• Journal of Hydrogen and New Energy
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• v.15 no.1
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• pp.72-81
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• 2004

Study on the analysis of sodium spray fire using Gaussian drop size distribution, which redistributes a droplet spectrum with given mean diameter if its size classes with critical diameter(D>8mm) occur, was carried out. In this case, the oversized droplets were reduced to a stable diameter. Results calculated by the code using Gaussian drop size distribution were in better agreement with AI experimental results than those of NACOM and SPRAY code. The effect of variance on pressure in the test cell appeared greatly by introducing Gaussian function, which could represent various sodium droplet size distribution. The increase of the variance with mean droplet size resulted had an important effect upon the pressure in the test cell.

• Journal of the Korean Society of Safety
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• v.13 no.3
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• pp.32-44
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• 1998

Analysis on the study for the sodium fire mitigation was carried out using the CONTAIN-LMR code. Sodium loop building was partitioned into the many cells, in which the safety venting systems were installed for the purpose of improving the sodium fire safety and minimizing its effect on the sodium loop building. The effects of sodium fire on sodium loop building partitioned into the many cells and not partitioned were investigated. The peak pressure and temperature of each cell accompanied by sodium fire in sodium loop building partitioned were lower than those of sodium loop building not partitioned. In the case of partitioning sodium loop building, the pressures, temperatures and aerosols into cells were transferred through propagation path of CONTAIN-LMR sodium fire model simulated by this study, and the effect of sodium spray fire on sodium loop building was mitigated by partitioning building. In addition, the excessive rise of pressure into cells was prevented by installing the over-pressure exhaust valve and under-pressure exhaust valve on the flow path between cells.

• Journal of the Korean Society of Safety
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• v.11 no.2
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• pp.79-88
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• 1996

A hypothetical accident in the containment vessel of liquid metal reactor could cause a pressure, temperature rise, and a strong aerosol release. The computer codes relating to the modelization of these accident make it necessary to use various input parameter, among which is the dynamic shape factor of aerosols produced. Combustion experiments of sodium spray fire carried out in a closed vessel, which was vertical cylinder made of 1.2m in diameter and 1.8m hight with a volume of 1.7$m^3$. The results of theoretical analysis presented here was compared to data obtained from experiments. The experimental results were summarized as follows. 1) The aerodynamic diameter and geometric diameter of aerosols are decreasing with increasing of injection pressure and injection temperature of sodium 2) The dynamic shape factor of aerosol is proportional to the aerodynamic diameter for a given particle. 3) The correspondence between the aerodynamic diameter and geometric diameter can be as $D_{ae}=0.70 D_{ge}$. 4) Peak pressure rose with increase in pressure and temperature of injection sodium, being more sensitive to the injection pressure than the injection temperature.

• Proceedings of the Korean Nuclear Society Conference
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• 1999.05a
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• pp.189-189
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• 1999

• Nuclear Engineering and Technology
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• v.26 no.4
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• pp.471-483
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• 1994

A sodium fire facility with a test chamber of 1.7㎥ volume was constructed and operated to carry out experiments of sodium fires such as pool, spray, and columnar fires which might take place in sodium-related facilities. The experimental results of pool fires showed that the increase of temperature and pressure in the test chamber was much smaller than that of spray and columnar fires even though their amount of sodium injection in the chamber was much larger compared to other types of fires. And it was found in pool fires that the temperatures of sodium pool and the gas temperature in the test chamber had been maintained much longer than other types of fires, and that the chamber pressure had come to vacuum due to depletion of the oxygen for a large amount of sodium injection in the chamber. The experimental results of spray fires showed that sprayed sodium of small particles instantly reacted with oxygen, and that its reaction heat increased gas temperature and pressure of the test chamber rapidly and decreased them shortly. And the maximum gas temperature and pressure of the test chamber in spray fires ore greatly changed according to the inlet sodium temperature in the test chamber. The characteristics of the columnar fires were almost similar to those of spray fires, but the maximum temperature and pressure of the test chamber were much smaller even for a large amount of sodium injection. And it was shown in spray and columnar fires that the temperatures at each measurement position in the test chamber were quite different due to the instantaneous sodium oxidation in comparision with pool fires. Finally, the graphex powder was proved to be a very effective extinguisher against sodium pool fires.

• Korean Journal of Hazardous Materials
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• v.2 no.1
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• pp.18-26
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• 2014

We analyzed the demand of competent authorities requiring adequate technical information for initial investigation of chemical accidents. Reflecting technical reports on chemical accident response by environmental agencies in the U.S. and Canada, we presented information on environmental diffusion and toxic effects available for the first chemical accident response. Hydrogen fluoride may have the risk potential to corrode metals and cause serious burns and eye damages. In case of inhalation or intake, it could have severe health effects. The substance itself is inflammable, but once heated, it decomposes producing corrosive and toxic fume. In case of contact with water, it can produce toxic, corrosive, flammable or explosive gases and its solution, a strong acid, may react fiercely with a base. In case of hydrogen fluoride leak, the preventive measures are to decrease steam generation in exposed sites, prevent the transfer of vapor cloud and promptly respond using inflammable substances including calcium carbonate, sodium bicarbonate, ground limestone, dried soil, dry sand, vermiculite, fly ash and powder cement. The method for fire fighting is to suppress fire with manless hose stanchions or monitor nozzles by wearing the whole body protective clothing equipped with over-pressure self-contained breathing apparatus from distance. In case of transport accident accompanied with fire, evacuation distance is 1,600m radius. In cae of fire, fire suppression needs to be performed using dry chemicals, CO₂, water spray, water fog, and alcohol-resistance foam, etc. The major symptoms by exposure route are dyspnoea, bronchitis, chemical pneumonia and pulmonary edema for respiration, skin laceration, dermatitis, burn, frostbite and erythema for eyes, and nausea, diarrhea, stomachache, and tissue destruction for digestive organs. In atmosphere, its persistency is low, and its bioaccumulation in aquatic organism is also low.