• 제목/요약/키워드: Sodium Chlorite

검색결과 40건 처리시간 0.028초

중소형 선박의 $SO_X/NO_X$ 동시제거를 위한 습식세정시스템 (Simultaneous removal of $SO_X$ and $NO_X$ by wet scrubber at small and medium craft)

  • 차유정;이주열;하태영;박병현
    • 한국응용과학기술학회지
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    • 제31권1호
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    • pp.159-166
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    • 2014
  • In recent years, researchers have put a considerable effort to decrease the emission of harmful gaseous pollutants to the atmosphere. In order to remove simultaneously $SO_2$ and $NO_X$ from the flue gas of small and medium-sized ship, we designed minimal wet scrubber inside a compact multistage modular system. In this study we proceed experiment of elemental technology at each stage of the scrubber. The each stage is oxidation of NO which is the main component of $NO_X$, and removal of $SO_2$, respectively. $NaClO_2$ was used to oxidize NO gas, and NaOH was used to remove $SO_2$ gas. The maximum NO conversion efficiency and the $SO_2$ removal efficiency are both indicate 100%.

바이오에탄올 생산을 위한 폐MDF의 전처리 및 효소 당화 (Pretreatment and Enzymatic Saccharification of Wasted MDF for Bioethanol Production)

  • 강양래;황진식;배기한;조훈호;이은정;조영손;남기두
    • KSBB Journal
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    • 제30권6호
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    • pp.332-338
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    • 2015
  • The objective of this study was designed to determine the possibility of bioethanol production from wasted medium density fiberboard (wMDF). We were investigated the enzymatic saccharification characteristics using the enzyme (Cellic CTec3) after pretreatment with sodium chlorite. According to the component analysis results, the lignin contents before and after the pretreatment of wMDF (milling using sieve size of $1,000{\mu}m$) was significantly reduced from 31.13% to 4.11%. Therefore, delignification ratio of pretreated wMDF was found to be up to about 87-89% depending on the sieve size. And we were tested to compare the saccharification ratio according to the sieve size of wMDF ($1,000{\mu}m$, $200{\mu}m$), but it was no significance depending on the sieve size. When enzyme dosage was 5% based on the substrate concentration, enzymatic saccharification ratio was obtained up to 70% by maintaining at $50^{\circ}C$ for 72 hours. We could made the substrate concentration of pretreated wMDF ($1,000{\mu}m$) up to 12% and then enzymatic saccharification ratio was 76.8%, also contents of glucose and xylose were analyzed to 77,750 and 14,637 mg/L, respectively.

케나프를 이용한 수초지 제조에 관한 연구 (The Prodoction of Kenaf Hand-Made Paper)

  • 임옥;이혜자;유혜자;한영숙
    • 한국의류학회지
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    • 제31권8호
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    • pp.1286-1296
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    • 2007
  • Hanji, the korean traditional papers were mostly made from mulberry paper. But the production and demand of hanji have decreased rapidly because mulberry paper yields were insufficient and handworked hanji procedures were complicated. Recently, the researches on hanji were carried out to improve the properties of hanji. Kenaf fibers have been interested as a substitute resource of mulberry paper for hanji production. In this research, Kenai pulps were manufactured with removal methods of lignin or hemicellulose from kenaf fibers and paper mulberry pulps with traditional alkali methods. Kenaf papers, paper mulberry, and kenaf/paper mulberry mixed papers were manufactured with their pulps. The crystallinity, fiber length, color of the pulps and tensile strength, tear strength, water absorption of the papers were investigated. The results were as follow: The removal rates of lignin of chemical retted kenaf fibers with sodium chlorite reaction for 40 minutes were 70% and were higher than 40% of double retted fibers. Paper mulberry pulps has less lignin and hemicellulose than kenaf differently. The crystallinity of paper mulberry pulps were very low with 60%, but kenaf pulps were 90%. The chemical retted CR-40-1 pulps were similar with paper mulberry pulps on fiber length & fibrilation of fibers. Tensile strength of paper mulberry were higher than kenaf papers because of fibrilation of paper mulberry, but tear strength were lower. Tensile strength and tear strength were improved on kenaf/paper mulberry 30/70 mixed papers.

잣나무의 탈리그닌 정도가 습식 해섬처리 효율 및 나노종이 인장 특성에 미치는 영향 (Effect of Different Delignification Degrees of Korean White Pine Wood on Fibrillation Efficiency and Tensile Properties of Nanopaper)

  • 박찬우;이서호;한송이;김보연;장재혁;김남훈;이승환
    • Journal of the Korean Wood Science and Technology
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    • 제43권1호
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    • pp.17-24
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    • 2015
  • 본 연구에서는 잣나무 목분의 탈리그닌 정도가 습식디스크밀을 이용한 해섬처리의 효율에 미치는 영향과 얻어진 해섬물의 성질을 조사하였다. 또한, 탈리그닌 정도가 종이의 인장강도 특성에 미치는 영향도 조사하였다. 탈리그닌의 정도는 아염소산나트륨과 초산을 사용하는 Wise법의 처리횟수를 달리함으로서 조절하였다. 탈리그닌 정도가 증가함에 따라 해섬효율은 향상되었으며, 디스크밀 처리횟수가 증가함으로서 섬유직경은 감소, 여수시간은 증가하였다. 또한 종이의 인장강도 및 탄성률도 탈리그닌 정도 및 디스크밀 처리횟수가 증가할수록 증가하였다.

잔디깍기와 TIBA 처리가 잔디 인공군락의 물질생산에 미치는 영향 (Effects of Mowing and TIBA(Triiodobenzoic acid) on Dry Matter Production of Cultivated Zoysia japonica Community)

  • 진희성
    • Journal of Plant Biology
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    • 제30권2호
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    • pp.135-149
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    • 1987
  • An experiment was made in order to analyze the growth characteristics and productivity of Zoysia japonica under control, mowing and TIBA treatment conditions at the experimental farm of Kyung Hee University. The field was planned by the split plot design method and each treatment was given to two plots (40$\times$40 and 100$\times$100 mm) and was replicated three times. Each plot was 9$m^2$ for Zoysia japonica. The sampling of each plot was taken once a week after sowing. In order to know the dry matter of total standing crops, each organ of plants was kept at 9$0^{\circ}C$ and weighed. Total leaf area of a plant was measured by drawing method. The author adopted the growth analysis of English School. Holocellulose analysis by sodium chlorite method was made. The increasing rate of LAI was high in all plots between 10th and 12th week after sowing and high growth rate of assimilatory organ was observed in low density area of TIBA plot. Between 10th and 12th week after sowing all the experimental plots showed high increasing rate of standing crop and in the process of growth each density area of TIBA plot recorded high increasing rate. In all the plots F/C ratio and RGR were high when the growth rate of assimilatory organ was increasing cosiderably, and the higher the planting density was, the higher F/C ratio was recorded. In all the plots NAR recorded maximum rate before the growth period to show a high increase of RGR. In the process of the growth TIBA plot showed high icnreasing rate of NAR. CGR showed high value in high density areas of all the plots and reached its maximum in the 13th week after sowing. Compared to the other experimental areas the low planting density areas of control plot and TIBA plot showed considerable earlier lignification indicating low Holocellulose content in the growth process.

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백운모광의 품위향상에 관한 연구 (A study on the Beneficiation of Muscovite Ore)

  • 이재장;최수용
    • 산업기술연구
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    • 제9권
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    • pp.29-41
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    • 1989
  • A general study on the upgrading of mica minerals which are mainly found in pegmatite deposits was carried out for the purpose of developing a technique for recovering mica in form of comercial grade products. By the way the grade one of about 5~6% $K_2O$ still is not developed. The target of this research work is to be establish a process for the efficient concentration of muscovite, containing more than 10% $K_2O$. The tests are applied to incraese the recovery and grade of concentrates in term of variations of conditions. The test sample consists of mainly muscovite and gangue mineral such as quartz, pyrite and chlorite. Decantation and shaking table tests were ineffective to up-grade this low grade one, but flotation method gave satisfactory result. By means of grade one, but flotation method gave satisfactory result. By means of grindability tests, an optimum result could be obtained from the sample ground to -48mesh feed size. The flotation result indicates that the dodecyl ammonium chloride used as a cationic collector is effective on the negatively charged surface, while the sodium dodecyl sulfate as an anionic collector is effective on the positively charged surface. Muscovite was floated by petroleum sulfonate as well as amine type collector, it also floated by MIBC as well as pine oil frother under well condition. Fine muscovite concentrates of about 10.68% $K_2O$ was obtained with 22.4% yield, by decantation, the muscovite concentrates of 10.10% $K_2O$ was obtained with 23.54% yield, by table concentration, the muscovite concentrates of 11.51% $K_2O$ was obtained with 23.0% yield by flotation.

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폐압축보드를 이용한 바이오에탄올 생산 (Bioethanol Production by using Wasted MDF)

  • 강양래;황진식;배기한;조훈호;이은정;조영손;남기두
    • KSBB Journal
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    • 제31권1호
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    • pp.73-78
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    • 2016
  • The aim of this study attempted to verify the possibility of bioethanol production using wasted medium density fiberboard (wMDF). In order to produce bioethanol from wood cellulosic materials must be carried out the process of pretreatment, saccharification, fermentation and distillation. First, the wMDF was pretreated using sodium chlorite and pretreated wMDF was prepared to 8% slurry and then slurry was saccharified with the commercial enzyme (Cellic CTec3). The fermentable sugar and pH of saccharified substrate were about 5.5% glucose and 4.4, respectively. Herein we compared the results of ethanol yield according to the nutrients added or without addition to increase ethanol yield. Ethanol fermentation was finished in about 24 hours, but it was delayed in experimental group without nutrients. Ethanol content and fermentation ratio of the final fermented mash prepared by utilizing jar fermenter was 25.40 g/L and 86.64%, respectively. At this time, the maximum ethanol productivity was confirmed as 1.78 g/Lh (ethanol content 21.38 g/L, 12 h), and the overall ethanol productivity was 1.05 g/Lh (ethanol content 25.27 g/L, 24 h). Using fermented liquid we could produced bioethanol 95.37% by continuous distillator packed with copper element in laboratory scale. These results show that wMDF has a potential valuable for bioethanol production.

전처리 근채류의 저장과정중의 품질평가 (Changes in Quality Characteristics of Wild Root Vegetables during Storage)

  • 곽수진;박나윤;김기창;김행란;윤기선
    • 한국식품영양과학회지
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    • 제41권8호
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    • pp.1158-1167
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    • 2012
  • 현재 전처리 농산물 중 소비비율이 높은 세척 근채류(연근, 우엉, 도라지)의 침지액의 효과 및 저장온도에 따른 품질 변화를 연구하였다. 본 연구의 대상인 근채류의 품질변화는 근채류의 종류와 온도, 저장기간에 따라 pH, 색도, 경도 등의 변화에 차이를 보였으며, 특히 $24^{\circ}C$에는 전처리 근채류의 품질변화가 빨라 $10^{\circ}C$에 저장한 근채류보다 품질유지기간이 평균 3~4일 정도 단축되었다. 침지액에 따른 미생물학적 품질변화 결과를 분석해본 결과, ASC 처리에 의하여 근채류의 초기 총균수 및 대장균군수가 가장 유의적으로 감소하여 미생물 억제 효과가 뚜렷이 나타났다. 연근 도라지에 AA, CA, ASC 처리한 처리군은 초기 PPO 활성을 유의적으로 낮추는데 효과적이었지만, 우엉의 경우 ASC 처리에 의한 갈변 억제 효과가 나타나지 않았다. AA 처리한 도라지의 경우 TW 처리군에 비하여 오히려 경도가 빠르게 감소하여 품목에 따른 침지 방법에 차이를 두어야 함을 확인할 수 있었다. 따라서 세척 근채류는 품목에 따라 저장온도와 침지방법이 품질에 영향을 미치므로 적절한 저장온도 및 세척액 사용과 포장방법을 유지한다면 품질의 안전성을 확보하여 품질유지기한을 연장할 수 있을 것이라고 사료된다.

NaClO2를 이용한 NO 산화 특성 (Characteristics of NO Oxidation Using NaClO2)

  • 이기만;변영철;고동준;신동남;김경태;고경보;조무현;남궁원;목영선
    • Korean Chemical Engineering Research
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    • 제46권5호
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    • pp.988-993
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    • 2008
  • 고정층 반응기에 충진한 $NaClO_2$에 의한 NO 산화특성을 온도와 가스조건 그리고 공간속도 등을 변화시켜가며 알아보았다. $NaClO_2$와 NO의 반응은 온도에 크게 의존함을 알 수 있었다. $110^{\circ}C$까지 $NaClO_2$와 NO의 반응성은 천천히 증가하고 그 이후의 온도에서는 빠르게 증가하였으며 $170^{\circ}C$ 부근에서 가장 높은 반응성을 나타내는 것을 확인하였다. 하지만 $190^{\circ}C$ 이상의 온도에서는 $NaClO_2$가 NaCl, $NaClO_3$, 상전이하여 NO와의 반응성이 나타나지 않았다. $NaClO_2$와 NO 반응의 주 생성물은 $NO_2$였으며 가스상 형태의 ClNO, $ClNO_2$ 등이 부산물로 나타났다. 이는 $NaClO_2$에 의한 NO의 산화물인 $NO_2$$NaClO_2$가 반응하여 가스상 부산물인 OClO를 생성하고, 생성된 OClO가 잔류하는 NO를 $NO_2$로 산화시키며 발생되는 Cl에 의한 것임을 확인하였다. 이와 함께 수분 및 산소의 변화는 NO 산화에 주는 영향이 미미하다는 것을 알 수 있었다.

폐지를 이용한 생분해성 고분자의 제조(I) - 폐지의 화학적 조성 분석 및 전처리 - (Manufacture of Biodegradable Polymer with Wastepaper(I) - Pretreatment and Analysis of Chemical Components On Wastepaper -)

  • 권기훈;임부국;양재경;장준복;이종윤
    • Journal of the Korean Wood Science and Technology
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    • 제28권3호
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    • pp.34-41
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    • 2000
  • 최근 들어 범용 플라스틱계 고분자의 환경오염이 심각한 사회적 문제를 유발함에 따라 많은 연구자들이 생분해성 고분자 소재 개발에 관한 연구를 시행하고 있으며, 본 연구에서는 폐지를 이용한 생분해성 고분자물질의 제조를 위하여 폐지의 화학적 성상 및 최적 전처리조건을 검토하기 위해 시행하였고, 그 결과는 다음과 같다. 각 공시재료별 화학적 조성분 분석 결과 신문폐지와 골판폐지의 리그닌 함량이 사무실 폐지에 비해 높게 나타났다. 또한 건식해리 펄프에 비해 습식해리 펄프의 회분 함량이 낮게 나타났다. 생분해성 고분자의 제조를 위해서는 반드시 폐지의 화학적 전처리가 요구되며, 습식해리 시료가 건식해리 시료에 비해 전처리 효과가 우수하였다. 본 연구에서 행해진 화학적 전처리 중 아염소산나트륨으로 가온($70^{\circ}C$)처리한 전처리방법이 가장 우수한 것으로 판명되었다. 한편 산소-알카리 전처리는 탈리그닌처리 효과는 우수하였지만, 수율이 과도하게 저하되고, 탄수화물의 붕괴에 따른 셀룰로오스의 중합도 저하로 인해 전처리 공정으로서 부적합하다고 판단되었다.

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