• 제목/요약/키워드: Soil and Groundwater

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과불화화합물 구조적 속성에 따른 흡착 특성 연구 (Study on Adsorption Characteristics of Perfluorinated Compounds(PFCs) with Structural Properties)

  • 최효정;김덕현;윤종현;권종범;김문수;김현구;신선경;박선화
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제26권5호
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    • pp.20-28
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    • 2021
  • Perfluorinated compounds(PFCs), an emerging environmental pollutant, are environmentally persistent and bioaccumulative organic compounds that possess a toxic impact on human health and ecosystems. PFCs are distributed widely in environment media including groundwater, surface water, soil and sediment. PFCs in contaminated solid can potentially leach into groundwater. Therefore, understanding PFCs partitioning between the aqueous phase and solid phase is important for the determination of their fate and transport in the environment. In this study, the sorption equilibrium batch and kinetic experiment of PFCs were carried out to estimated the sorption coefficient(Kd) and the fraction between aqueous-solid phase partition, respectively. Sorption branches of the PFDA(Perfluoro-n-decanoic acid), PFNA(Perfluoro-n-nonanoic acid), PFOA(Perfluoro-n-octanoic acid), PFOS(Perfluoro-1-octane sulfonic acid) and PFHxS(Perfluoro-1-hexane sulfonic acid) isotherms were nearly linear, and the estimated Kd was as follow: PFDA(1.50) > PFOS(1.49) > PFNA(0.81) > PFHxS(0.45) > PFOA(0.39). The sorption kinetics of PFDA, PFNA, PFOA, PFOS and PFHxS onto soil were described by a biexponential adsorption model, suggesting that a fast transport into the surface layer of soil, followed by two-step diffusion transport into the internal water and/or organic matter of soil. Shorter times(<20hr) were required to achieve equilibrium and fraction for adsorption on solid(F1, F2) increased with perfluorinated carbon chain length and sulfonate compounds in this study. Overall, our results suggested that not only the perfluorocarbon chain length, but also the terminal functional groups are important contributors to electrostatic and hydrophobic interactions between PFCs and soils, and organic matter in soils significantly affects adsorption maximum capacity than kinetic rate.

원전사고에 따른 토양.지하수 방사성오염의 효과적인 관리 연구 (A Study on Effective Management Scheme for Soil and Groundwater Contaminated by Radioactive Materials Due to Nuclear Accidents)

  • 김희주;현윤정;김영주;황상일
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제16권6호
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    • pp.113-121
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    • 2011
  • In this study, we suggested the management scheme of analyzing the national and oversea related policy against soil and groundwater contamination by radioactive materials due to nuclear accidents. In Korea, we need to remedy swiftly the contaminated land due to intensive land development demand. So, we need to develop more effective management scheme to recover actively the land contaminated by radioactive materials. We require to improve monitoring network, to expand media-specific monitoring system, to prepare management system for remediation of contaminated land, and to develop flow work for soil and groundwater remediation.

기름 유출로 인한 토양 및 지하수의 오염

  • 김동진;양재의;유진열;김희갑;김기동
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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    • pp.424-427
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    • 2006
  • Soil contamination with petroleum oil around a military army was investigated. It showed that soils of a riverside highland, an entrance of the military army, and nearby roads were contaminated with total petroleum hydrocarbons (TPH) released from the military army to the depth of approximately 2 m. The measured concentrations were as high as 15,277 mg/kg. A wide range of soil in the riverside highland was contaminated by the movement of oil to the surface soil, which occurred with the vertical movement of groundwater table caused by the change of river water level and groundwater level. Spilled petroleum oil components were released into Wonju Stream by the increase of hydraulic conductivity and the groundwater flow.

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국내 화산암 지역 지하수 중 자연방사성 물질에 대한 환경 특성 (Environmental Characteristics of Natural Radionuclides in Groundwaters in Volcanic Rock Areas: Korea)

  • 정도환;김문수;주병규;홍정기;김동수;김현구;김혜진;박선화;한진석;김태승
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제18권1호
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    • pp.36-45
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    • 2013
  • We analyzed natural radionuclides in 80 wells in volcanic rock areas and investigated environmental characteristics. Uranium and radon concentrations ranged from ND to $9.70{\mu}g/L$ (median value: 0.21) ${\mu}g/L$, 38~29,222 pCi/L (median value: 579), respectively. In case of gross-${\alpha}$, 26 samples exceeded MDA (minimum detectable activity, < 0.9 pCi/L) value and the activity values ranged from 1.05 to 8.06 pCi/L. The radionuclides concentrations did not exceed USEPA MCL (maximum contaminant level) value of Uranium ($30{\mu}g/L$) and gross-${\alpha}$ (15 pCi/L). But Rn concentrations in 4 samples exceeded USEPA AMCL (Alternative maximum contaminant level, 4,000 pci/L) and one of them showed a significantly higher value (29,222 pCi/L) than the others. The levels of uranium concentrations in volcanic rock aquifer regions were detected in order of andesite, miscellaneous volcanic rocks, rhyolite, basalt aquifer regions. Radon, however, was detected in order of miscellaneous volcanic rocks, rhyolite, andesite, basalt aquifer regions. The correlation coefficient between uranium and radon was r = 0.45, but we found that correlations of radionuclides with in-situ data or major ions were weak or no significant. The correlation coefficient between the depth of wells and uranium concentrations was a slightly higher than that of depth of wells and radons. Radionuclide concentrations in volcanic rock aquifers showed lower levels than those of other rock aquifers such as granite, metamorphic rock aquifers, etc. This result may imply difference of host rock's bearing-radioactive-mineral contents among rock types of aquifers.

수리지질 특성을 고려한 제주도 서부 해안지역 용천의 유형 분류 (Classification of Spring Types in the Western Coastal Area of Jeju Island, Korea, Based on the Hydrogeological Characteristics)

  • 고창성;고은희;박원배;고기원
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제28권5호
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    • pp.25-35
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    • 2023
  • This study aimed to classify spring types based on the hydrogeological characteristics of springs in Yongsu-ri~Hamo-ri coastal area in western part of Jeju Island. The springs in study area can be broadly categorized into three groups: perched groundwatrer springs (soil type), perched groundwater springs (sediment type), and basal groundwater springs. The perched groundwater springs of soil type correspond to springs where groundwater seeps out from the perched aquifer formed in the soil layer due to the development of clayey Kosan Formation beneath the surface. Because of the low hydraulic conductivity of soil layer, the average of spring discharge is less than 1 m3/day. The quality of spring water is significantly influenced by agricultural activities, resulting in high nitrate nitrogen concentrations and electrical conductivity. While the perched groundwater springs (sediment type) of the Suwolbong Tuff, which are located in the upper part of Kosan Formation, exhibited relatively higher discharge rates, their water quality was similar to soil-type springs. Basal groundwater springs are located in the zone of basal groundwater, mostly near the coastline. This type of spring appears to discharge of up to 3,707 m3, and the salinity content varies with the tidal fluctuations, especially increasing significantly during dry seasons.