• 제목/요약/키워드: SnPt

검색결과 156건 처리시간 0.028초

산화제 생성율이 높은 촉매성 산화물 전극(DSA)의 개발에 관한 연구(II) (A Study on the Preparation of the Dimensionally Stable Anode(DSA) with High Generation Rate of Oxidants(II))

  • 박영식;김동석
    • 한국환경과학회지
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    • 제18권1호
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    • pp.61-72
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    • 2009
  • Fabrication and oxidants production of 3 or 4 components metal oxide electrode, which is known to be so effective to destruct non-biodegradable organics in wastewater, were studied. Five electrode materials (Ru as main component and Pt, Sn, Sb and Gd as minor components) were used for the 3 or 4 components electrode. The metal oxide electrode was prepared by coating the electrode material on the surface of the titanium mesh and then thermal oxidation at $500^{\circ}C$ for 1h. The removed RhB per 2 min and unit W of 3 components electrode was in the order: Ru:Sn:Sb=9:1:1 > Ru:Pt:Gd=5:5:1 > Ru:Sn=9:1 > Ru:Sn:Gd=9:1:1 > Ru:Sb:Gd=9:1:1. Although RhB decolorization of Ru:Sn:Sb:Gd electrode was the highest among the 4 components electrode, the RhB decolorization and oxidants formation of the Ru:Sn:Sb=9:1:1 electrode was higher than that of the 3 and 4 components electrode. Electrogenerated oxidants (free Cl and $ClO_2$) of chlorine type in 3 and 4 components electrode were higher than other oxidants such as $H_2O_2\;and\;O_3$. It was assumed that electrode with high RhB decolorization showed high oxidant generation and COD removal efficiency. OH radical which is electrogenerated by the direct electrolysis was not generated the entire 3 and 4 components electrode, therefore main mechanism of RhB degradation by metal oxide electrode based Ru was considered indirect electrolysis using electrogenerated oxidants.

MnO$_2$가 첨가된 Pb(Sn$_{1}$2/Nb$_{1}$2/)O$_3$-PbTiO$_3$-PbZrO$_3$ 세라믹의 유전 및 초전특성에 관한 연구 (A Study on the Dielectric and Pyroelectric Properties of the Pb(Sn$_{1}$2/Nb$_{1}$2/)O$_3$-PbTiO$_3$-PbZrO$_3$ Ceramics doped with MnO$_2$)

  • 함영욱;이능헌;이덕출
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1993년도 추계학술대회 논문집
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    • pp.10-13
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    • 1993
  • ln this study, x PSN - y PT - z PZ ceramics doped with w MnO$_2$were fabricated by the mixed oxide method at 1250[$^{\circ}C$] for 2[hr] and then the dielectric and pyroelectric properties were investigated. In the 0.05 PSN - 0.4 PT - 0.55 PZ specimen with 0.5[wt.%] MnO$_2$, the pyroelectric coefficient was 6.6${\times}$10$\^$-8/[C/cm$^2$$.$$^{\circ}C$], respectibly.

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One-pot 공정으로 합성된 귀금속 나노입자에 의한 SnO2 나노섬유 가스센서의 감응 특성 향상

  • 변준혁;최선우;선건주;;김상섭
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.371.2-371.2
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    • 2014
  • 가스 센서분야에서 특정 가스종에 대한 선택성과 감응도 향상을 위해 금속 촉매 등을 센서 물질 표면이나 내부 등에 형성시키는 방안이 많이 연구되고 있다. 1차원 구조 반도성 물질인 나노섬유 내에 금속 촉매를 형성시켜 특정 가스에 대한 선택성과 감응도를 향상시키는 연구가 보고된 바 있다. 선행연구에 의하면 Au와 Pt입자가 형성된 나노섬유의 경우, 각각 CO와 toluene가스에 대하여 선택적인 감응을 나타내는 것으로 확인되었다. 본 연구에서는 전기방사법과 광환원법을 동시에 이용하여 Au와 Pt 입자가 포함된 $SnO_2$ 나노섬유를 합성하고, 이들 나노섬유의 가스감응 특성을 연구하였다.

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광패키징용 마이크로 솔더범프의 형성과 Contact Pad용 UBM간의 계면 반응 특성에 관한 연구 (A Study on Bumping of Micoro-Solder for Optical Packaging and Reaction at Solder/UBM interface)

  • 박종환;이종현;김용석
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.332-336
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    • 2001
  • In this study, the reaction at UBM(Under Bump Metallurgy) and solder interface was investigated. The UBM employed in conventional optical packages, Au/Pt/Ti layer, were found to dissolve into molten Au-Sn eutectic solder during reflow soldering. Therefore, the reaction with different diffusion barrier layer such as Fe, Co, Ni were investigated to replace the conventional Pt layer. The reaction behavior was investigated by reflowing the solder on the pad of the metals defined by Cr layer for 1, 2, 3, 4, and 5 minutes at $330^{\circ}C$. Among the metals, Co was found to be most suitable for the diffusion barrier layer as the wettability with the solder was reasonable and the reaction rate of intermetallic formation at the interface is relatively slow.

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$Pb(Sn_{1/2}Nb_{1/2})O_3-PbTiO_3-PbZrO_3$계 세라믹스의 유전 및 초전특성에 관한 연구 (A Study on Dielectric and Pyroelectric Properties of $Pb(Sn_{1/2}Nb_{1/2})O_3-PbTiO_3-PbZrO_3$ Ceramics)

  • 명재욱;이능헌;김용혁;이덕춘
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1496-1498
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    • 1994
  • In this study, x PSN - y PT - z PZ ceramics doped with w $MnO_2$ were fabricated by the mixed oxide method at 1250 [$^{\circ}C$] for 2[hr] and then the dielectric and pyroelectric properties were investigated. In the 0.05 PSN - 0.4 PT - 0.55 PZ specimen with 0.5[wt%] $MnO_2$ the Pyroelectrics coefficient was $6.6{\times}10^{-8}[C/cm^2.^{\circ}C]$, respectibly.

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$Pb({Sn}_{1/2}Nb_{1/2})O_3-PbTiO_3-PhZrO_3$ 세라믹의 유전 및 초전특성에 관한 연구 (A Study on the Dielectric and Pyroelectric Properties of the $Pb({Sn}_{1/2}Nb_{1/2})O_3-PbTiO_3-PhZrO_3$ Ceramics)

  • 함영욱;이능헌;김용혁;김진수;김영일
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1993년도 하계학술대회 논문집 B
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    • pp.1119-1121
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    • 1993
  • The PSN-PT-PZ ceramics doped with the Mn-oxide(0.5wt%) were fabricated by the mixed oxide method at 1250($^{\circ}C$) for 2(hr) and then the dielectric and pyroelectric properties were investigated with the compositions. In the 0.05PSN-0.4PT-0.55PZ specimen with 0.5(wt%) $MnO_2$, the pyroelectric coefficient was $6.6{\times}10^{-8}(C/Cm^2^{\circ}C)$, and the figure of merits for pyroelectric current and voltage were $27{\times}10^{-9},\;45{\times}10^{-12}$(C.Cm/J), respectibly.

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Some Features of Dye-sensitized Solar Cell Combining with Single-walled Carbon Nanotubes

  • Lee, Sanghun;Park, Hyunjune;Park, Taehee;Lee, Jongtaek;Yi, Whikun
    • Bulletin of the Korean Chemical Society
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    • 제35권3호
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    • pp.925-928
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    • 2014
  • A dye-sensitized solar cell (DSSC) was fabricated with a nanocrystalline $TiO_2$ film electrode on FTO glass, N719 dye, electrolytes (or $CsSnI_3$), and counter Pt electrode by incorporating it with single-walled carbon nanotubes (SWNTs). SWNTs were combined with $TiO_2$ film, $CsSnI_3$, Pt electrode, separately, and the SWNT-containing cell was compared with a pristine cell in cell performance. We also examined the performance change by pressing $TiO_2$ film, during cell fabrication, inside a high pressure chamber. Mostly, the change of conversion efficiency was compared for each cell, and an atomic force microscopy data were suggested to explain our results.

$Pb(Sb_{1/2}Sn_{1/2})O_3-PbTiO_3-PbZrO_3$ 세라믹의 유전 및 초전 특성에 관한 연구 (A Study on the Dielectric and Pyroelectric Properties of the $Pb(Sb_{1/2}Sn_{1/2})O_3-PbTiO_3-PbZrO_3$ Ceramics)

  • 윤종원;이성갑;배선기;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1989년도 추계학술대회 논문집 학회본부
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    • pp.91-93
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    • 1989
  • x $Pb(Sb_{1/2}Sn_{1/2})O_3-PbTiO_3-PbZrO_3$, (0.05$\leq$x$\leq$0.30) ternary compound ceramics were fabricated by the mixed oxide method. The sintering temperature and time were $1200{\sim}1300[^{\circ}C]$, 2 hour, respectively. Increasing the PSS contents, the transition temperatures were decreased. The relative dielectric constant and Curie temperature of the 0.30PSS-0.20PT-0.50PZ specimens were 372, 190[$^{\circ}C$]. The pyroelectric coefficient, figure of merits for pyroelectric current and detectivity of the 0.25PSS-0.25PT-0.50PZ specimens had the good values, $5.41{\times}10^{-8}[C/cm^{2}K]$, $27.72{\times}10^{-12}[Ccm/J]$, $7.65{\times}10^{-10}{Ccm/J]$, respectively.

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산화제 생성율이 높은 촉매성 산화물 전극(DSA)의 개발에 관한 연구(I) (A Study on the Preparation of the Dimensionally Stable Anode(DSA) with High Generation Rate of Oxidants(I))

  • 김동석;박영식
    • 한국환경과학회지
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    • 제18권1호
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    • pp.49-60
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    • 2009
  • Fabrication and oxidants formation of 1 and 2 component metal oxide electrode, which is known to be so effective to destruct non-biodegradable organics in wastewater, were studied. Five electrode materials (Ru, Pt, Sn, Sb and Gd) were used for the 1 and 2 component electrode. The metal oxide electrode was prepared by coating the electrode material on the surface of the titanium mesh and then thermal oxidation at $500^{\circ}C$ for 1 h. The removed RhB per 2 min and unit W for one component electrode decreased in the following sequences: Ru/Ti>Sb/Ti>Pt/Ti>Gd/Ti>Sn/Ti. The concentration of oxidants generated in 1 and 2 component electrodes was in the order of: $ClO_2$> free Cl>$H_2O_2>O_3$. OH radical was not generated from in entire one and two component electrodes. RhB degradation rate and generated oxidants of the Ru-Sn=9:1 electrode was higher than that of the two component electrode. The exact relationship between the removal of RhB and the generated oxidants concentration was not obvious. However, it was assumed that electrode with high RhB decolorization had high oxidant concentration.

$MnO_2$가 첨가될 PSS-PT-PZ 세라믹의 유전 및 초전특성에 관한 연구 (A Study on the Dielectric and Pyroelectric Properties of the PSS-PT-PZ Ceramics Added $MnO_2$)

  • 이성갑;류기원;이영희;배선기;박창엽
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1991년도 하계학술대회 논문집
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    • pp.194-197
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    • 1991
  • In this study, $(Pb_{0.99}La_{0.01})[(Sb_{1/2}Sn_{1/2})_{0.10}Ti_{0.25}Zr_{0.65}]O_3$, added $MnO_2$ (0-0.30[mol%]) ceramics were fabricated by the mixed oxide method. The sintering temperature and time were $1250[^{\circ}C]$, 2[hr], respectively. In the $(Pb_{0.99}La_{0.01})[(Sb_{1/2}Sn_{1/2})_{0.10}Ti_{0.25}Zr_{0.65}]O_3$ added $MnO_2$ (0.24[mol%]) specimens, relative dielectric constant and dielectric loss were minimum values 3.52, 0.003, respectively, and Curie temperature were highest values $256[^{\circ}C]$. Pyroelectric coefficient and voltage responsivity of the $(Pb_{0.99}La_{0.01})[(Sb_{1/2}Sn_{1/2})_{0.10}Ti_{0.25}Zr_{0.65}]O_3$, and added $MnO_2$ (0.24[mol%]) specimen were good values, $6.73{\times}10^{-8}[C/cm^2K],\;125[v/W]$, respectively. Figure of merit of pyroelectric current, voltage and detectivity of the specimen, $(Pb_{0.99}La_{0.01})[(Sb_{1/2}Sn_{1/2})_{0.10}Ti_{0.25}Zr_{0.65}]O_3$ added $MnO_2$ (0.24[mol%]) were good values $2.714{\times}10^{-8}[Ccm/J],\;7.706{\times}10^{-11}[Ccm/J],\;2.640{\times}10^{-8}[Ccm/J]$, respectively. Voltage responsivity of the $(Pb_{0.99}La_{0.01})[(Sb_{1/2}Sn_{1/2})_{0.10}Ti_{0.25}Zr_{0.65}]O_3$ added $MnO_2$ (0.24[mol%]) specimens were decreased with increasing the chopper frequency.

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