• Title/Summary/Keyword: Softening effect

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Effect of the applied voltage of pulsed electric fields and temperature on the reduction of calcium ion concentration (고전압 펄스 전계의 인가전압과 온도가 수중 칼슘 농도 저감에 미치는 영향)

  • Kim, Jae-Hyun;Chang, In-Soung
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.2
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    • pp.95-101
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    • 2019
  • High voltage impulse(HVI) has been gained attention as an alternate technique controlling $CaCO_3$ scale formation. Investigation of key operational parameters for HVI is important, however, those had not been reported yet. In this study, the effect of temperature and applied voltage of HVI on $Ca^{2+}$ concentration was studied. As the applied voltage from 0 to 15kV and the temperature increased from 20 to $60^{\circ}C$, the $Ca^{2+}$ concentration decreased, indicating that the aqueous $Ca^{2+}$ precipitated to $CaCO_3$. The $Ca^{2+}$ concentration decreased up to 81% under the condition of 15kV and $60^{\circ}C$. Rate constant for the precipitation reaction, k was determined under different temper1ature and voltage. The reaction rate constant under the 15kV and $60^{\circ}C$ condition was evaluated to $66{\times}10^{-3}L/(mmol{\cdot}hr)$, which was 5 times greater than the k of the reaction without HVI at same temperature. The increases in k by HVI at higher temperature region(40 to $60^{\circ}C$) was much greater than at lower temperature region(20 to $40^{\circ}C$), which implies temperature is more important parameter than voltage for reducing $Ca^{2+}$ concentration at high temperature region. These results show that the HVI induction accelerates the precipitation to $CaCO_3$, particularly much faster at higher temperature.

Interaction between Light and other Factors Affecting Germination of Oenothera lamarckiana Ser. Seed. (큰달맞이꽃 종자발아(種子發芽)에 영향하는 요인(要因)과 광간(光間)의 상호작용(相互作用))

  • Kim, J.S.;Hwang, I.T.;Koo, S.J.;Cho, K.Y.
    • Korean Journal of Weed Science
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    • v.8 no.1
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    • pp.15-22
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    • 1988
  • In this experiment, interactions between light and other factors such as chilling, alternating temperature, moisture, content, oxygen, and seed coat which affect germination of Oenothera lamarckiana Ser. seed were investigated to study the physiological effects of light on the germination. Light induced the initial stage of seed germination before radical protrusion by affecting embryo rather than seed coat even under anaerobic condition or low water potential (-18 bars). This light effect on germinability of seed was suppressed by blue light irradiation and the effect was increased with increment of blue light intensity and irradiation time. However, the blue light effect was reversible. Chilling, alternating temperature, softening of seed coat and light showed promotive interaction in the induction of seed germination. Irradiation of filtered light (monochrome), however, reduced chilling effect on germination. Hydrogen-ion concentration and gibberellic acid treatment had no effect on light or dark germination.

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Quality Characteristics of Low-Salted Yacon Pickles with Leaf-mustard and Pepper (갓과 고추를 첨가한 저염 야콘 피클의 품질 특성)

  • Shim, Ki Hoon;Choi, Ok Ja
    • Korean Journal of Food Science and Technology
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    • v.44 no.5
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    • pp.545-552
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    • 2012
  • To improve a low-salted yacon pickle, the change of quality characteristics during the storage of yacon pickles were investigated at $18^{\circ}C$ for 50 days using two-way ANOVA. One factor that was added was the leaf-mustard and pepper (A), the other was storage time (B). The leaf-mustard and pepper were added to increase the yacon pickle's taste, flavor, and properties. The sugar content, total acidity and salinity were significant for factor A and B. With the interaction effect of the two factors, yacon pickles increased as storage time increased. The L value was not significant for factor A but significant for factor B. The a and b values were significant for the two factors. All Hunter's color value had the interaction effect. The shearing force was not significant for each factor, and yacon pickles did not show a softening effect. In the results of the sensory evaluation, color, taste, and overall preference were significant for factor A and B, yet the flavor was only significant for factor B. The texture was not significant at all. In the overall preference, yacon pickles were higher at 30 and 40 days and also, had the interaction effect. Yacon pickles were not above the 3.0% of salinity.

Microstructural Changes during Tempering Treatment of Nitrogen-permeated STS 410 and 410L Martensitic Stainless Steels (질소침투 열처리한 STS 410 및 410L 마르텐사이트계 스테인리스강의 템퍼링에 의한 조직변화)

  • Lee, Hea Joeng;Kong, Jung Hyun;Lee, Hae Woo;Yu, Dea Kyung;Kang, Chang Yong;Sung, Jang Hyun
    • Journal of the Korean Society for Heat Treatment
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    • v.20 no.2
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    • pp.84-93
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    • 2007
  • Microstructural changes during tempering at the temperature range of $300^{\circ}C{\sim}700^{\circ}C$ for the nitrogen-permeated STS 410 and 410L martensitic stainless steels has been investigated. After nitrogen permeation at temperature between 1050 and $1150^{\circ}C$, the surface layer appeared fine $Cr_2N$ of square and rod types in the martensite matrices. Hardness of the nitrogen-permeated surface layer represented 680Hv and 625Hv, respectively, for 410 and 410L steels. It is considered that the fine homogeneously dispersive effect of precipitates by nitrogen caused the increased hardness. Due to the counter current effect of carbon from interior to surface during nitrogen diffusion from surface to interior, the 0.1%C alloyed 410 steel showed the low nitrogen content of 0.025% compared with 0.045% of 410L steel at the distance of $100{\mu}m$ from the surface. Tempering of nitrogen-alloyed 410 and 410L showed the maximum hardness at $450^{\circ}C$. This maximum hardness was considered to be the secondary hardening effect of very fine carbide and nitride. The decrease in hardness at $700^{\circ}C$ was the softening effect of the matrix due to the precipitation of many needle-shaped $Cr_2N$ for 410 steel and the precipitation of coarse nitride of $Cr_2N$ in line with the spherical precipitates with directionality for 410L steel. For 410 steel, the corrosion resistance of nitrogen permeated surface in the solution of 1 N $H_2SO_4$ were nearly unchanged, however the superior corrosion resistance was obtained for nitrogen permeated 410L steel compared to the solution annealed condition.

Behavioral Characteristics of Decomposed Residual Solis (다짐 풍화잔적토의 거동특성 연구)

  • Lee, In-Mo;Lee, Seung-Cheol;Kim, Yong-Jin
    • Geotechnical Engineering
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    • v.12 no.6
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    • pp.115-126
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    • 1996
  • The purpose of 1,his study is to analyze the compression and strength charactefistics of the decomposed -weathered soil originating from biotite gneiss or fine grained gneiss sampled from Poidong, Seoul : to figure out the behavioural characteristics of the decomposed -weathered soil in accordance with mineral composition and origin by comparing experimental results of residual soils. originating from granites and sampled from Bulam, Andong and Kimchun area. A series of CIU, CID CKoV, CKoD tests were car lied out. Although weathered soils have different origin and mineral composition, the slope of the NCL A was similar. It was also shown that plastic strain ratio was about 85% mainly due to the particle crushing effect during compression. The Poidong soil showed strain softening phenomenon unlike the Kimchun and Andong soils. this implies that the behavioural characteristics are affected by the origin and the mineral composition of the soil particles. Moreover, it was found that the angle of the shear resistance$(\phi')$ was dependent on the mineral composition. On the oher hand, measured Af values of decomposed weathered soils were more than one regardless of the origin and the mineral composition.

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A Study on the Shear Behaviors of Geosynthetic-soil Interface in the Waste Landfill Site (폐기물 매립장 차수시설 접촉면 전단특성에 관한 연구)

  • Park, Inn-Joon;Kwak, Chang-Won;Park, Jum-Bum;Cho, Jun-Sik
    • Journal of the Korean Geotechnical Society
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    • v.28 no.3
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    • pp.45-54
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    • 2012
  • Various geosynthetics are widely applied to civil structures and waste landfill site for reinforcement and water resistance. The use of geosynthetics inevitably involves the coupled behaviors of different materials which include large displacement and strain-softening behaviors, etc. In this study, the effect of chemical element in the leachate on the interface shear strength under the cyclic loading condition was analyzed. The Multi-purpose Interface Apparatus (M-PIA) has been modified and cyclic direct shear tests have been performed. The submerging period of each specimen is 200 days. Additionally, the Field-Emission Scanning Electronic Microscopy (FIB) analysis has been also performed to induce the reason of the variation of disturbance function and verify the hypothesis on the decay-proof ability of geosynthetics. Consequently, the charateristics of chemical degradation of geosynthetic-soil interface are verified and the variation of the disturbance function is mainly caused by the different type of soil mineral decay, based on the FIB results.

Characteristics of Opal Glass by Calcium Phosphate Opacifier for a LED Light Diffuser (Calcium Phosphate 유백제 투입량에 따른 LED Diffuser용 유백유리의 특성)

  • Ku, Hyun-Woo;Lim, Tae-Young;Hwang, Jonghee;Kim, Jin-Ho;Lee, Mi-Jai;Shin, Dong Wook
    • Journal of the Korean Ceramic Society
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    • v.50 no.1
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    • pp.75-81
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    • 2013
  • We fabricated translucent opal glass to replace the polycarbonate diffuser in LED lighting systems in order to solve the durability problem. Batch materials of opal glass with a composition of calcium phosphate were created and melted at $1550^{\circ}C$, and the effect of opaqueness was identified by an addition of 1~7% calcium phosphate as an opacifier raw material. As a result, translucent opal glass was obtained by the melting of the mixed batch materials with a composition of more than 5% calcium phosphate glass at $1550^{\circ}C$ for 2 hrs, which had excellent optical properties for the diffuser of a LED lighting system with no dazzling from direct light by a high haze value exceeding 90% and a low parallel transmittance value of about 5%. For the thermal properties, the thermal expansion coefficient was found to be $5.6{\sim}5.9{\times}10^{-6}/^{\circ}C$ and the softening point was $874{\sim}884^{\circ}C$. In addition, good thermal properties such as good thermal shock resistance and feasibility for use with a general manufacturing process during the forming of glass tubes and bulbs were noted. Therefore, it is concluded that this translucent opal glass can be used as a glass diffuser material for LED lighting due to its high heat resistance and high durability as a replacement for a polycarbonate diffuser.

The Effect of Pretreatment(Q/T) on the Plasma Nitriding of SCM435 Structural Steel (SCM435 구조용 합금강의 플라즈마 질화에 미치는 전처리(Q/T)의 영향)

  • Lim, Young-Phil;Park, Dae-Chul;Lee, Jae-Sig;You, Yong-Zoo
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.2
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    • pp.99-110
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    • 1998
  • The effects of pre-heat treatment(Q/T) on microstructure and hardness of SCM435 structural steel nitrided by micro-pulse plasma was investigated. The quenching and tempering temperatures for obtaining matrix hardness of SCM435 steel on range of HRC30 to HRC40 desired for machine parts were about $860^{\circ}C$ and $500^{\circ}C$ respectively. The case depth of SCM435 nitrided at $480^{\circ}C$ for 5 hours was independent of pre-heat treatment condition and was approximately $150{\mu}m$. However, hardness and compactness of nitrified layer on Q/T treated specimen were more heigher than annealed specimen. The case depth increased linearly with the increase of nitriding temperature, however, the hardness of nitrified layer decreased with the temperature. Phase mixture of ${\gamma}^{\prime}$-phase($Fe_4N$) and ${\varepsilon}$-phase($Fe_3N$) were detected by XRD analysis in the nitrified layer formed at optimum nitriding condition, and only single ${\gamma}^{\prime}$-phase was detected in the nitrified layer formed at higher nitriding temperature such as $540^{\circ}C$. The optimum nitriding temperature was approximately $480^{\circ}C$ which is lower than tempering temperature for preventing softening behavior of SCM435 matrix during nitriding process and the surface hardness of nitrified layer obtained by optimum preheat treatment condition was about Hv930.

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The Effect of Pre-Heat Treatment Parameters on the Ion Nitriding of Tool Steel (금형공구강의 이온질화에 미치는 이전열처리 조건의 영향)

  • Lee, J.S.;Kim, H.G.;You, Y.Z.
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.1
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    • pp.27-34
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    • 2001
  • The effects of pre-heat treatment(Q/T) on microstructure and hardness of STD11 and STD61 tool steel nitrided by micro-pulse plasma were investigated. The quenching temperature for obtaining matrix hardness of STD11 and STD61 steel on range of HRC 50 to HRC 60 desired for machine parts is about $1070^{\circ}C$ and $1020^{\circ}C$ respectively. The hardness of STD11 and STD61 quenched at the temperature was HRC 63 and HRC 56 respectively. The nitrided case depth of STD11 and STD61 nitrided at $550^{\circ}C$ for 5 hours was independent of pre-heat treatment condition and the depth was approximately $100{\mu}m$. However, hardness and compactness of nitrided layer on Q/T treated specimen were higher than the annealed specimen. The case depth increased linearly with the increase of nitriding temperature, however, the hardness of nitrided layer decreased with the increase of temperature. Phase mixture of ${\gamma}-Fe_4N$ and ${\varepsilon}-Fe_{2-3}N$ was detected by XRD analysis in the nitrided layer formed at the optimum nitriding condition. The optimum nitriding temperature was approximately $490^{\circ}C$ which was $10^{\circ}C$ lower than the tempering temperature for preventing softening behavior of STD11 and STD61 matrix during nitriding process and the surface hardness of nitrided layer obtained by optimum pre-heat treatment condition was about Hv1400.

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Development and Characterization of Translucent Opal Glass for Diffuser of LED Lighting (LED 조명용 반투명 유백유리 Diffuser 조성 개발 및 특성)

  • Ku, Hyun-Woo;Lim, Tae-Young;Hwang, Jonghee;Kim, Jin-Ho;Lee, Mi-Jai;Shin, Dong Wook
    • Korean Journal of Materials Research
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    • v.22 no.12
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    • pp.650-657
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    • 2012
  • For the purpose of improving the durability problem, translucent opal glass was fabricated as a substitute for the polycarbonate diffuser of LED lighting. Calcium phosphate was used as an opacifier of opal glass and melted in an electric furnace. The opaque effect was identified according to the change of the cooling procedure. As results, translucent opal glass was obtained by the melting of a batch with a composition of 3.8% calcium phosphate at $1550^{\circ}C$ for 2 hrs and then the cooling of the material in the furnace. For the cooling condition of the glass sample, HTCG (High Temperature Cooled Glass) was found to have better optical properties than LTAG (Low Temperature Annealed Glass). It had excellent optical properties for a diffuser of LED lighting, with no dazzling from direct light due to its high haze value of over 99% and low parallel transmittance value of under 1%. For the thermal properties, it had an expressed thermal expansion coefficient of $5.7{\times}10^{-6}/^{\circ}C$ and a softening point of $876^{\circ}C$; it also had good thermal properties such as good thermal shock resistance and was easy to apply to the general manufacturing process in the forming of glass tubes and bulbs. Therefore, it is concluded that this translucent opal glass can be used as a glass diffuser material for LED lighting with high heat resistance and high durability; this material is suitable as a substitute for polycarbonate diffusers.