• Korean Journal of Environmental Agriculture
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• v.24 no.3
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• pp.238-244
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• 2005

Fertilization effects on changes in soil $CO_2$ flux and organic C in switchgrass (Panicum virgatum L.) land managed for biomass production were investigated. The mean daily soil $CO_2$ flux in the manure treatment was 5.63 g $CO_2-C\;m^{-2}\;d^{-1}$, and this was significantly higher than the mean value of 3.36 g $CO_2-C\;m^{-2}\;d^{-1}$ in the control. The mean daily $CO_2$ fluxes in N and P fertilizer treatments plots were not different when compared to the value in the control plots. Potentially mineralizable C (PMC), soil microbial biomass C (SMBC), and particulate organic C (POC) were highest at the 0 to 10 cm depth of the manure treatment. Potentially mineralizable C had the strongest correlation with SMBC (r = 0.91) and POC (r = 0.84). There was also a strong correlation between SMBC and POC (r = 0.90). Our results indicated that for the N and P levels studied, fertilization had no impact on temporal changes in soil organic C, but manure application had a significant impact on temporal changes in soil $CO_2$ evolution and active C constituents such as PMC, SMBC, and POC.

• Korean Journal of Agricultural and Forest Meteorology
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• v.5 no.2
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• pp.110-115
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• 2003

The iufluence of abandonment of agricultural fields on soil carbon and nitrogen dynamics is rarely addressed due to lack of appropriately paired sites. In this study, we identified three sites that have native forest and abandoned rice and crop fields at Mt. Kumdan near Seoul. Currently the vegetation of indigenous forest and the abandoned rice field is deciduous hardwood forest, while that of the abandoned crop field is deciduous shrub. We measured soil $CO_2$ evolution and inorganic N availability for the three sites from 25 July 2002 through 24 January 2003. Soil $CO_2$ evolution tracked seasonal soil temperature. Mean soil $CO_2$ evolution (g $CO_2$/$m^2$/hr) for the study period was 0.42 for the rice field to forest, 0.50 for the crop field to shrub, and 0.41 for the indigenous forest, respectively. Soil $CO_2$ evolution and soil temperature were not different among the sites; however, soil water content was significantly different. Soil water content had a very weak influence on soil $CO_2$ evolution. Inorganic resin N availability differed among the three sites and seemed to be related to soil moisture.

• The Korean Journal of Ecology
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• v.24 no.3
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• pp.141-147
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• 2001

Soil respiration and some environmental factors which affect soil respiration were studied in an oak forest, Kongju, Korea. Soil respiration was measured at midday of the 15th and 30th day at every month in control(Con), artificial forest gap (Gap) and litter removed area (Lr) with portable CO₂ Analyzer equipped soil respiration chamber. In July, maximum soil respiration in Con, Cap and Lr was 15.6, 11.2 and 7.7 CO₂μmol·m/sup -2/·s/sup -1/, respectively. Respiration in Gap and Lr decreased by 28.6% and 50.6%, respectively, compared with that in Con. Annual amount of soil CO₂ evolution from Con, Gap and Lr was 6.86, 5.84, 3.81 kg·m/sup -2/·yr/sup -1/, respectively. Annual amount of CO₂ evolution in Gap and Lr decreased by 14.8% and 44.5%, respectively, compared with that in Con. Soil respiration rates exponentially increased with temperature. Temperature of soil surface and at 5 cm depth was strongly related to soil respiration rates in Con (r₂＝0.87, 0.93), Gap (r₂=0.81, 0.88) and Lr (r/sub 2/=0.89).

• Journal of Life Science
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• v.20 no.9
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• pp.1353-1357
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• 2010

Quantification of the ecosystem respiration is essential in understanding the carbon cycling of natural and disturbed landscapes. Soil respiration and some environmental factors which affect soil respiration were investigated in a Larix leptolepis plantation inKongju, Korea. Soil respiration was measured at midday of the $15^{th}$ and $30^{th}$ day of every month from May to December in a non-cutting area (Control) and a cutting area (Treatment) with IRGA Soil Respiration Analyzer. Throughout the study period, average soil temperature and water content were $23.3{\pm}0.5^{\circ}C$ and $27.76{\pm}7.12%$ for control, and $25.9{\pm}3.1^{\circ}C$ and $24.55{\pm}5.12%$ for treatment, respectively. There was a positive correlation ($R^2$=0.8905) between soil respiration and soil temperature in the study area. However, there was no significant correlation between soil respiration and soil moisture ($R^2$=0.4437). The seasonal soil respiration increased in the summer and decreased in the winter. In August, maximum soil respirations in the control and treatment areas were $0.82{\pm}0.13$ and $1.32{\pm}0.10$ $gCO_2{\cdot}^{-2}{\cdot}r^{-1}$, respectively. Total amounts of $CO_2$ evolution in the control and treatment areas from May to December in 2008 were 2,419.2 and 3,610.8 $CO_2g{\cdot}m^{-2}$, respectively. The amount of soil respiration in the treatment area was 49.3% greater than in the control. Increased soil respiration in the treatment area may be due to increased soil temperature, which drives increased microbial decomposition. According to our present investigation, forest cutting will increase the atmospheric $CO_2$ by increasing soil respiration.

• Journal of Soil and Groundwater Environment
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• v.24 no.3
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• pp.24-35
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• 2019

It is known that ${\delta}^{13}C_{DIC}$ (carbon-13 isotope of dissolved inorganic carbonate (DIC) ions) of water increases when dissolved $CO_2$ degases. However, ${\delta}^{13}C_{DIC}$ could decrease when the pH of water is lower than 5.5 at the early stage of degassing. Laboratory experiments were performed to observe the changes of ${\delta}^{13}C_{DIC}$ as $CO_2$ degassed from three different artificial $CO_2$-rich waters (ACWs) in which the initial pH was 4.9, 5.4, and 6.4, respectively. The pH, alkalinity and ${\delta}^{13}C_{DIC}$ were measured until 240 hours after degassing began and those data were compared with kinetic isotope fractionation calculations. Furthermore, same experiment was conducted with the natural $CO_2$-rich water (pH 4.9) from Daepyeong, Sejong City. As a result of experiments, we could observe the decrease of DIC and increase of pH as the degassing progressed. ACW with an initial pH of 6.4, ${\delta}^{13}C_{DIC}$ kept increasing but, in cases where the initial pH was lower than 5.5, ${\delta}^{13}C_{DIC}$ decreased until 6 hours. After 6 hours ${\delta}^{13}C_{DIC}$ increased within all cases because the $CO_2$ degassing caused pH increase and subsequently the ratio of $HCO_3{^-}$ in solution. In the early stage of $CO_2$ degassing, the laboratory measurements were well matched with the calculations, but after about 48 hours, the experiment results were deviated from the calculations, probably due to the equilibrium interaction with the atmosphere and precipitation of carbonates. The result of this study may be not applicable to all natural environments because the pressure and $CO_2$ concentration in headspace of reaction vessels was not maintained constant as well as the temperature. Nevertheless, this study provides fundamental knowledge on the ${\delta}^{13}C_{DIC}$ evolution during $CO_2$ degassing, and therefore it can be utilized in the studies about carbonated water with low pH and the monitoring of geologic carbon sequestration.

• Applied Biological Chemistry
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• v.21 no.2
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• pp.71-80
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• 1978

In an attempt to elucidate the fate of 3,4-DCA and TCAB in various French soils, uniformly $^{14}C-ring-labeled$ 3,4-DCA and TCAB mere utilized and the following results obtained. 1) The rate of breakdown of $^{14}C-3,4-DCA$ into $^{14}CO_2$ was relatively higher in the early stage than that in the later stage. In 6 months of incubation in alkaline soil (pH 7.9), the rate was as high as 6.5% at dose 1 (1.5 ppm) and as low as 1.92% at dose 2(94 ppm), whereas in organic acid soil (pH 5.5) the rate was 4.91% at dose 1 and 4.24% at dose 2, respectively, without making any great difference between the two levels. 2) At dose 1, 47.70% of the initial radioactivity of $^{14}C-3,4-DCA$ was bound to soil in organic acid soil and 29.49% bound in alkaline soil, whereas at dose 2, 38.40% in organic acid soil and 20.30% in alkaline soil, respectively. 3) The amount of formation of $^{14}C-TCAB$ from $^{14}C-3,4-DCA$ seems to depend largely on the concentration of 3,4-DCA applied rather than on soil types. At dose 2, the amount was 50% of the total radioactivity extracted in organic acid soil and 30% in alkaline soil, corresponding to 1.8% and 1.4% of the initial radioactivity applied to soil, respectively. Cis-TCAB also seemed to be formed at dose 2 in both soils. Meanwhile, at dose 1, even though $^{14}C-TCAB$ was detected in trace on tlc and glc in both soils, the amount does not exceed 2 to 3% of the radioactivity extracted, corresponding to 0.05 to 0.1% of the initial radioactivity. 4) The rate of breakdown of $^{14}C-TCAB$ into $^{14}CO_2$ ranged from 0.05 to 0.20% in all the four soils. Most of the applied $^{14}C-TCAB$ remained intact after 3 months, not producing any detectable metabolites. 5) The fact that much more $^{14}C-TCAB$ was adsorbed to alkaline soil than to the other soils strongly indicates that in alkaline condition trans-isomer was converted tocisisomer which has the higher adsorption affinity than the former.

• Korean Journal of Environmental Agriculture
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• v.14 no.2
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• pp.202-212
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• 1995

In order to elucidate the degrading characteristics of the pyrethroid acaricide-insecticide, acrinathrin in two different types of soils, Soil A(pH, 5.8; organic matter, 3.4%; C.E.C., 115 mmol(+)/kg soil; texture, sandy loam) and Soil B(pH, 5.7; organic matter, 2.0%; C.E.C., 71 mmol(+)/kg soil; texture, sandy loam), residualities of the non-labeled compound under the field and laboratory conditions, extractability with organic solvents and formation of non-extractable bound residues, and degradabilities of [$^{14}C$]acrinathrin as a function of aging temperature and aging period were investigated. The half lives of acrinathrin in Soil A treated once and twice were about 18 and 22 days and in Soil B about 13 and 15 days, respectively, in the field, whereas, in the laboratory, those in Soil A and B were about 36 and 18 days, respectively, suggesting that the compound would be non-persistent in the environment. The amounts of $^{14}CO_2$ evolved from [$^{14}C$]acrinathrin in Soil A and B during the aging period of 24 weeks were 81 and 62%, respectively, of the originally applied $^{14}C$ activity, and those of the non-extractable soil-bound residues of [$^{14}C$]acrinathrin were about 70% of the total $^{14}C$ activity remaining in both soils, increasing gradually with the aging period. Degradation of [$^{14}C$]acrinathrin in both soils increased with the aging temperature. Three degradation products of m/z 198(3-phenoxy benzaldehyde), m/z 214(3-phenoxybenzoic acid), and m/z 228(methyl 3-phenoxybenzoate) as well as an unknown were detected by autoradiography of acetone extracts of both soils treated with [$^{14}C$]acrinathrin and aged for 15, 30, 60, 90, 120, and 150 days, respectively, and the degradation pattern of acrinathrin was identical in both soils. Acrinathrin in soil turned out to be degraded to 3-phenoxybenzaldehyde cyanohydrin by hydrolytic cleavage of the ester linkage adjacent to the $^{14}C$ with a cyano group, the removal of hydrogen cyanide therefrom led to the formation of 3-phenoxybenzaldehyde as one of the major products, and the subsequent oxidation of the aldehyde to 3-phenoxybenzoic acid, followed by decarboxylation would lead to the evolution of $^{14}CO_2$.

• Korean Journal of Soil Science and Fertilizer
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• v.25 no.1
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• pp.62-69
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• 1992

A series of laboratory experiment was conducted to find out the effects of physico-chemical, microbiological and commercial inhibitors on the odorous gas evolution in the fermentation of livestock feces. The results obtained were summarized as follows. 1. The rate and amount of evolution of gas were the highest at 7 days after incubation, thereafter gradually decreased until 24 days after incubation. 2. The rate and amount of gases were evolved in order of $CO_2>N_2O>CH_4>NH_3>N_2S$, respectively. 3. The highest amount of methane gas was evolved from the poultry feces, those of carbon dioxide and nitrous oxide were evolved from the pig feces, and that of hydrogen sulfide was dominantly evolved from the cattle feces. 4. Negative correlation were obtained between the total amounts of $NH_3$ and $CH_4$, $CO_2$ and $CH_4$, $N_2O$ and $CH_4$, $N_2O$ and $CH_4$, while positive correlations were obtained between the amounts of $CO_2$ and $N_2O$, $CO_2$ and $NH_3$, and $NH_3$ and $N_2O$, respectively. 5. There was no significantly inhibiting effect obtained that the application of commercial gas inhibitor as VK 88. On the other hand there was significantly inhibiting effect obtained when application of fertile paddy soil and photosynthetic bacteria to the fermentation of livestock feces.