• Title/Summary/Keyword: Sodium-water

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Flotation-Concentration of Trace Phosphate Ion in Water Samples by $La(OH)_3$ Coprecipitation ($La(OH)_3$ 공침에 의한 물시료 중 흔적량 인산이온의 부선 농축)

  • Kim, Young-Sang;Park, Sang-Wan;Choi, Hee-Seon
    • Analytical Science and Technology
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    • v.5 no.4
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    • pp.425-431
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    • 1992
  • The concentration and determination of trace phosphate ion was studied by $La(OH)_3$ coprecipitaiton. Phosphate ions in 1.0L samples were coprecipitated with lanthanium hydroxide at pH 9.5 adjusted with ammonia solution. The precipitates were floated with the aid of mixed surfactant(1:8 sodium oleate/sodium dodecyl sulfate) and nitrogen gas bubbles. The floated precipitate was collected in suction flask from the solution. The precipitate were washed with dil. ammonia solution and dissolved in sulfuric acid. The phosphate ion in the concentrated solution was finally determinated by UV/VIS spectrophotometry using the molybdenium blue method. The proposed method could be applied to the determination of phosphate ion in tap water and river water.

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Inverse Emulsion Polymerization of Water Absorbent Polymer for Strength Enhancement of Mortars (모르타르 강도 증진을 위한 고분자 흡수제의 역유화 중합)

  • Hwang, Ki-Seob;Jung, Myoung-Geun;Jang, Seok-Soo;Jung, Yong-Wook;Lee, Seung-Han;Ha, Ki-Ryong
    • Polymer(Korea)
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    • v.34 no.5
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    • pp.434-441
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    • 2010
  • Sodium polyacrylate (PAANa) was synthesized by inverse emulsion polymerization method to absorb excess water in concrete. Liquid paraffin was used as a continuous phase. Acrylic acid (AA) was neutralized by aqueous sodium hydroxide solution (8 M). Different amount of N,N'-methylene bisacrylamide (MBA) was used as a crosslinking agent to change crosslinking density of the synthesized PAANa. The size distribution of synthesized particles was measured by particle size analyzer. Swelling ratio of crosslinked PAANa was evaluated from the equation in D. I. water, cement aqueous solution, and $Ca(OH)_2$ aqueous solution. The FTIR spectroscopy was used to characterize $Ca^{2+}$ ion interaction with PAANa. Incorporation of 1.0 wt% PAANa into cement increased compressive and flexural strength approximately 30% and 10%, respectively, compared with those of ordinary portland cement.

Study on the Gelling Formation and Anti-gelling Properties of Liquid Detergent Based on Sodium Lauryl Ethoxy Sulfate (SLES) (소듐 라우릴 에톡시 설페이트(SLES) 베이스 액체세정제의 겔링성 및 겔링방지 특성에 대한 연구)

  • Chi, Gyeong-Yup
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.620-625
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    • 2018
  • Liquid detergent based on sodium lauryl ethoxy sulfate (SLES) as main ingredient sometimes met gelling film on the surface when it is opened in the air. It was assumed because of the change of phase diagram of micelle by concentration change of surfactant, major ingredient of detergent when the water of detergent is evaporated. SLES showed strong hexagonal liquid crystal (LC) in 30~60 wt%, and lamellar LC over 60 wt%. In this research surface gelling formation of liquid detergent which is based on SLES as main ingredient was because of water evaporation. As water of detergent was evaporated, concentration of surfactant became higher. It was checked that surface gelling was LC of mixed surfactant system. Conclusionally we applied alpha olefin sulfonate (AOS) having good solubility, Sodium secondary alkane sulfonate (SAS) preventing hexagonal LC and hydrotrope sodium xylene sulfonate (SXS) and PEG1500 in order to prevent gelling film in SLES based liquid detergent. Like this, improved formula 4 and 5 can prevent the formation of gelling film on the surface of liquid detergent when it is opened in the air.

Color Developing Capacity of Plasma-treated Water as a Source of Nitrite for Meat Curing

  • Jung, Samooel;Kim, Hyun Joo;Park, Sanghoo;Yong, Hae In;Choe, Jun Ho;Jeon, Hee-Joon;Choe, Wonho;Jo, Cheorun
    • Food Science of Animal Resources
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    • v.35 no.5
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    • pp.703-706
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    • 2015
  • The interaction of plasma with liquid generates nitrogen species including nitrite (NO2). Therefore, the color developing capacity of plasma-treated water (PTW) as a nitrite source for meat curing was investigated in this study. PTW, which is generated by surface dielectric barrier discharge in air, and the increase of plasma treatment time resulted in increase of nitrite concentration in PTW. The PTW used in this study contains 46 ppm nitrite after plasma treatment for 30 min. To evaluate the effect of PTW on the cured meat color, meat batters were prepared under three different conditions (control, non-cured meat batter; PTW, meat batter cured with PTW; Sodium nitrite, meat batter cured with sodium nitrite). The meat batters were vacuum-packaged and cooked in a water-bath at 80℃ for 30 min. The typical color of cured meat developed in cooked meat batter treated with sodium nitrite or PTW. The lightness (L*) and yellowness (b*) values were similar in all conditions, whereas, the redness (a*) values of cooked meat batter with PTW and sodium nitrite (p<0.05) were significantly higher than the control. These data indicate that PTW can be used as a nitrite source in the curing process of meat without addition of other nitrite sources.

Studies on the Fouling Reduction through Oxyfluorination of Porous Polyethylene Membranes (함산소불소화법을 통한 다공성 폴리에틸렌막의 파울링현상 감소연구)

  • Kang, Su Yeon;Rhim, Ji Won;Cheong, Seong Ihl
    • Membrane Journal
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    • v.24 no.6
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    • pp.431-437
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    • 2014
  • To overcome the flux reduction due to the fouling by adsorption of foulants onto the porous hydrophobic polyethylene membrane surface, the oxyflorination was introduced to hydrophilize the hydrophobic membranes. After the hydrophilization through oxyfluorination, the contact angle decreased from $93^{\circ}$ to $50^{\circ}$ while the water flux increased to 60%. It was considered that for the model foulants dissolved in water, such as albumin (form bovine serum, BSA), humic acid sodium salt (HA), and alginic acid sodium salt (SA), the flux was enhanced since the adsorbed foulants decreased by the oxyfluorination. Particularly, it was obtained that the water flux was over twice more than the untreated polyethylene membrane in case of SA foulant.

A simple and effective method for addition silicone impression disinfection

  • Azevedo, Maria Joao;Correia, Ines;Portela, Ana;Sampaio-Maia, Benedita
    • The Journal of Advanced Prosthodontics
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    • v.11 no.3
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    • pp.155-161
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    • 2019
  • PURPOSE. Although dental impression disinfection is determinant to reduce the cross-infection risk, some studies have shown that, in real practice, the disinfection procedures vary considerably. Thus, the aim of this study was to evaluate the antimicrobial effectiveness and the impact on the dimensional stability of addition silicone' impressions of water wash and the most clinically used disinfection solutions: 3% hydrogen peroxide, commercial disinfectant MD520 (Durr) and 1% and 5.25% sodium hypochlorite. MATERIALS AND METHODS. For this investigation, dental impressions were taken on 16 volunteer dental students. The antimicrobial effectiveness of each procedure was evaluated by pour plate method. The dimensional stability was evaluated using a standardized stainless-steel model, according to ANSI/ADA nº19 specification. RESULTS. The study results showed that water wash does not alter the dimensional stability of addition silicone impressions but doesn't reduce the microbial load of the material (P>.05). On the other hand, addition silicone disinfection by immersion with 3% hydrogen peroxide, MD520 (Durr), or sodium hypochlorite at 1% and 5.25% does not alter the dimensional stability significantly but reduces > 99.9% of the microbial load of the impressions (P<.001). CONCLUSION. Addition silicone impressions should always be disinfected after water wash in order to reduce effectively the cross-infection risk. All disinfectants tested showed high antimicrobial efficiency without significant changes in three-dimensional shape of impressions. Hydrogen peroxide and sodium hypochlorite are of particular importance because are easily accessible in dental setting. The less explored hydrogen peroxide could be a valuable alternative for silicone impressions disinfection.

Studies on the Photographic Emulsion Manufacture for Color Paper and Hardening Test (천연색 인화지용 사진유제 제조와 경막 시험에 관한 연구)

  • Kim, Yeoung-Chan
    • The Journal of Information Technology
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    • v.8 no.4
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    • pp.43-50
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    • 2005
  • In this paper, we describe a study on the relationship between photographic emulsion manufacture and hardening test of color paper. The hardener was prepared by the reaction of cyanuric chloride with sodium hydroxide, disodium hydrogenphosphate-12-water and trisodium phosphate-12-water in the presence of water. The hardener used in this study is a 2,4-dichloro-6-hydroxy-1,3,5-triazine mono sodium salt. The hardening test of photographic emulsion was studied respectively at pH 5.5, 7, 8.5 and about increasing temperature. Novel hardener can be used in photo-graphic emulsion of color paper and showed very good hardening effect.

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A Green Protocol for the Bromination and Iodination of the Aromatic Compounds using H5IO6/NaBr and H5IO6/NaI in the Water

  • Yousefi-Seyf, Jaber;Tajeian, Kazem;Kolvari, Eskandar;Koukabi, Nadiya;Khazaei, Ardeshir;Zolfigol, Mohammad Ali
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2619-2622
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    • 2012
  • Bromination and iodination of the aromatic compounds have efficiently been carried out at room temperature and $70^{\circ}C$, respectively, in short reaction times using orthoperiodic acid/sodium bromide (1:2) and orthoperiodic acid/sodium iodide (1:2) in water to prepare the corresponding halo compounds with excellent yields.

Effects of Salts on the Hydration of $\alpha$-Calcium Sulfate Hemihydrate ($\alpha$형 반수석고의 수화에 미치는 염류의 영향)

  • 최상흘;이구종;홍성윤;이석곤
    • Journal of the Korean Ceramic Society
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    • v.25 no.5
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    • pp.449-454
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    • 1988
  • The effects of salts which was used as a catalysis in formation of $\alpha$-calciumusulfate hemihydrate from dicalcium sulfate hydrate were investigated on the hydration of $\alpha$-calciumsulfate hemihydrate. The hydration of $\alpha$-calciumsulfate hemihydrate was studied by the measurements of crystalline water, heat evolution. Also the hydrates were analyzed by XRD, DSC and SEM. The promotive effect each salts on the hydration was as follows: NaCl>NH4Cl>NaNO3>NH4NO3, and the hydration rate was accelerated with concentration of salts. The effect of Al2(SO4)3 and potassium sodium tartrate on the hydration was slmilar to water, whereas sodium succinate and gelatin retarded the hydration in comparision with water. These salts affected the hydration time but total heat evoution was similar.

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Advantages of Acoustic Leak Detection System Development for KALIMER Steam Generators

  • Kim, Tae-Joon;Valery S. Yughay;Hwang, Sung-Tai;Chai, Jeong-Kyung;Choi, Jong-Hyeun
    • Nuclear Engineering and Technology
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    • v.33 no.4
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    • pp.423-440
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    • 2001
  • For sodium cooling liquid metal reactors during the last 25 years, it was most important to verify the safety of the steam generator, which absolutely requires a water leak detection system with fine sensitivity and response. This study describes the structure and leak classification of the HAMMER (Korea Advanced Liquid Metal Reactor) steam generator, compared with other classifications, and explains the effects of leak development. The requirements and experimental situations for the development of the KALIMER acoustic leak detection system (KADS) which detects micro leaks, not intermediate leaks, are introduced. We proposed four frequency bands, 1∼8kHz, 8∼20kHz, 20∼40kHz and 40∼200kHz, split effectively for analyzing the detected acoustic leak signals obtained from the sodium-water reaction model or water model in the mock-up system.

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