• Analytical Science and Technology
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• v.37 no.3
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• pp.174-188
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• 2024

This review summarized research trends regarding sample collection methods, pretreatment method, and types of analysis devices for microplastics (MPs) in soil and groundwater matrices. Soil sampling considers the selection of sampling location, depth, and volume. The typically sampling depth is within 15 cm (topsoil), and about 1 kg of mixed each sample. Among spot sampling and continuous flow sampling, groundwater sampling mainly used a continuous flow sampling, with collection rates 2 to 6 L/min in the range of 300~1,000 L, and followed by immediate on-situ filtration. Pretreatment method, applied to soil and groundwater, consist of organic digestion and density separation. In the organic digestion method, H₂O₂ is recommended among H₂O₂, acidic, alkaline, and enzymatic method. NaCl is primarily used as a reagent in density separation. However, depending on the density of MPs, other regents can be selectively used like ZnCl₂, ZnBr₂, and etc. Representative analysis device includes Fourier Transform Infrared (FTIR) and Raman spectroscopy for non-destructive analysis and Pyrolysis Gas Chromatography Mass Spectrometry (Py-GC/MS) for destructive analysis. µ-FTIR and Raman can count MPs of larger than 10 and 1 ㎛, and analyze MPs materials. However, it is need to sufficiently remove interference, like organic matter, in spectroscopic analysis using essential pretreatment method. Py-GC/MS is being continuously researched because it doesn't require complex pretreatment method and allows quantitative analysis of specific materials.

• Journal of the Korean Geotechnical Society
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• v.18 no.4
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• pp.167-177
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• 2002

A test method has been attempted to estimate the soil stiffness by measuring and analyzing dynamic signals of stress waves reflected at the bottom end of the SPT rod contacting a soil deposit. Before conducting a real size testing, a series of parametric studies were conducted in this paper to examine the applicability and the theoretical adequacy of the test method. As a result of these studies, it has been shown that the most significant influence factor affecting the amplitude ratio of the reflected wave to the incident wave at the rod-soil interface was the variation of soil stiffness. Also, the variation of the amplitude ratio was found to be closely related with the variation of impedance ratio of the soil deposit to the SPT rod. As a result, a potential of the test method could be proved to estimate the impedance and the elastic modulus of the soil deposit interfaced with the SPT rod using the test method.

• Applied Biological Chemistry
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• v.35 no.2
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• pp.115-121
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• 1992

Avermectin B1(abamectin) is an very effective acaricide/insecticide. Because it is applied at low rates, the resultant residue level would be quite low and this requires highly sensitive analytical method. In this study, three analytical methods for avermectin $B1_a$, were compared in view of detectability and sensitivity. The first analytical method was an HPLC method employing the fluorescence detection of avermectin. The second analytical technique to quantitate avermectin $B1_a$, and its photodegradative delta 8,9-isomer employed trifluoroacetic anhydride and 1-methylimidazole in DMF. The new method was the modification of trifluorescence method. The average recoveries of avermectin $B1_a$ for the concentration range from 1 and 10 ng/g in whole apple fruit by fluorescence method were 90.3% and 88.2% respectively. In trifluorescence method, the recoveries of the avermectin $B1_a$ and delta 8,9-isomer were 100.7% and 94.7% in concentration from 5 ng/g and 25 ng/g. The average recoveries of 5 ng and 25 ng/g in the newly modified method were 95.0, 99.0. 96.0, 92.8% in whole apple and soil respectively.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.19 no.3
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• pp.213-232
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• 2009

This document was prepared to review and summarize the analytical methods for airborne and bulk asbestos. Basic principles, shortcomings and advantages for asbestos analytical instruments using phase contrast microscopy(PCM), polarized light microscopy(PLM), X-ray diffractometer (XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM) were reviewed. Both PCM and PLM are principal instrument for airborne and bulk asbestos analysis, respectively. If needed, analytical electron microscopy is employed to confirm asbestos identification. PCM is used originally for workplace airborne asbestos fiber and its application has been expanded to measure airborne fiber. Shortcoming of PCM is that it cannot differentiate true asbestos from non asbestos fiber form and its low resolution limit ($0.2{\sim}0.25{\mu}m$). The measurement of airborne asbestos fiber can be performed by EPA's Asbestos Hazard Emergency Response Act (AHERA) method, World Health Organization (WHO) method, International Standard Organization (ISO) 10312 method, Japan's Environmental Asbestos Monitoring method, and Standard method of Indoor Air Quality of Korea. The measurement of airborne asbestos fiber in workplace can be performed by National Institute for Occupational Safety and Health (NIOSH) 7400 method, NIOSH 7402 method, Occupational Safety and Health Administration (OSHA) ID-160 method, UK's Health and Safety Executive(HSE) Methods for the determination of hazardous substances (MDHS) 39/4 method and Korea Occupational Safety and Health Agency (KOSHA) CODE-A-1-2004 method of Korea. To analyze the bulk asbestos, stereo microscope (SM) and PLM is required by EPA -600/R-93/116 method. Most bulk asbestos can be identified by SM and PLM but one limitation of PLM is that it can not see very thin fiber (i.e., < $0.25{\mu}m$). Bulk asbestos analytical methods, including EPA-600/M4-82-020, EPA-600/R-93/116, OSHA ID-191, Laboratory approval program of New York were reviewed. Also, analytical methods for asbestos in soil, dust, water were briefly discussed. Analytical electron microscope, a transmission electron microscope equipped with selected area electron diffraction (SAED) and energy dispersive X-ray analyser(EDXA), has been known to be better to identify asbestiform than scanning electron microscope(SEM). Though there is no standard SEM procedures, SEM is known to be more suitable to analyze long, thin fiber and more cost-effective. Field emission scanning electron microscope (FE-SEM) imaging protocol was developed to identify asbestos fiber. Although many asbestos analytical methods are available, there is no method that can be applied to all type of samples. In order to detect asbestos with confidence, all advantages and disadvantages of each instrument and method for given sample should be considered.

• Geomechanics and Engineering
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• v.35 no.4
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• pp.385-393
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• 2023

To analyze the consolidation with horizontal sand drains, the plane strain consolidation model under multi-ramp loading is established, and its corresponding analytical solution is derived by using the separation of variables method. The proposed solution is verified by the field measurement data and finite element results. Then, the effects of the loading mode and stress distribution on consolidation and dissipation of pore pressure are investigated. At the same time, the influence of hydraulic conductivity and thickness of sand blankets on soil consolidation are also analyzed. The results show that the loading mode has a significant effect on both the soil consolidation rate and generation-dissipation process of pore water pressure. In contrast, the influence of stress distribution on pore pressure dissipation is obvious, while its influence on soil consolidation rate is negligible. To guarantee the fully drained condition of the sand blanket, the ratio of hydraulic conductivity of the sand blanket to that of clay layer k_d/k_v should range from 1.0×10⁴ to 1.0×10⁶ with soil width varying from 100 m to 1000 m. A larger soil width correspondingly needs a greater value of kd/kv to make sure that the pore water can flow through the sand blanket smoothly with little resistance. When the soil width is relatively small (e.g., less than 100 m), the effect of thickness of the sand blanket on soil consolidation is insignificant. And its influence appears obvious gradually with the increase of the soil width.

• Analytical Science and Technology
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• v.21 no.5
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• pp.364-374
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• 2008

Antarctic Environmental Monitoring Handbook' was published by COMNAP/SCAR in 2000. The standardized method described in this handbook is recommended for monitoring of antarctic environment. High pressure bomb technique in this guide was used to decompose soil samples. In compliance with this guide book, high pressure bomb technique was applied to decompose the antarctic soil sampled at the King Sejong Station. An Isotope Dilution-Inductively Coupled Plasma-Mass Spectrometry (ID-ICP-MS) was applied to determine mass concentrations of Pb, Cu and Zn in the soil. The accuracy in this method was verified by the analysis of certified reference materials (CRM) of NIST 2702 (marine sediment). The analytical results agreed with certified value within the range from 99.5~100.8%. Matrix separation was necessitated for the determination of Cu and Zn by Chelex 100 ion exchange resin. As a result, the average mass concentrations of Pb, Cu and Zn which are suspected to be caused by anthropogenic pollution were 332.9 mg/kg, 95.6 mg/kg and 115.3 mg/kg, respectively. Those for the metals sampled in the soils of the remote regions from the station were 28.1 mg/kg, 101.8 mg/kg and 115.6 mg/kg, respectively.

• Journal of the Korean Society for Railway
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• v.14 no.1
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• pp.24-30
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• 2011

Conventional slope stability analysis is focused on calculating minimum factor of safety or maximum probability of failure. To minimize inherent uncertainty of soil properties and analytical model and to reflect various analytical models and its failure shape in slope stability analysis, slope stability analysis method considering simultaneous failure probability for multi failure mode was proposed. Linear programming recently introduced in system reliability analysis was used for calculation of simultaneous failure probability. System reliability analysis for various analytical models could be executed by this method. For application analysis for embankment, the results of this method shows that system stability of embankment calculate quantitatively.

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.1
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• pp.20-26
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• 1997

This paper examines the influences of mining activities on the concentrations of heavy metals in soils in the vicinity of the Dalsung Cu-W mine, Korea. Geochemical surveys were undertaken in the Dalsung mine area and sampling of surface and subsurface soils was carried out. Samples were prepared using 0.1 N HCI, HNO$_3$-HClO$_4$, and aqua regia, and analyzed for Cd, Cu, Pb and Zn by Atomic Absorption Spectrometry. In addition, soil samples were sequentially extracted to investigate the chemical speciation of heavy metals in soils. Heavy metals are highly contaminated in soils in the vicinity of mining area ranging up to 28 $\mu\textrm{g}$/g Cd, 5000 $\mu\textrm{g}$/g Cu, 2390 $\mu\textrm{g}$/g Pb and 930 $\mu\textrm{g}$/g Zn by the method using HNO$_3$-HClO$_4$. The pollution indices calculated with the permissible levels are up to 49 in surface and subsurface soils, which are considered sufficient to raise environmental problems. However, the heavy metal levels by the method using 0.1 N HCl are not higher than Korean standard for soil contamination. It suggests that analytical methods and soil standard should be re-examined. From the results of the sequential extraction methods for metal speciation, total Cu, Pb and Zn concentrations may be determined by analytical methods using HNO$_3$-HClO$_4$ or aqua regia, and exchangeable phase of those metals by the method using 0.1 N HCl.

• Proceedings of the KSRS Conference
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• v.2
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• pp.547-550
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• 2006

This study is to suggest a methodology to produce landslide hazard map by combining LRA (Logistic Regression Analysis) and AHP (Analytic Hierarchy Program) Approach. Topographic factors (slope, aspect, elevation), soil drain, soil depth and land use were adopted to classify landslide hazard areas. The method was applied to a 520 $km^2$ region located in the middle of South Korea which have occurred 39 landslides during 1999 and 2003. The suggested method showed 58.9 % matching rate for the real landslide sites comparing with the classified areas of high-risk landslide while LRA and AHP showed 46.1 % and 48.7 % matching rates respectively.

• Structural Engineering and Mechanics
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• v.40 no.2
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• pp.279-295
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• 2011

A solution of space curved bars with generalized Winkler soil found by means of Transfer Matrix Method is presented. Distributed, concentrated loads and imposed strains are applied to the beam as well as rigid or elastic boundaries are considered at the ends. The proposed approach gives the analytical and numerical exact solution for circular beams and rings, loaded in the plane or perpendicular to it. A well-approximated solution can be found for general space curved bars with complex geometry. Elastic foundation is characterized by six parameters of stiffness in different directions: three for rectilinear springs and three for rotational springs. The beam has axial, shear, bending and torsional stiffness. Numerical examples are given in order to solve practical cases of straight and curved foundations. The presented method can be applied to a wide range of problems, including the study of tanks, shells and complex foundation systems. The particular case of box girder distortion can also be studied through the beam on elastic foundation (BEF) analogy.