• Title/Summary/Keyword: Sodium-water

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The Effect of Sodium Lactate and Sodium Chloride on Water Activity of Water-Sorbitol System (Water-Sorbitol System의 수분활성도에 미치는 Sodium Lactate 및 Sodium Chloride의 영향)

  • Park, Jang-Woo;Rhee, Chul
    • Korean Journal of Food Science and Technology
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    • v.23 no.3
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    • pp.330-335
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    • 1991
  • The values of water activity in the different concentrations of NaCl and sodium lactate were measured by hygrometer in the water-sorbitol systems. Interaction of NaCl and sodium lactate was evaluated by Raoult's law. The discrepancy between experimental and theoretical value by the Raoult's law was defined as interaction between water-sorbitol and added solutes in the systems. The changes of interacted water and solutes were observed in whole range of water activity. The value of interacted water (water: sorbitol=1 : 1.1241) obtained by added sodium lactate was found to be higher than sodium chloride. The amount of interacted solute reached maximum about Aw 0.87, while the interactions between added solute and sorbitol showed an increasing tendency below Aw 0.87.

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Noise Generation by Water-Sodium Reaction and its Absorption on Hydrogen Bubbles for KALIMER Steam Generator (칼리머 증기발생기에서 물-소듐 반응에 의한 소음 발생과 수소 기포의 소음 흡수)

  • Kim, Tae-Joon;Yughay, Valeri S.;Hwang, Sung-Tai
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.1829-1835
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    • 2000
  • The experimental results of sodium-water reaction noise measurement in frequency range $1{/sim}200kHz$ are presented. The experiments of noise generation under the condition of sodium test facility, water leak rate $0.01{\sim}1.2g/s$ and temperature of sodium $250{\sim}500^{\circ}C$, were carried out. From theoretical study it is noted that the noise resonant attenuation on hydrogen bubbles in liquid sodium plays the significant role for leak noise spectra formation. Interaction of leak noise and hydrogen bubbles in sodium being accompanied by thermal, emission and viscosity energy dissipation was studied. Acoustic noise spectra were investigated from point of view of water leak detection in sodium/water steam generator. The results of sodium-water reaction noise absorption on hydrogen bubbles in liquid sodium by temperature $250{\sim}500^{\circ}C$ are presented. The theoretical model of noise absorption using the coefficients of attenuation was developed. From calculation the coefficients of attenuation were estimated.

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Design and Evaluation of Biphenyl Dimethyl Dicarboxylate Injections (비페닐디메칠디카르복실레이트 주사제의 설계 및 평가)

  • 김혜진;전인구
    • YAKHAK HOEJI
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    • v.44 no.3
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    • pp.263-271
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    • 2000
  • In an attempt to develop an injectable form of practically insoluble biphenyl dimethyl dicarboxylate (DDB), the effect of various vehicles, cosolvents and hydrotropic agents was investigated. It was found that polyethylene glycol (PEG) 400 revealed the best solvency toward DDB (17.7 mg/ml at $37^{\circ}C$), and decreasing order of the solubility was as follows: PEG 400>PEG 300>diethylene glycol monoethyl ether (DGME)>PEG-8 glyceryl caprylate/caprate. Among the hydrotropes used, sodium salicylate, sodium benzoate and nicotinamide were effective in increasing the solubility in water. The solubility of DDB in 2 M sodium salicylate, sodium benzoate and nicotinamide solutions was increased 44.3, 23.5 and 44.0 times than that in water, respectively. The addition of sodium salicylate and sodium benzoate to PEG 300-water PEG 400-water and DGME-water cosolvents remarkably increased the solubility of DDB, and significantly retarded precipitate formation when mixed with water Hemolytic properties of DDB injections (2 mg/4~10 ml) in PEG 300-water or DGME-water (60:40 v/v) cosolvents containing sodium benzoate (0.14~0.35 M) were very low. It was concluded from the results that these solutions would be applied to the design of new DDB injections.

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Investigation on Performance Analysis of Sodium-Water Reaction Pressure Relief System of Prototype Generation-IV Sodium-Cooled Fast Reactor (소듐냉각고속로 원형로 소듐-물 반응 압력완화계통 성능 해석 연구)

  • Park, Sun Hee;Han, Ji-Woong
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.28-41
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    • 2019
  • We carried out performance analysis of Sodium-Water Reaction Pressure Relief System of Prototype Generation-IV Sodium-Cooled Fast Reactor. We analyzed transient-dynamic behavior of fluids inside the steam generator to vent into a sodium dump tank or a water dump tank when tubes in the steam generator were broken to cause a large-water-leak accident. Accordingly, we preliminarily evaluated design requirements of our system. Our results showed that sodium in the shell side of the steam generator and in Intermediate Heat Transport System was completely vented within 50 s and feed water in the tube side of the steam generator was completely vented within 2.5 s. It was analyzed that pressure of the tube side of the steam generator was higher than pressure of the shell side of the steam generator, which showed that sodium in the shell side did not flow into the tube side. Our results are expected to be used as basis information to performance analysis of Sodium-Water Reaction Pressure Relief System of Prototype Generation-IV Sodium-Cooled Fast Reactor.

Fundamental evaluation of hydrogen behavior in sodium for sodium-water reaction detection of sodium-cooled fast reactor

  • Tomohiko Yamamoto;Atsushi Kato;Masato Hayakawa;Kazuhito Shimoyama;Kuniaki Ara;Nozomu Hatakeyama;Kanau Yamauchi;Yuhei Eda;Masahiro Yui
    • Nuclear Engineering and Technology
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    • v.56 no.3
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    • pp.893-899
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    • 2024
  • In a secondary cooling system of a sodium-cooled fast reactor (SFR), rapid detection of hydrogen due to sodium-water reaction (SWR) caused by water leakage from a heat exchanger tube of a steam generator (SG) is important in terms of safety and property protection of the SFR. For hydrogen detection, the hydrogen detectors using atomic transmission phenomenon of hydrogen within Ni-membrane were used in Japanese proto-type SFR "Monju". However, during the plant operation, detection signals of water leakage were observed even in the situation without SWR concerning temperature up and down in the cooling system. For this reason, the study of a new hydrogen detector has been carried out to improve stability, accuracy and reliability. In this research, the authors focus on the difference in composition of hydrogen and the difference between the background hydrogen under normal plant operation and the one generated by SWR and theoretically estimate the hydrogen behavior in liquid sodium by using ultra-accelerated quantum chemical molecular dynamics (UA-QCMD). Based on the estimation, dissolved H or NaH, rather than molecular hydrogen (H2), is the predominant form of the background hydrogen in liquid sodium in terms of energetical stability. On the other hand, it was found that hydrogen molecules produced by the sodium-water reaction can exist stably as a form of a fine bubble concerning some confinement mechanism such as a NaH layer on their surface. At the same time, we observed experimentally that the fine H2 bubbles exist stably in the liquid sodium, longer than previously expected. This paper describes the comparison between the theoretical estimation and experimental results based on hydrogen form in sodium in the development of the new hydrogen detector in Japan.

Enhancement of the Water-resistance and Physical Properties of Sodium Alginate Film

  • Kim, Eun-Jung;Kim, Byung-Yong;Rhim, Jong-Whan
    • Food Science and Biotechnology
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    • v.14 no.1
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    • pp.108-111
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    • 2005
  • To improve water-resistance and physical properties of sodium alginate film, effects of sodium alginate and plasticizer concentrations, divalent cation types and concentrations, and immersion time of films into divalent cation solutions on sodium alginate films were evaluated, based on elongation strength (ES), elongation rate (E), water vapor permeability (WVP), and water solubility (WS). Film made from 1.5% sodium alginate solution (w/w) had low WVP and WS, which are optimal characteristics for application of film preparation. Addition of plasticizer increased E and WS. Less than 2% $CaCl_2$ addition and 15min immersion time reduced WVP, WS, and E significantly (p<0.05). Sodium alginate films treated with $CuCl_2$, and $ZnCl_2$ solutions had lower WVP and WS, whereas $MgCl_2$ had no influence on improving water resistance of films.

A Study on the Stable Operation of High Sodium Hypochlorite Generation (고농도 차아염소산나트륨 발생장치의 안정적 운영에 관한 연구)

  • Cho, Haejin;Na, Chanwook;Ko, Sungho
    • The KSFM Journal of Fluid Machinery
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    • v.20 no.2
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    • pp.69-74
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    • 2017
  • Sodium hypochlorite, used as water disinfectant, is generated by electrolysis of salt. Compared to chlorine gas disinfection, it is free from high-pressure gas regulation and does not generate toxic gas, so it is increasingly used as a safe disinfectant. Despite these advantages, the concentration of sodium hypochlorite decreases with temperature during long-term storage, and the amount of chlorate increases when a large amount is added, it has mainly been applied to small-scale waterworks. To solve this problem, high sodium hypochlorite generation was developed. In this study, the changes of concentration and chlorate of sodium hypochlorite with time has been studied. As a result of the test, it was found that the usable period of sodium hypochlorite produced at a certain temperature or less was increased from 1.5 days to 13 days. Overall, sodium hypochlorite can be applied even in large-scale waterworks, which makes operation more stable and also reduces the disinfection byproducts, thus it contributed greatly to securing water quality.

Water and Sodium Balance of Body Fluid (체액의 수분 및 나트륨 균형)

  • Kim, Ji-Hong
    • Childhood Kidney Diseases
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    • v.14 no.2
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    • pp.111-119
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    • 2010
  • The maintenance of the osmolality of body fluids within a very narrow physiologic range is possible by water balance mechanisms that control the intake and excretion of water. Main factors of this process are the thirst and antidiuretic hormon arginine vasopressin (AVP), secretion regulated by osmoreceptors in the hypothalamus. Body water is the primary determinant of the osmolality of the extracellular fluid (ECF), disorders of body water homeostasis can be divided into hypo-osmolar disorders, in which there is an excess of body water relative to body solute, and hyperosmolar disorders, in which there is a deficiency of body water relative to body solute. The sodium is the predominant cation in ECF and the volume of ECF is directly proportional to the content of sodium in the body. Disorders of sodium balance, therefore, may be viewed as disorders of ECF volume. This reviews addresses the regulatory mechanisms underlying water and sodium metabolism, the two major determinants of body fluid homeostasis for a good understanding of the pathophysiology and proper management of disorders with disruption of water and sodium balance.

Investigation on Design Requirements of Vent Lines for Sodium-Water Reaction Pressure Relief System of Prototype Generation-IV Sodium-Cooled Fast Reactor (소듐냉각고속로 원형로 소듐-물 반응 압력완화계통의 배출배관 설계요건 연구)

  • Park, Sun Hee;Han, Ji-Woong
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.388-403
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    • 2018
  • We investigated design requirements of vent lines for Sodium-Water Reaction Pressure Relief System of Prototype Generation-IV Sodium-Cooled Fast Reactor. We developed design requirements of areas of the rupture disks of the steam generator, a diameter of the gas vent line of the sodium dump tank, a diameter of the gas vent line of the water dump tank, a diameter of the water dump line of the steam generator. With the design requirements, we calculated the time to vent fluid inside the steam generator and analyzed the transient pressure behavior, also evaluated the close pressure value of the isolation valve of the water dump line. Our results are expected to be used as basis information to design Sodium-Water Reaction Pressure Relief System of Prototype Generation IV Sodium-Cooled Fast Reactor.

Evaluation of a Sodium-Water Reaction Event Caused by Steam Generator Tubes Break in the Prototype Generation IV Sodium-cooled Fast Reactor

  • Ahn, Sang June;Ha, Kwi-Seok;Chang, Won-Pyo;Kang, Seok Hun;Lee, Kwi Lim;Choi, Chi-Woong;Lee, Seung Won;Yoo, Jin;Jeong, Jae-Ho;Jeong, Taekyeong
    • Nuclear Engineering and Technology
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    • v.48 no.4
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    • pp.952-964
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    • 2016
  • The prototype generation IV sodium-cooled fast reactor (PGSFR) has been developed by the Korea Atomic Energy Research Institute. This reactor uses sodium as a reactor coolant to transfer the core heat energy to the turbine. Sodium has chemical characteristics that allow it to violently react with materials such as a water or steam. When a sodium-water reaction (SWR) occurs due to leakage or breakage of steam generator tubes, high-pressure waves and corrosive reaction products are produced, which threaten the structural integrity of the components of the intermediate heat-transfer system (IHTS) and the safety of the primary heat-transfer system (PHTS). In the PGSFR, SWR events are included in the design-basis event. This event should be analyzed from the viewpoint of the integrities of the IHTS and fuel rods. To evaluate the integrity of the IHTS based on the consequences of the SWR, the behaviors of the generated high-pressure waves are analyzed at the major positions of a failed IHTS loop using a sodium-water advanced analysis method-II code. The integrity of the fuel rods must be consistently maintained below the safety acceptance criteria to avoid the consequences of the SWR. The integrity of the PHTS is evaluated using the multidimensional analysis of reactor safety-liquid metal reactor code to model the whole plant.