• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.242-246
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• 2005

The heavy metal analysis (Cd, Pb, Cu, Cr, Zn, Ni) with various extraction methods was performed using the certified sample and real soil sample. In case of the certified samples, $10.5{\sim}118%$ of recovery was showed with various ranges depend on the metal kinds and extraction methods. Also, the alkali-digestion method was showed the proper results by applying in hexavalent chromium. In case of real sample, compared to amounts of heavy metals extracted using 0.1N-HCl, those extracted using acid digestion are higher by $3{\sim}24$ times in Cu, $1.1{\sim}1.5$ times in Cd, $2{\sim}23$ times in Pb, $3{\sim}104$ times in Zn, $12{\sim}101$ times in Ni, $30{\sim}202$ times in Cr. There is no considerable difference between four acid digestion methods.

• Journal of the Korean Chemical Society
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• v.38 no.6
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• pp.418-426
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• 1994

This study was aimed at the detection of 40 semi-volatile organic base/neutral compounds from soil among 129 priority pollutants listed by EPA. Two extraction procedures, sonication extraction and Soxhlet extraction, were studied as a extraction and concentration method for priority pollutants in soil. Extracts were analyted by GC/MS-SIM(selected ion monitoring). The analytical methods were tested by standard compounds spiked into blank soil. Accuracy and precision of the methods were measured by calculation of mean recovery and mean relative standard deviation. And the method detection limits were estimated.

• Korean Journal of Environmental Agriculture
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• v.23 no.4
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• pp.245-250
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• 2004

An analytical method was developed to determine monocrotophos residues in apple, citrus, and soil using high-performance liquid chromatography (HPLC) with ultraviolet absorption detection. Monocrotophos was extracted with acetone from apple, citrus and moist soil samples. The extract was concentrated, added with saline water, and subjected to n-hexane washing to remove nonpolar co-extractives. Dichloromethane partition was then followed to recover monocrotophos from the aqueous phase. Silica gel column chromatography was employed to further purify the extract prior to HPLC determination. Reverse-phase HPLC using an oct-adecylsilyl column was successfully applied to separate and quantitate the monocrotophos residue in sample extracts at the wavelength of 230 nm. Overall recoveries of monocrotophos from fortified samples averaged $95.3{\pm}2.1%$ (n=6), $970{\pm}0.7%$ (n=6), and $92.8{\pm}4.3%$ (n=12) for apple, citrus, and soil, respectively. The proposed method was quite reproducible and sensitive enough to replace the troublesome gas-liquid chromatographic analysis for monocrotophos residues.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 1999.10a
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• pp.83-90
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• 1999

This paper presents a method of seismic analysis for a cylindrical liquid storage structure on horizontally layered half-space considering the effects of the interior fluid and exterior soil medium in the frequency domain. the horizontal and rocking motions of the structures are included in this study. The fluid motion is expressed in terms of analytical velocity potential function which can be obtained by solving the boundary value problem including the sloshing behavior of the fluid as well as deformed configuration of the structure. The effect of the fluid is included in the equation of motion as the impulsive added mass and a frequency-dependent convective added mass along the nodes on the wetted boundary with structure. The soil medium is presented using the 3-D axisymmetric finite elements and dynamic infinite elements. The present method can be applied to the structures embedded in ground as well as on ground since it models the soil medium directly as well as the structure. For the purpose of vertification dynamci characteristics of a tank on homogeneous half-space is analyzed. Comparison of the present results with those by others shows good agreement.

• Structural Engineering and Mechanics
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• v.7 no.6
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• pp.533-550
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• 1999

Optimal design of raft-pile foundations is examined by combining finite element technique and the optimization approach. The piles and soil medium are modeled by three dimensional solid elements while the raft is modelled by shell elements. Drucker-Prager criterion is adopted for the soil medium while the raft and the piles are assumed to be linear elastic. For the optimization process, the approximate semi-analytical method is used for calculating constraint sensitivities and a constraint approximation method which is a combination of the extended Bi-point approximation and Lagrangian polynomial approximation is used for predicting the behaviour of the constraints. The objective function of the problem is the volume of materials of the foundation while the design variables are raft thickness, pile length and pile spacing. The generalized reduced gradient algorithm is chosen for solving the optimization process. It is demonstrated that the method proposed in this study is promising for obtaining optimal design of raft-pile foundations without carrying out a large number of analyses. The results are also compared with those obtained from the previous study in which linear analysis was carried out.

• Journal of Soil and Groundwater Environment
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• v.18 no.1
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• pp.112-122
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• 2013

Current status of soil contamination with fluorine and its source were investigated. The basic principles and procedures of various techniques for the analysis of fluorine contents in soil and solid phase samples were summarized in this review. Analysis of fluorine in solid matrices can be achieved by two types of techniques: (i) UV/Vis spectrophotometer or ion selective electrode (ISE) analysis after performing appropriate extraction steps and (ii) direct solid analysis. As the former cases, the standard method of Korean ministry of environment, alkali fusion-ISE method, pyrohydrolysis, oxygen bomb combustion, aqua regia digestion-automatic analysis, and sequential extraction-ISE method were introduced. In addition, direct analysis methods (i.e., X-ray fluorescence spectrometry and proton induced gamma-ray emission spectrometry) and atomic spectrometry combining with the equipment for introducing solid phase sample were also reviewed. Fluorine analysis techniques can be reasonably selected through site-specific information such as matrix condition, contamination level, the amount of samples and the principles of various methods for the analysis of fluorine presented in this review.

• Proceedings of the Korean Geotechical Society Conference
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• 2002.03a
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• pp.423-430
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• 2002

A feasibility of a trial test method was evaluated analytically, in which the elastic modulus of a soil deposit was tried to estimate by analyzing dynamic signals measured during conducting the SPT. If there existed a reliable relationship between the impedance ratio of a rod to a soil and the amplitude ratio of a reflected to an incident wave signal at the tip of steel rod contacting the soil surface, it was expected that one could determine the impedance of soil, and then roughly estimate the elastic modulus from the impedance. For a simple rod-soil system, the existence of the relevant relationship was verified in this study by analyzing computed wave signals propagating up and down through the rod. On the basis of these results, thus, a potential of the test method to practical applications could be seen. However, apparent theoretical shortcomings possessed in this approach were also realized since the soil part had an unconfined contact area where contacted with the rod. Therefore, it was concluded that further studies needed to be conducted, in which the reliable theoretical relationship between the impedance and the amplitude ratio as well as the effective contacting soil area contributing to wave reflection should be justified.

• Structural Engineering and Mechanics
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• v.78 no.4
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• pp.425-437
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• 2021

Under foundation shock mats have been used in the current practice in order to reduce/damp vibrations received by buildings through the surrounding environment. Although some investigations have been made on under foundation shock mats performance, their effectiveness in the reduction of railway induced-vibrations has not been fully studied, particularly with the consideration of underneath soil media. In this regard, this research is aimed at investigating performance of shock mat used beneath building foundation for reduction of railway induced-vibrations, taking into account soil-structure interaction. For this purpose, a 2D finite/infinite element model of a building and its surrounding soil media was developed. It includes an elastic soil media, a railway embankment, a shock mat, and the building. The model results were validated using an analytical solution reported in the literature. The performance of shock mats was examined by an extensive parametric analysis on the soil type, bedding modulus of shock mat and dominant excitation frequency. The results obtained indicated that although the shock mat can substantially reduce the building vibrations, its performance is significantly influenced by its underneath soil media. The softer the soil, the lower the shock mat efficiency. Also, as the train excitation frequency increases, a better performance of shock-mats is observed. A simplified model/method was developed for prediction of shock mat effectiveness in reduction of railway-induced vibrations, making use of the results obtained.

• Economic and Environmental Geology
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• v.40 no.5
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• pp.563-574
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• 2007

Laser induced breakdown spectroscopy (LIBS) is a recently developed analytical technique that is based upon the measurement of emission lines generated by atomic species close to the surface of the sample, thus allowing their chemical detection, identification and quantification. With powerful advantages of LIBS compared to the conventional analytical methodology, this technique can be applied in the detection of heavy metals in the field. LIBS allows the rapid analysis by avoiding laborious chemical steps. LES have already been applied for the determination of element concentration in a wide range of materials in the solid, liquid and gaseous phase with simplicity of the instrument and diversity of the analytical application. These feasibility of rapid multi elemental analysis are appealing proprieties for the in-situ analytical technique in geochemical investigation, exploration and environmental analysis. There remain still some limitations to be solved for LIBS to be applied in soil environment as an in-situ analytical technology. We would like to provide the basic principle related to the plasma formation and laser-induced breakdown of sample materials. In addition, the matrix effect, laser properties and the various factors affecting on the analytical signal of LIBS was dealt with to enhance understanding of LIBS through literature review. Ultimately, it was investigated the feasibility of LIBS application in soil environment monitoring by considering the basic idea to enhance the data quality of LIBS including the calibration method for the various effects on the analytical signal of LIBS.

• 한국환경농학회:학술대회논문집
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• 2011.07a
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• pp.177-187
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• 2011

This study was conducted to determine some physical and chemical properties of the soil and their relationship to spectroscopic-based (visible range) analytical methods while evaluating soil organic matter fractions and soil quality in degraded and non-degraded soils in a wide range of environments. Soil samples were collected from the different landscape positions of cultivated and noncultivated soils, and the latter from the same landscape positions but with different vegetation, at Songco, Lantapan, Bukidnon. The physical and chemical properties of the soils were determined at the SPAL, CMU, Musuan, Bukidnon while the metagenomic properties were determined at the Laboratory of the University of Missourri, Missourri, USA. Bulk density and air dry soil strength values of the soils from the cultivated areas were generally higher than those of the uncultivated areas. Also, soils at the summit generally had lower bulk density and soil strength values than the other landscape positions. Moreover, soils planted to camote (Ipomoea batatas) had higher bulk density and soil strength values compared to soils grown to pepper under the trees. Exchangeable calcium (Ca), magnesium (Mg), and potassium (K) and cation exchange capacity (CEC) of the soils were generally higher in uncultivated areas than those of the cultivated areas. A similar trend was observed for the potassium permanganate ($KMnO_4$)-oxidizable organic C contents determined by spectroscopic method and the total C contents determined by the Walkley-Black method. The $KMnO_4$-oxidizable organic C contents determined by spectroscopic method and the total C contents determined by the Walkley-Black method were closely related ($r=0.631^{**}$). Hence, the former method shows promise in assessing soil quality as it is a rapid test, relatively low cost and can be distributed as a field kit either with a portable spectrometer or with a color chart.