• Title/Summary/Keyword: Sodium hydroxide(NaOH)

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Synthesis, Crystallization Behaviors and Conductivity of $\beta$-Alumina from Aluminum Isopropoxide and Sodium Hydroxide (Aluminum Isopropoxide와 Sodium Hydroxide로부터 $\beta$-Alumina의 합성과 결정화 과정 및 전도도)

  • 양유철;박용민;김형욱;손영국
    • Journal of the Korean Ceramic Society
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    • v.32 no.9
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    • pp.1076-1084
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    • 1995
  • A mixture of aluminum isopropoxide (Al(OC3H7i)3) solution and sodium hydroxide (NaOH) solution was hydrolyzed in the range between pH 1~14. the powder obtained from sol-gel process was calcined at several temperatures and crystallization behaviors of various samples were investigated. The hydrolyzed sols of pH 1~6 wre clear, or near clear. On the other hand, powder precipitated from sols of pH 7~14. The sample obtained from pH 3 solution crystallized via complicated route, and $\beta$-Al2O3 and $\beta$"-Al2O3 phases appeared at lower temperature than samples from other pH conditions. And the quantity of remained $\beta$"-Al2O3 phase after heat treatment at 150$0^{\circ}C$ was more than samples from other pH conditions. After sintering, ionic conductivities were 1.3$\times$10-4S.cm-1 to 0.76$\times$10-4S.cm-1.0-4S.cm-1.

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A Study on the Property and the Skin Irritability of the Reclaimed Soap (폐유을 이용한 재생비누의 특성 및 피부자극도에 대한 연구)

  • 하금;이혜자;유혜자
    • Journal of the Korean Home Economics Association
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    • v.36 no.1
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    • pp.1-11
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    • 1998
  • The purpose of this study is to find troubles in producing and using the reclaimed soaps to get the solutions of their troubles. Five kinds of reclaimed soaps were taken from religious or civic organizations and nine kinds of soaps were made by adding sodium hydroxide of different concentrations to the used vegetable oil in our laboratory. Washing efficiency, pH test, BOD, and skin irritability of the reclaimed of manufactured soaps were examined. The washing efficiency of the manufactured soaps were ±80%. The percent of free-alkali tended to increase as the amount of NaOH increased. The skinirritability was proportional to the amount of NaOH added. To make the reclaimed soap, the best percent of NaHO to used oil is 17% or 18% and this ratio(17%∼18%) should be kept. Manufactured soaps by this ratio have good apperance condition and washing efficiency. And also they have low skin irritability and free-alkali. This study has the limitations that the skin irritability test can have individual and the collected soaps couldn't represent all kinds of recaimed soap.

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Synthesis of Magnesium Hydroxide and Surface Modification by Sorbitol Surfactants (수산화마그네슘의 합성과 솔비톨계 계면활성제를 이용한 표면개질)

  • Kang, Kuk-Hyoun;Hyun, Mi-Ho;Ryu, Kun-Sung;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.92-100
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    • 2014
  • Hydrophobic magnesium hydroxide [$Mg(OH)_2$] was modified by hydrothermal method using non-ionic sorbitol surfactant with Span series. Mganesium chloride [$MgCl_2$] and sodium hydroxide [NaOH] were used for synthesis of $Mg(OH)_2$. Also non-ionic surfactant were added as a stabilizer, dispersant and surface modifier. Addition of non-ionic surfactant was favourable to obtain small sized $Mg(OH)_2$ particles with better dispersibility and hydrophobic property of $Mg(OH)_2$ particles. The obtained product were characterized by particle size analysis(PSA), scanning electron microscope(SEM), energy dispersive spectroscopy(EDS), x-ray diffraction(XRD) and fourier transform infrared spectroscopy(FT-IR). The results show that the product are prepared with this method has a well hydrophobic properties and dispersity compared with unmodified $Mg(OH)_2$ particles. The improve properties of surface modified $Mg(OH)_2$ particles were also verified by similarity synthesizing under slightly different conditions.

Prediction of compressive strength of bacteria incorporated geopolymer concrete by using ANN and MARS

  • X., John Britto;Muthuraj, M.P.
    • Structural Engineering and Mechanics
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    • v.70 no.6
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    • pp.671-681
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    • 2019
  • This paper examines the applicability of artificial neural network (ANN) and multivariate adaptive regression splines (MARS) to predict the compressive strength of bacteria incorporated geopolymer concrete (GPC). The mix is composed of new bacterial strain, manufactured sand, ground granulated blast furnace slag, silica fume, metakaolin and fly ash. The concentration of sodium hydroxide (NaOH) is maintained at 8 Molar, sodium silicate ($Na_2SiO_3$) to NaOH weight ratio is 2.33 and the alkaline liquid to binder ratio of 0.35 and ambient curing temperature ($28^{\circ}C$) is maintained for all the mixtures. In ANN, back-propagation training technique was employed for updating the weights of each layer based on the error in the network output. Levenberg-Marquardt algorithm was used for feed-forward back-propagation. MARS model was developed by establishing a relationship between a set of predictors and dependent variables. MARS is based on a divide and conquers strategy partitioning the training data sets into separate regions; each gets its own regression line. Six models based on ANN and MARS were developed to predict the compressive strength of bacteria incorporated GPC for 1, 3, 7, 28, 56 and 90 days. About 70% of the total 84 data sets obtained from experiments were used for development of the models and remaining 30% data was utilized for testing. From the study, it is observed that the predicted values from the models are found to be in good agreement with the corresponding experimental values and the developed models are robust and reliable.

Changes in CO2 Absorption Efficiency of NaOH Solution Trap with Temperature

  • Park, Se-In;Park, Hyun-Jin;Yang, Hye In;Choi, Woo-Jung
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.6
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    • pp.554-561
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    • 2017
  • Under the projected global warming, release of carbon as $CO_2$ through soil organic matter decomposition is expected to increase. Therefore, accurate measurement of $CO_2$ released from soil is crucial in understanding the soil carbon dynamics under increased temperature conditions. Sodium hydroxide (NaOH) traps are frequently used in laboratory soil incubation studies to measure soil respiration rate, but decreasing $CO_2$ gas solubility with increasing temperature may render the reliability of the method questionable. In this study, the influences of increasing temperature on the $CO_2$ capture capacity of NaOH traps were evaluated under $5{\sim}35^{\circ}C$ temperature range at $10^{\circ}C$ interval. Two closed-chamber experiments were performed where NaOH traps were used to capture $CO_2$ either released from acidified $Na_2CO_3$ solution or directly injected into the chamber. The sorption of ambient $CO_2$ within the incubators into NaOH traps was also measured. The amount $CO_2$ captured increased as temperature increased within 2 days of incubation, suggesting that increased diffusion rate of $CO_2$ at higher temperatures led to increases in $CO_2$ captured by the NaOH traps. However, after 2 days, over 95% of $CO_2$ emitted in the emission-absorption experiment was captured regardless of temperature, demonstrating high $CO_2$ absorption efficiency of the NaOH traps. Thus, we conclude that the influence of decreased $CO_2$ solubility by increased temperatures is negligible on the $CO_2$ capture capacity of NaOH traps, supporting that the use of NaOH traps in the study of temperature effect on soil respiration is a valid method.

Reaction Properties of Non-Cement Mortar Using Ground Granulated Blast Furnace Slag (고로슬래그 미분말을 사용한 무시멘트 경화체의 반응 특성)

  • Park, Sun-Gyu;Kwon, Seung-Jun;Kim, Yun-Mi;Lee, Sang-Soo
    • The Journal of the Korea Contents Association
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    • v.13 no.9
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    • pp.392-399
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    • 2013
  • The purpose of this study is to identify the manufacturing possibility of non-cement mortar using blast furnace slag and alkali accelerator. In this experimental study, the blast furnace slag which is the by-product of the steel industry substitute for cement, and the potassium hydroxide(KOH), calcium hydroxide ($Ca(OH)_2$) and sodium hydroxide(NaOH) as stimulus were added to each specimen. And the analysis on reaction property of non-cement mortar was conducted by measurement such as flexural and compressive strength, XRD, EDS and SEM. From the test results, it can be founded that $SiO_2$ and CaO included in the blast furnace slag are released and make the calcium silicate hydrate like the hydration reaction of the cement. Also, the continued study is need to reduce emission of $CO_2$ because of major content in filed of the building construction.

Alkali Gelatinization of Rice, Corn, Arrow Root and Ginger Root Starches (쌀, 옥수수, 칡 및 생강 전분의 알카리 호화)

  • Kim, Sung-Kon;Chung, Hye-Min;Cho, Man-Hee
    • Applied Biological Chemistry
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    • v.27 no.3
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    • pp.214-216
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    • 1984
  • Alkali gelatinization of rice, corn, arrow root and ginger root starches at various sodium hydroxide concentrations was investigated. Critical concentrations of alkali for starch gelatinization ranged from 2.33 to 3.17 meq NaOH per gram of starch. Ginger root starch was most resistant to alkali gelatinization and arrow root starch was least stable to alkali.

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Hydrolysis of Sarin(GB) in Aqueous NaOH Solution (가성소다 수용액에서 사린(GB)의 가수분해)

  • Lee, Yong-Han;Lee, Jong-Chol;Hong, Deasik
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.172-177
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    • 2007
  • The hydrolysis reaction of sarin(GB), one of the nerve agents was studied in aqueous sodium hydroxide(NaOH) solutions to find the experimental conditions which can convert GB into the less toxic compounds. 10 wt% of GB was added into the aqueous NaOH(2.05 eq) in a small-scale jacket-attached reactor connected to a circulator. The reaction rate constants were measured at three temperatures(50, 70 and $90^{\circ}C$) and the reaction times required to degrade the material to > 99% were calculated at different temperatures. In this study, 10 wt% of GB was degraded to 99.99% in 1.2hr at $90^{\circ}C$ by the aqueous NaOH solution. The major hydrolysate of GB was isopropyl methylphosphonate.

Hydrogen Production by the Reaction of Al and Alkaline Solution for PEMFC Application (알루미늄 알칼리용해에 의한 PEMFC용 수소 생성)

  • Sim, Woo-Jong;Na, Il-Chal;Song, Myung-Hyun;Chung, Hoi-Bum;Kim, Jeong-Ho;Kim, Tae-Hee;Park, Kwon-Pil
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.1
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    • pp.1-8
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    • 2009
  • Hydrogen production by the reaction of aluminum alloys and NaOH solution was studied for an automotive proton exchange membrane fuel cell(PEMFC) application. In our experiment conditions($30{\sim}75^{\circ}C$, NaOH $0.5{\sim}5M$), passivation of aluminum was not occurred. Higher rate of hydrogen production was observed at the reaction with Al alloys that contain impurities. With an increase in reaction temperature, hydrogen production rate by an increase in NaOH concentration increased much. When hydrogen was fed into the anode without filtering, PEMFC cell performance decreased 35% by ionic contamination such as $Na^+$ on the membrane and electrode. Thus, filtering of produced hydrogen is necessary for PEMFC operation.

Recovery of Alumina from the First Calcined Waste Pottery (1차소성 폐도자기로부터 알루미나 회수)

  • 김재용;서완주;이진수;박수길;엄명헌
    • Journal of environmental and Sanitary engineering
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    • v.15 no.1
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    • pp.62-68
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    • 2000
  • This study was investigated to the recovery of alumina from the first calcined waste pottery using alkaline sintering. This study was based on calcination result of a commercial ${\alpha}-Al2_O_3$ with NaOH powder. $NaAlO_2$ was formed by calcination of ${\alpha}-Al_2O_3$ with NaOH and conversion of $NaAlO_2$ from ${\alpha}-Al_2O_3$ was 91.4% at calcination condition ; weight ritio of $NaOH/{\alpha}-Al2_O_3$ 1.5, $800^{\circ}C$, and 90min. The first calcined waste porrery from the manufacturing Procedure of H Ltd. was grinded to 170/270mesh by a ball mill and calcined over $500^{\circ}C$ with NaOH powder. The calcined sample was dissolved in $25^{\circ}C$ water and sodiumaluminosilicate solid was formed. After filtration, the contained aluminum was leached out by dissolving sodiumaluminosilicate solid in 1N HCl. We estimated the efficiency of Al extraction from waste pottery by ICP analysis and NaOH was added to the filtrate and then aluminum compound was precipitated with $Al(OH)_3$ and recovered. The investigation was carried out with the variables ; the calcination temperature($500-900^{\circ}C$), the calcination time(30~90min), and the weight ratio of NaOH/waste pottery(0.5~1.5). The treatment efficiency of the waste pottery and the recovery of Al as 97.9%, 91.9% were obtained under the optimum conditions as followed ; the weight ratio of NaOH/waste pottery was 1.5 and the calcination conditions were $900^{\circ}C$ and 60min.

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