• 제목/요약/키워드: Sofc

검색결과 659건 처리시간 0.025초

SOFC 밀봉재로서 $SiO_2-R_2O_3-RO$계에서 $R_2O_3$, RO 변화 따른 특성 (Characterization with Change of $R_2O_3$, RO in $SiO_2-R_2O_3-RO$ System for SOFC Sealnat)

  • 양상진;최병현;이미재;지미정;이홍림;유영성
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.8-11
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    • 2007
  • SOFC 스택 밀봉재로서 $SiO_2-R_2O_3$계를 선정하여 $R_2O_3$와 RO를 변화 하였을 때 유리 전이 온도, 열팽창계수, 이종 물질간의 젖음성, 환원 가스에 반응성 등을 조사하였다. 또한 모유리에 filler를 넣었을 때 filler 첨가에 따른 특성을 조사한 결과 $B_2O_3/SiO_2$ 함량비 증가에 따라 열팽창계수는 증가하였고 전이점은 낮아졌으며 밀봉재를 이용한 SUS 와 SUS를 $800^{\circ}C$ 접합 후 산화 ${\cdot}$ 환원분위기에서 작동했을 때. 화학적 반응 및 확산 반응층은 관찰되지 않았다.

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SOFC 용 LSCF/CGO 공기극의 제조 및 특성연구 (Synthesis and Characterization of LSCF/CGO Composite Used as SOFC Cathode Materials)

  • 박재량;임탁형;이승복;박석주;신동렬;송락현
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.184-186
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    • 2009
  • Composites of LSCF($La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-\delta}$ and CGO(gadolinium doped ceria) is an efficient candidate cathode material with CGO electrolytes. In this study, LSCF with exact perovskite structure was synthesized by using solid state reaction(SSR) method. The optimized temperature to synthesize $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-\delta}$ with rhombohedral structure. was $1100^{\circ}C$. The polarization resistance of the LSCF/CGO(50:50 wt.%) was smaller than those of other composite cathodes. The analysis of the EIS data of LSCF/CGO suggests that the diffusion and adsorption-desorption of oxygen can be the key process in the cathodic reaction of SOFC using LSCF/CGO as cathode material.

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TMS320C40를 이용한 이중아암 로봇의 퍼지제어 시스템 설계 (Design of Fuzzy Control System for Dual-Arm robot Based-on TMS320C40)

  • 김종수;정동연;한성현
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2002년도 추계학술대회 논문집
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    • pp.241-249
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    • 2002
  • In this paper, a self-organizing fuzzy controller(SOFC) for the industrial robot manipulator with a actuator located at the base is studied. A fuzzy login composed of linguistic conditional statements is employed by defining the relations of input-output variable of the controller, In the synthesis of a FLC, one of the most difficult problems is the determination of linguistic control rules from the human operators. To overcome this difficult SOFC is proposed for a hierarchical control structure consisting of basic level and high level that modify control rules. The proposed SOFC scheme is simple in structure, fast in computation, and suitable for implementation of real-time control. Performance of the SOFC is illustrated by simulation and experimental results for robot with tow joints.

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A Novel Metal Supported SOFC Fabrication Method Developed in KAIST: a Sinter-Joining Method

  • Bae, Joongmyeon
    • 한국세라믹학회지
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    • 제53권5호
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    • pp.478-482
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    • 2016
  • Metal-supported SOFCs have been investigated to overcome the disadvantages of ceramic-supported SOFCs, including issues related to mechanical strength and sealing. In the case of ceramic-supported cells, the mechanical support is a brittle ceramic or cermet, and it contains expensive materials. However, metal-supported cells utilize ceramic layers that are only as thick as necessary for electrochemical functioning, thereby compensating for the disadvantages of ceramic-supported cells. The mechanical support is fabricated from inexpensive and robust metals, and the electrochemically active layers are applied directly to the metal support. The metal-supported SOFCs thus can provide a reduced system cost, ease of manufacturing, and operational advantages. Owing to these features, metal-supported SOFCs are a very promising candidate for commercialization. Given the importance of studying worldwide trends in metal-supported SOFC research for performance evaluation, this paper reviews development trends with a focus on fabrication methods. Furthermore, a novel fabrication method developed in KAIST is discussed.

연료전지 시스템을 위한 헤머스테인-위너 모델기반의 모델예측제어 (Hammerstein-Wiener Model based Model Predictive Control for Fuel Cell Systems)

  • 이상문
    • 전기학회논문지
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    • 제60권2호
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    • pp.383-388
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    • 2011
  • In this paper, we consider Hammerstein-Wiener nonlinear model for solid oxide fuel cell (SOFC). A nonlinear model predictive control (MPC) is proposed to trace the constant stack terminal power by Hydrogen flow as control input. After the stability of the closed-loop system with static output feedback controller is analysed by Lyapunov method, a nonlinear model predictive control based on the Hammerstein-Wiener model is developed to control the stack terminal power of the SOFC system. Simulation results verify the effectiveness of the proposed control method based on the Hammerstein-Wiener model for SOFC system.

Joining of Lanthanum Chromite and Yttria Stabilized Zirconia in Sealing of Planar Solid Oxide Fuel Cell

  • Lee, You-Kee;Park, Jong-Wan
    • 한국재료학회지
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    • 제4권7호
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    • pp.741-749
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    • 1994
  • The planar solid oxide fuel cell(SOFC) contains several ceramic materials depending on its structure and has rdfractory metal parts for manifolds, shrouds and current leads. Among ceramic materials for planar SOFC, joining of lanthanum chromite separator and yttria stabilized zirconia(YSZ) electoyte in planar SOFC stack to give strong gas tight seals is necessary for satisfactory operation and high performance. Nevertheless, for planar SOFC/sub s/, how to seal the cell stack and gas manifold remains as one of the unsolved problems. Therefore, in this study. we investigated the joining of sintered lanthanum chromite and YSZ pellets using unsintered lanthanum chromite green films as sealent. Scanning electron microscopy(SEM) and energy dispersive X-ray analysis(EDX) revealed that Ca in the sealing material diffused and dissolved into YSZ and sintered lanthanum chromite, and unsintered lanthanum chromite green films reacted with YSZ to from a new phase at the interface. Also, the densification of unsintered lanthanum chromite green films was inpeded by the Ca migration.

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갑작스런 부하 변동에 따른 고체산화물 연료전지의 동적 성능 거동 특성에 관한 연구 (A Study on the Dynamic Performance Behavior of Solid Oxide Fuel Cells with Stepwise Load Changes)

  • 손정락;노승탁;양진식
    • 대한기계학회논문집B
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    • 제29권4호
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    • pp.477-484
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    • 2005
  • Model fer the dynamic simulation of dynamic behaviors of a solid oxide fuel cell (SOFC) is provided. This model is based upon (1) coupled mass and heat transfer characteristics and (2) important chemical reactions such as electrochemical and reforming reactions in high temperature fuel cells such as SOFC. It is found that the thermal inertia of solid materials in SOFC plays an important role to the dynamic behavior of cell temperature. Dynamic characteristics of cell voltage, power, and chemical compositions with different levels of load change are investigated.