를 이용한 복원에 토양의 조성이 미치는 영향에 대한 것으로서, 토양의 조성에 따른 배치실험 및 주상실험을 실시하였다. 복원 정도는 clay 함량에 따라 대우 달랐으며, clay 함량이 34% 미만일 때 복원율이 높았음을 보여주었다. 또한 clay 함량이 68% 이상일 때에는 복원율이 매우 낮았다.

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Groundwater and Soil Environment of Plastic Film House Fields around Middle Korea (우리나라 중부지방 시설원예지 토양 및 지하수 환경)

  • Kim, Jin-Ho;Ryu, Jong-Soo;Kwun, Soon-Kuk
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2001.10a
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    • pp.479-483
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    • 2001
  • This Study was carried out to know the soil properties and the quality of shallow groundwater in the plastic film house fields around mid-Korea. This study was conducted at 11 sites in Suweon, Pyungtaek, Yongin, and Chunchen on May, June, July and August in 1999. The the average concentration of nitrate-nitrogen was 19.1 mg/L, it reached almost to the limiting level, 20 mg/L. Moreover about 36.4% of survey sites exceeded limiting level to agricultural groundwater quality. And Sulfur concentrations also at some sites exceeded to agricultural groundwater quality limit level (50 mg/L), which could make damage to the crop. Nitrate-nitrogen, which is one of the most important factors in the groundwater quality, It has highly positive correlation with any other ion in groundwater. This result showed that groundwater quality management practices should be taken for the agricultural production as well as for environment at the plastic film house areas.

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Interpolation of Missing Groundwater-Level Data at the National Groundwater Monitoring Wells (장기 관측 지하수위 결측자료 보완)

  • 정상용;심병완;강동환;원종호;김규범
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.15-22
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    • 2000
  • Long ranged groundwater-level data often have the missing intervals because of the trouble of monitoring systems at the national groundwater monitoring wells. Geostatistical methods are very useful for the supplement of the missing data. Ordinary kriging was applied for the interpolation of the missing groundwater-level data with a smooth sinusoidal variation. Conditional simulation was used for the reproduction of the missing data with high fluctuations. Two geostatistical methods produced the very accurate estimates at the missing intervals and reproduced their original variations. This fact is proved by the cross validation test and graphical method, respectively.

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Hydrochemical Characteristics and Nitrate-Nitrogen Contamination in Shallow Groundwater in Two Agricultural areas in Korea

  • Sul-Min Yun;Hang-Tak Jeon;Ji-Min Hwang;MoonSu Kim;HyunKoo Kim;Se-Yeong Hamm
    • Journal of the Korean earth science society
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    • v.44 no.4
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    • pp.291-306
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    • 2023
  • Shallow groundwater in rural areas is primarily polluted by agricultural activities. Nitrate-nitrogen is an indicator of artificial pollution. In this study, the hydrochemical characteristics and nitrate-nitrogen pollution of shallow groundwater were examined in two agricultural villages (Hyogyo-ri and Sinan-ri) in Chungcheongnam-do Province, Korea. Physicochemical quality analysis of shallow groundwater and stream water in the field, and chemical analysis in the laboratory were conducted from July 2020 to October 2021. In Hygyo-ri and Sinan-ri villages, shallow groundwater mainly belonged to the Ca-Cl, Ca-H CO3, Na-HCO3, and Na-Cl types, whereas stream water predominantly belonged to the Ca-HCO3 type. The nitrate-nitrogen concentration in shallow groundwater varied depending on the season, displaying an increased concentration of nitrate-nitrogen in the dry season compared to the rainy season. Stream water may be influenced by runoff into villages from the surrounding area, although both shallow groundwater and stream water are affected by artificial pollution. In addition, the nitrate-nitrogen concentration in stream water was lower than that in shallow groundwater.

Assessment of Drought Effects on Groundwater System in Rural Area using Standardized Groundwater Level Index(SGI) (표준지하수위지수(SGI)를 이용한 농촌지역 지하수계의 가뭄 영향 평가)

  • Song, Sung-Ho
    • Journal of Soil and Groundwater Environment
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    • v.23 no.3
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    • pp.1-9
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    • 2018
  • This study is aimed to quantitatively evaluate the effects of drought on groundwater system in rural areas. For this purpose, the standardized groundwater level index (SGI) was used for 68 groundwater monitoring wells. To determine accumulation period (AP) which represents the month with the highest correlation coefficient between SGI and SPI, correlation analysis between the two for 68 wells were peformed. The results indicated the AP values ranged in 1~3 months for most of the well, but it was 7~10 months in some wells. These results can be interpreted such that the total amount of groundwater will not decrease significantly in long-term drought situations unlikely the reservoirs with the high AP values. The nationwide maximum AP values were 4.1 and 4.0 in Chungbuk-do and Gyeongnam-do, while the minimum AP values were 1.8 and 2.0 in Gangwon-do and Chungnam-do, respectively. The maximum and minimum values of correlation coefficient were 0.623 and 0.459 in Gyeongnam-do and Chungnam-do/Chungbuk-do, respectively. Consequently, it could be concluded that the wells with low AP value tend to respond to short-term drought, but it has little effect on groundwater system when the long drought occurs.

제주도 서부지역의 지하수 오염취약성 작성 연구

  • Lee Yong-Du;Song Hui-Gyeong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.316-318
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    • 2006
  • The purpose of this research is to write out vulnerability for western area in Jeju island by using drastic method which is the most frequently utilized among the writing techniques of underground water vulnerability. In case of aquifer, it was divided into two types, gravel layer or not and rated. And soil media was rated two kinds of method. Plan 1 is concerned with only soil class and plan 2 is concerned with soil class and gravels (or rocks), Vadose zone was rated differently according to the ratio of gravel layer. In case of plan 1, the scope of drastic index is from the minimum 77 to the maximum 176, on the other hand, plan 2, the scope of drastic index is from the minimum 79 to the maximum 182. In case of using the water quality data of Nitrate from 1994 to 2004, Pearson correlation coefficient are 0.164(Plan 1) and 0.124(Plan 2) and Spearman correlation coefficient are 0.132(Plan 1) and 0.113.

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Effect of the Presence of Soil on the Ferrous Catalyzed Sodium Persulfate Oxidation of Naphthalene (과황산나트륨과 제일철 촉매를 이용한 나프탈렌 산화 시 토양이 미치는 영향 평가)

  • Han, Dai-Sung;Yun, Yeo-Bog;Ko, Seok-Oh
    • Journal of Soil and Groundwater Environment
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    • v.15 no.1
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    • pp.29-38
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    • 2010
  • Batch tests were carried out to examine the influence of the presence of soil and Fe(II) sorption capacity of soil on the ferrous catalyzed sodium persulfate oxidation for the destruction of organic pollutants in the application of in-situ chemical oxidation. Laboratory column tests were also conducted to investigate the transport of oxidant and catalyst in contaminated groundwater. Test results proved that Fe(II) was adsorbed on soil surface, and thus soil behaved as a heterogeneous catalyst, enhancing the naphthalene removal rate up to 50%. Column tests that were conducted with and without dissolved Fe(II) showed that naphthalene removal ratio were 24% and 25%, respectively. The removal efficiency was not enhanced with dissolved Fe(II), since the dissolved Fe(II) flew out of the column as the oxidant progressively injected into the column saturated with Fe(II). It indicates that the injected oxidant could not interact with dissolved Fe(II). But target organic pollutant was degraded in soil column system, implying that sulfate radical was produced by the reaction of dissolved persulfate with Fe(II) adsorbed on soil.

Impact of Residual Hydrofluoric Acid on Leaching of Minerals and Arsenic from Different Types of Geological Media (잔류 불산에 의한 모델 지질토양시료의 광물 용해 및 비소 용출 특성)

  • Jeon, Pilyong;Moon, Hee Sun;Shin, Doyun;Hyun, Sung Pil
    • Journal of Soil and Groundwater Environment
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    • v.23 no.2
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    • pp.23-29
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    • 2018
  • This study explored secondary effects of the residual hydrofluoric acid (HF) after a hypothetical acid spill accident by investigating the long-term dissolution of minerals and leaching of pre-existing arsenic (As) from two soil samples (i.e., KBS and KBM) through batch and column experiments. An increase in the HF concentration in both soil samples resulted in a dramatic increase in the release of major cations, especially Si. However, the amounts of mineral dissolved were dependent on the soil type and mineral characteristics. Compared to the KBM soil, relatively more Ca, Mg and Si were dissolved from the KBS soil. The column experiment showed that the long-term dissolution rates of the minerals are closely associated with the acid buffering capacity of the two soils. The KBM soil had relatively higher effluent pH values compared to the KBS soil. Also, more As was leached from the KBM soil, with a more amorphous hydrous oxide-bound As fraction. These results suggest that the potential of heavy metal leaching by the residual acid after an acid spill will be influenced by heavy metal speciation and mineral structure in the affected soil.