• 대한환경공학회지
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• 제27권1호
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• pp.75-84
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• 2005

본 연구는 해양구조물로 재활용되는 제강 슬래그의 납, 구리, 카드뮴과 수은의 용출특성을 평가하는데 있다. 이를 위하여 고형폐기물의 용출규제 시험, 액고비 변화시험, pH 고정시험과 같은 다양한 용출시험을 하였다. 용출용매로 증류수를 이용한 경우와 해수를 이용한 경우의 pH 고정시험 결과, 제강슬래그에서 용출된 납, 구리, 카드뮴은 뚜렷한 차이를 확인할 수 있었다. 용출용매로 증류수 사용시, pH 7-8 구간과 pH 11-12 구간에서 낮은 용출을 보였지만, 해수를 용출용매로 사용한 경우는, 증류수를 용매로 사용한 것 보다 높게 용출되었다. 수은 용출의 경우는 증류수를 용출용매로 이용한 것보다 해수를 이용한 경우에서 더 낮게 용출되었다. 한편, 제강 슬래그에서 용출되는 납, 구리, 카드뮴의 용존 및 침전 상태의 파악과 중금속 화합물들의 파악을 위하여 지화학 평형 프로그램인 Visual minteq를 사용하였다. 해수와 반응한 제강 슬래그에서 용출된 납, 구리는 pH 11-12 구간에서 대부분 용존되지만 pH가 감소되는 pH 7-10에서는 90% 이상만이 침전하였고, 카드뮴의 경우는 100% 용존상태로 존재하였다. 증류수와 반응한 제강 슬래그에서 용출된 납은 해수의 경우도 유사하였고, 구리와 카드뮴은 100% 용존상태로 존재하였다. 해수 내의 $Cl^-,\;CO_3^{-2},\;SO_4^{-2}$와 결합한 납화합물은 $PbCl^+,\;PbSO_4$로 이루어졌으며, 구리화합물은 $CuSO_4,\;CuCO_3$, 카드뮴화합물은 $CdCl^+,\;CdSO_4$ 등이 형성되었다. 수은의 경우는 해수 및 증류수를 용출용매로 이용한 모든 경우에서 납, 구리, 카드뮴과는 달리 대부분 침전하였다. 더욱이 해수에 존재하는 고농도 염소($Cl^-$)와의 수착으로 인해 finite solid인 calomel($Hg_2Cl_2$)이 형성되어 대부분 침전(SI=0)되기 때문에 납, 구리, 카드뮴 보다 더 낮은 환경이동성을 갖을 것으로 사료된다. 상기 실험결과 용출용매로 증류수와 해수를 이용했을 때, 제강 슬래그에서 용출되는 납, 구리, 카드뮴, 수은의 용출 경향의 차이를 확인할 수 있었고 이에 따라서, 납, 구리, 카드뮴의 용출 유해성은 낮기 때문에 해양구조물로의 제강슬래그 유효이용은 적합할 것으로 판단되었다.

• 한국환경과학회지
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• 제5권5호
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• pp.611-617
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• 1996

유일한 탄소원으로서 Biphenyl을 포함하고 있는 액체배지에서 Pseudomonas sp. P2의 생육에 미치는 영양원의 효과에 관해 연구하였다. Pseudomonas sp. P2의 특성을 조사하기 위한, 배양시간은 균의 생육 유선에서 대수성장기 말인 100시간으로 하였다. PCBs를 분해하는 Pseudomonas sp. P2의 생육을 위한 최적 조성은 1000 mg/L $NH_4NO_3$, 1000 mg/L KH_2PO_4$, 100 mg/L MgSO_4$.$7H_2O$, 30 mg/L $CaCl_2$.$2H_2O$, 200 mg/L NaCl, 10mg/L $FeSO_4$.$7H_2O$였다. Pseudomonas sp. P2에 의한 100시간 배양후 절연유 내에 있는 PCBs의 분해률은 500mg/L에서 59.3%, 1000mg/L에서 57.6%, 1500mg/L에서 51.4%, 2000mg/L에서는 48.775 였다.

• 재활간호학회지
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• 제3권2호
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• pp.141-153
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• 2000

The several Chinese herbs such as Soon-Ki-Hwal-Hyul-Tang, Bo-Yang-Hwan-O-Tang, Seong-Hyang-Jeong-Ki-San, So-Hap-Hyang-Won and O-Yak-Soon-Ki-San were extracted with water and then lyophilized. For identification of the effect of extracted herbs, they were medicated to 103 patients of cerebrovascular accident for 4 week. They were hospitalized in D-Oriental Medical Hospital from April to August in 1999. The herbs were extracted with water and lyophilized and then, used as samples. The medical history of each patient was detected and analyzed from their medical records. The results were as follows; 1) Each sample (Soon-Ki-Hwal-Hyul-Tang, Bo-Yang-Hwan-O-Tang, Seong-Hyang-Jeong-Ki-San, and O-Yak-Soon-Ki-San) was statistically significant differences of systolic blood pressure(t=4.22, P=0.0004; t=3.44, P=0.0028; t=2.11, P=0.0463; t=3.23, P=0.0052). The statistically significant difference of diastolic blood pressure showed by medicated with Soon-Ki-Hwal-Hyal-Tang, Seong-Hyang-Jeong-Ki-San, and O-Yak-Soon-ki-San (t=2.13, P=0.0459; t=2.68, P=0.0136; t=3.12, P=0.0066). 2) The statistically significant difference of the arm/leg-ROM showed by medicated with Soon-Ki-Hwal-Hyul-Tang, Bo-Yang-Hwan-O Tang, So-Hap-Hyang-Won(t=4.74/4.95, P=0.0002/0.0001; t=2.25/2.44, P=0.0368/0.0248; t=5.85/6.76, P=0.0001/0.0001). 3) In the verbal disorder, Soon-Ki-Hwal-Hyul-Tang, Bo-Yang-Hwan-O-Tang had statistically significant differences(t=4.50, P=0.0002; t=3.32, P=0.0036). 4) In the conscious disorder, Soon-Ki-Hwal-Hyul-Tang, Bo-Yang-Hwan-O-Tang, Seong-Hyang-Jeong-Ki-San, and So-Hap-Hyang-Won had statistically significant differences(t=6.32, P =0.0001; t=8.32, P=0.0001; t=3.74, P=0.0012; t=5.14, P=0.0001). 5) Bovine aortic endothelial cell (BAEC) were cultured in DMEM treating 0.01mg/ml, and 0.1mg/ml of each lyophilized samples for 24 hours. In BAECs were treated by 5 kinds of samples, the effect of So-Hyap-Hyang-Won induced syncytium of adjacent endothelial cells. It may induce the recovering of the damaged blood vessels in cerebrovascular accidental patient by angiogensis of endothelial cells. Therefore, it suggests that the medication of So-Hap-Hyang-Won will help to nursing care for cerebrovascular accidental patients.

• 한국산림과학회지
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• 제78권2호
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• pp.209-217
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• 1989

$SO_2$에 대한 내성수종(耐性樹種)을 선발(選拔)하기 위하여, 6수종(樹種)에 대하여 인공산성우(人工酸性雨)를 처리(處理)하면서 엽피해율(葉被害率), 엽록소함량(葉綠素含量) 및 생장(生長)을 조사(調査)하고, 산성연무(酸性煙霧)를 처리(處理)하면서 엽피해율(葉被害率)을 조사(調査) 비교(比較)하였다. 찔레는 처리산성우(處理酸性雨)의 pH값이 작아질수록 묘고생장(苗高生長)이 나빠졌으며 대조구에서 가장 좋게 나타났으나 가중나무는 pH 5.0 처리구(處理區)에서 묘고생장(苗高生長)이 가장 좋게 나타났다. 아까시나무, 일본목련 및 등나무는 pH 5.0 처리구(處理區)에서 지상부(地上部)와 지하부(地下部)의 생장(生長)이 모두 대조구(對照區)보다 좋게 나타나 상대적(相對的)으로 타수종(他樹種)에 비(比)해 산성우(酸性雨)에 대한 내성(耐性)이 강(强)할 것으로 기대(期待)된다. 처리산성우(處理酸性雨) 및 산성연무(酸性煙霧)의 pH 값이 작아질수록 모든 수종(樹種)에서 엽피해율(葉被害率)(피해엽면적(被害葉面積)과 피해엽율(被害葉率))이 증가(增加)하였다. 수종별(樹種別)로 처리간(處理間) 엽록소함량(葉綠素含量)의 변화(變化)는 조금씩 차이(差異)가 있으나, 찔레의 경우(境遇)는 측정시기(測定時期)에 관계(關係)없이 처리산성우(處理酸性雨)의 pH값이 작아질수록 총엽록소함량(總葉綠素含量)이 낮아지는 경향(傾向)이 있으며 일본목련의 경우(境遇)는 7월 측정(測定)에서는 처리산성우(處理酸性雨)의 pH 값이 작아질수록 총엽록소함량(總葉綠素含量)이 월등(越等)히 높았다가 산성우처리(酸性雨處理)가 계속(繼續)됨에 따라 감소(減少)하여 9월 측정(測定)에서는 처리산성우(處理酸性雨)의 pH 값이 작아질수록 총엽록소함량(總葉綠素含量)이 현저(顯著)히 낮아졌다.

• 환경위생공학
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• 제15권1호
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• pp.102-108
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• 2000

Seasonal variation of $NO_2$ and $SO_2$ concentration was investigated at the underground shopping center in Chonan from October 1997 to August 1998. $NO_2$ and $SO_2$ was collected by personal air sampler at $0.4{\ell}/min$ and $0.5{\ell}/min$ respectively and analyzed using UV spectrophotometer at 550nm and 548nm individually. The results were as follows. 1. The concentration of $NO_2$ was 0.070 ppm in spring, 0.068 ppm in summer, 0.074 ppm in autumn and 0.085 ppm in winter. There was no significant difference. 2. The concentration of $SO_2$ was 0.0233 ppm in spring, 0.0216 ppm in summer, 0.0188 ppm in autumn and 0.0621 ppm in winter. There was significant difference (p<0.01). 3. The higher concentration of $NO_2$ and $SO_2$ gases were shown near the cafeteria (p<0.001, p<0.05). 4. The higher concentration of $NO_2$ was observed at indoor than the underground passage. There was significant difference between two values (p<0.01).

• The Korean Journal of Ecology
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• 제21권5_1호
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• pp.449-456
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• 1998

This study was carried out to investigate the characteristics of acid deposition by stemflow, throughfall, rainfall and $SO_{2}$ in the industrial, urban and rural areas where were affected by the acid rain areas air pollution in Pinus thunbergii than Quercus spp. forest. As the stemflow pH in industrial and urban area were lowed that of rural area, the result industrial and urban, and correlation of negative ($r=-0.9415^{**}$) between pH and EC. The concentration of acid ion by stemflow, throughfall, rainfall were high $SO_{4}^{2-}$ ion at industrial areas, especially of $NO_{3}^{-}$ ion at urban areas. The concentration of basic ion all rain fall were high $Ca^{2+},\;Na^{+}$ ion at industrial areas, but there were high $Ca^{2+}$, $Na^{+}$ ion at urban areas. The concentration of $SO_{2}$ at survey areas were high $SO_{2}$ concentration at industrial and urban areas, but there was low at rural areas. There was correlation of negative ($r=-0.8007^{**}$ between pH and $SO_{2}$ concentration at survey areas. Soil acidity was also affected by stemflow and showed sigificantly low pH in industerial and urban areas.

• 한국환경보건학회지
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• 제19권3호
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• pp.29-35
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• 1993

This study was performed to obtain optimal conditions for reduction of color in dye wastewaters using coagulation-sedimentation processes with redox reactions. The reduction of color as well as organic matters variation was observed after coagulation-sedimentation processes using FeSO$_4$ $\cdot$ 7H$_2$O and NaOCl. Coagulation-redox reaction was done with the dose of Coagulant and oxidant at various pH values. Redox reaction was done through jar-mixing and aeration. The results of study were as follows: 1. In the coagulation-sedimentation processes using FeSO$_4$ $\cdot$ 7H$_2$O, color reduction was heigher at pH 3. With variance of dosage of FeSO$_4$ $\cdot$ 7H$_2$O, color reduction was higher at 250 mg/l. When coagulation-sedimentation using FeSO$_4$ $\cdot$ 7H$_2$O 250 mg/l was added at pH 3, the reduction of color, COD$_{Mn}$, and COD$_{Cr}$ showed 47.6%, 21.3% and 22.1%, respectively. 2. When NaOCI was added at level of 100 ppm in raw wastewater at pH 3, the reduction of color, COD$_{Mn}$, and COD$_{Cr}$ showed 30.2%, 5.5% and 6.2%, respectively. 3. After coagulation-sedimentation processes by addition of FeSO$_4$ $\cdot$ 7H$_2$O, when NaOCl was added at level of 250 mg/l in supernant, color reduction was 47.8% in aeration and 37.5% in jar-mixing. 4. Color reduction by aeration was higher than that by jar-mixing.

• 한국환경보건학회지
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• 제19권1호
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• pp.37-43
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• 1993

The airborne concentrations of Sulfur Dioxide and Total Suspended Particulates were investigated in 4 subway lines in Seoul at early summer, 1990 and early summer, 1991. The results of the study were as follows: 1. The airborne concentrations of SO$_2$ and TSP were 0.022 ppm, 445.7 $\mu$g/m$^3$ respectively. And percents of over annual air quality standard of WHO was that SO$_2$ and TSP were 41.7%, 100% respectively. 2. Airborne SO$_2$ concentrations by subway lines were that line 1 was 0.025 ppm, line 2 was 0.023 ppm, line 3 was 0.020 ppm, and line 4 was 0.017 ppm. And TSP concentrations by subway lines were that line 2 was 533.8 $\mu$g/m$^3$, line 1 was 516.5 $\mu$g/m$^3$, line 4 was 371.6 $\mu$g/m$^3$, and line 3 was 369.3 $\mu$g/m$^3$ 3. Annual variation of concentration of TSP was not significant statistically (t=0.327), and that of SO$_2$, in 1990 was slightly higher than that in 1991 (t=1.433, p<0.1). 4. Coefficients of correlation between TSP and SO$_2$ by years were that early summer, 1990 was r=0.277 (p>0.1), and early summer, 1991 was r=0.32 (p>0.1).

• 한국산림과학회지
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• 제98권6호
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• pp.712-718
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• 2009

본 연구에서는 비교적 청정지역인 홍천 계방산지역내의 장거리이동에 따른 대기오염물질의 유입정도를 알아보고자 이 지역 내의 강수를 채취하여 산도(pH) 및 이온분석을 실시하였다. 분석 자료에 대한 이온수지와 전기전도도(EC) 검토에서 신뢰성이 확인되었고 홍천 계방산지역 내 강수산도(pH)는 산성우의 기준이 되는 pH5.6 이하의 범위인 pH5.0~5.5 범위에 집중적으로 나타났다. 대체적으로 강수량이 많을수록 이온농도가 감소하는 경향을 나타내었고 산성원인물질의 증감과 중화물질에 따라 강수산도(pH)의 증감에 영향을 미치는 것을 알 수 있었다. 한편, 강수중 이온성분의 조성비율을 살펴보면 음이온은 $SO_4^{2-}$와 $nss-SO_4^{2-}$, 양이온은 $NH_4^+$와 $nss-Ca^{2+}$가 많은 비율을 차지하였다. 특히 대기오염물질 배출원이 거의 없는 홍천 계방산지역에서 인위적 오염물질인 $SO_4^{2-}$와 토양의 유입원인물질인 $Ca^{2+}$의 농도가 높았던 결과를 통해 이곳의 강수 화학성이 장거리 이동성 물질에 의해 영향을 받고 있음을 추정할 수 있다.

• Asian-Australasian Journal of Animal Sciences
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• 제17권12호
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• pp.1717-1724
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• 2004

The study was conducted to determine the effect of Salmonella typhymurium lipopolysaccharide (LPS) challenge on egg-laying performance, inflammatory response, zinc metabolism in layer fed diets supplemented with organic or inorganic zinc since 3-wk-old. The three dietary treatments were corn-soybean meal basal diet without supplemental zinc or with supplemental zinc at 60 mg/kg zinc from $ZnSO_4$ or zinc amino acid complex (ZnAA). At the age of 58 wk-old, twelve hens from each dietary treatment were allotted into two sub-groups. On day 1, 3, 5, 7 of the $58^{th}$ week of age, six birds of one sub-group were injected intraperitoneally (i.p.) with 2 ml LPS (1.0 $\ell$/ml) or sterile saline. Neither zinc source ${\times}$ immune challenge interaction nor zinc source effect on egg production performance was observed (p>0.05), LPS-challenge decreased egg production (p<0.04) and increased percentage of cracked eggs (p <0.01). With LPS challenged, the fever response of hens fed ZnAA peaked and subsided earlier than in hens fed $ZnSO_4$ or basal diet. Serum IL-1$\beta$ at 3 h was higher (p<0.01), but lower (p<0.001) at 12 h post-challenge with LPS in hens fed ZnAA than $ZnSO_4$. In salinetreated groups, serum IL 1$\beta$ was higher in hens fed ZnAA than the basal diet at 3 h post-injection (p<0.01). LPS-challenged birds had lower serum zinc and higher zinc sequestered in liver and spleen (p<0.001). In saline-treated birds, there was no difference in zinc concentration of serum, liver and spleen among different dietary treatments (p>0.05). Supplementation of 60 mg/kg zinc from either ZnAA or $ZnSO_4$ significantly (p<0.05) elevated metallothionein (MT) concentration in liver and spleen. MT concentration in liver of birds fed ZnAA diet was higher than in those fed $ZnSO_4$ diet (p<0.05). The magnitude of increase of hepatic and splenic MT due to LPS challenge was higher by supplementation of ZnAA than $ZnSO_4$. The results suggest that zinc amino acid complex enhanceed MT synthesis and zinc sequestered in liver and spleen and increased the sensitivity to immune response due to LPS challenge.