• Title/Summary/Keyword: Sn-addition

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Properties of Sintered Body of the $Ba(Ti_{1-x}Sn_x)_4O_9$ Ceramics Synthesized by Oxalate Method (II) (수산염법으로 합성한 $Ba(Ti_{1-x}Sn_x)_4O_9$ 분말의 소결체 특성(II))

  • 허혜경;지미정;안주삼;최병현
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.895-900
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    • 1996
  • Ba(Ti1-xSnx)4O9 powder was synthesized by oxalate method. With the substitution of Sn into Ti site the sintered BaTiO4 crystal phase was stabilized due to the formation of solid solution. The optimal amounts of Sn solutbility for formation of BaTi4O9 crystalline phase was 0.16mole and of Sn was substituted and sintering was done at 135$0^{\circ}C$ for 30 minutes long rod type crystal was well developed and the highest Q value was obtained. But dielectric constant wasnearly constant without regarding to the Sn addition and the sintering time.

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Sn02 Two-dimensional Nanostructures Prepared by Solution Reduction Method and Their Gas Sensing Characteristics (용액환원법에 의한 Sn02 2차원 나노구조의 합성과 가스 감응 특성)

  • Park, Hong-Chul;Kim, Hae-Ryong;Lee, Jong-Heun
    • Korean Journal of Materials Research
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    • v.18 no.8
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    • pp.438-443
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    • 2008
  • SnO nanosheets were prepared at room temperature through a reaction between an aqueous solution of $SnCl_2$, $N_2F_4$, and NaOH and were converted into $SnO_2$ nanosheets without a morphological change. The SnO nanosheets were formed through a dissolution-recrystallization mechanism. Uniform and well-dispersed SnO nanosheets with the round-shape morphology were attained when the solution was treated by ultrasonic sound immediately after the addition of NaOH. The $SnO_2$ nanosheets prepared by means of solution reduction under the ultrasonic treatment, and subsequent oxidation at $600^{\circ}C$ showed a high level of gas sensitivity to $C_2H_5OH$ and $CH_3COCH_3$.

Wettability Evaluation of Sn-0.3Ag-0.7Cu Solder Alloy with Different Flux Activity and Indium Addition (플럭스 활성도 및 In 첨가에 따른 Sn-0.3Ag-0.7Cu 솔더 조성의 젖음 특성 변화)

  • Yu, A-Mi;Kim, Jun-Ki;Kim, Mok-Soon;Hyun, Chang-Yong;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.4
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    • pp.51-57
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    • 2008
  • In this paper, wetting and interfacial reaction properties for low Ag containing Sn-Ag-Cu Pb-free solder alloy, i.e., Sn-0.3Ag-0.7Cu were investigated and compared with those of Sn-1.0Ag-0.5Cu and Sn-3.0Ag-0.5Cu. Melting behavior and stress-strain curves of some Sn-xAg-xCu alloys were also measured using a differential scanning calorimeter(DSC) and a tensile test machine, respectively. In order to enhance insufficient wetting properties of Sn-0.3Ag-0.7Cu alloy, the improvement of wetting properties were analyzed by applying fluxes containing higher content of halide or indium adding of 0.2wt.% into the solder alloy. It was concluded that the small addition of indium is more effective for the improvement of wettability in low temperature range of $230{\sim}240^{\circ}C$ than applying flux containing higher content of halide.

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Effects of Ta addition in Co-sputtering Process for Ta-doped Indium Tin Oxide Thin Film Transistors

  • Park, Si-Nae;Son, Dae-Ho;Kim, Dae-Hwan;Gang, Jin-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.334-334
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    • 2012
  • Transparent oxide semiconductors have recently attracted much attention as channel layer materials due to advantageous electrical and optical characteristics such as high mobility, high stability, and good transparency. In addition, transparent oxide semiconductor can be fabricated at low temperature with a low production cost and it permits highly uniform devices such as large area displays. A variety of thin film transistors (TFTs) have been studied including ZnO, InZnO, and InGaZnO as the channel layer. Recently, there are many studies for substitution of Ga in InGaZnO TFTs due to their problem, such as stability of devices. In this work, new quaternary compound materials, tantalum-indium-tin oxide (TaInSnO) thin films were fabricated by using co-sputtering and used for the active channel layer in thin film transistors (TFTs). We deposited TaInSnO films in a mixed gas (O2+Ar) atmosphere by co-sputtering from Ta and ITO targets, respectively. The electric characteristics of TaInSnO TFTs and thin films were investigated according to the RF power applied to the $Ta_2O_5$ target. The addition of Ta elements could suppress the formation of oxygen vacancies because of the stronger oxidation tendency of Ta relative to that of In or Sn. Therefore the free carrier density decreased with increasing RF power of $Ta_2O_5$ in TaInSnO thin film. The optimized characteristics of TaInSnO TFT showed an on/off current ratio of $1.4{\times}108$, a threshold voltage of 2.91 V, a field-effect mobility of 2.37 cm2/Vs, and a subthreshold swing of 0.48 V/dec.

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A Study on Low-Melting Temperature Sn-In (wt%) Pb-Free Solders for Photovoltaic Ribbons (태양광 리본용 저융점 Sn-In (wt%) 무연 솔더 연구)

  • Dong-Hyeon Shin;Seung-Han Lee;Tae-Sik Cho;Il-Sub Kim
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.2
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    • pp.186-190
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    • 2023
  • We studied the various characteristics of Sn-In (wt%) Pb-free solders for photovoltaic ribbon application. The solders near the eutectic composition of Sn48In52 (wt%) existed in InSn4 and In3Sn alloy phases, and in In crystal phase, but not in Sn crystal phase. In addition, the InSn4 phase (γ-alloy) existed separately from the In3Sn (β-alloy) and the In phase confirmed by an SEM-EDS-mapping. The melting temperature of the eutectic solder of Sn48In52 (wt%) was 119.2℃, and when the Sn content decreased in reference to the eutectic composition, it slightly increased to 121.4℃, but when the Sn content increased, it remained almost constant at 119.1℃. The peel strength of the ribbon plated with the Sn42In58 (wt%) solder was 38.7 N/mm2, and it tended to increase when the Sn content increased. The peel strength of the eutectic Sn48In52 (wt%) solder was 53.6 N/mm2, and that of the Sn51In49 (wt%) solder was 61.6 N/mm2 that was the highest.

The Oxidation Study of Lead-Free Solder Alloys Using Electrochemical Reduction Analysis (전기화학적 환원 분석을 통한 무연 솔더 합금의 산화에 대한 연구)

  • Cho Sungil;Yu Jin;Kang Sung K.;Shih Da-Yuan
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.1 s.34
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    • pp.35-40
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    • 2005
  • The oxidation of pure Sn and Sn-0.7Cu, Sn-3.5Ag, Sn-lZn, and Sn-9Zn alloys at $150^{\circ}C$ was investigated. Both the chemical nature and the amount of oxides were characterized using electrochemical reduction analysis by measuring the electrolytic reduction potential and total transferred electrical charges. X-ray photoelectron spectroscopy (XPS) was also conducted to support the results of reduction analysis. The effect of Cu, Ag and Zn addition on surface oxidation of Sn alloys is reported. For Sn, Sn-0.7Cu and Sn-3.5Ag, SnO grew first and then the mixture of SnO and $SnO_2$ was found. $SnO_2$ grew predominantly for a long-time aging. For Zn containing Sn alloys, both ZnO and $SnO_2$ were formed. Zn promotes the formation of $SnO_2$. Sn oxide growth rate of Pb-free solder alloys was also discussed in terms of alloying elements.

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New Sequence Number(SN*) Algorithm for Cell Loss Recovery in ATM Networks (ATM 네트워크에서 셀손실 회복을 위한 새로운 순서번호($SN^{\ast}$) 알고리즘)

  • 임효택
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.24 no.7B
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    • pp.1322-1330
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    • 1999
  • The major source of errors in high-speed networks such as Broadband ISDN(B-ISDN) is buffer overflow during congested conditions. These congestion errors are the dominant sources of errors in high-speed networks and result in cell losses. Conventional communication protocols use error detection and retransmission to deal with lost packets and transmission errors. As an alternative, we have presented a method to recover consecutive cell losses using forward error correction(FEC) in ATM(Asynchronous Transfer Mode) networks to reduce the problem. The method finds the lost cells by observing new cell sequence number($SN^{\ast}$). We have used the LI field together with SN and ST fields to consider the $SN^{\ast}$ which provides more correcting coverage than SN in ATM standards. The $SN^{\ast}$ based on the additive way such as the addition of LI capacity to original SN capacity is numbered a repeatedly 0-to-80 cycle. Another extension can be based on the multiplicative way such that LI capacity is multiplied by SN capacity. The multiplicative $SN^{\ast}$ is numbered in a repeatedly 0-to-1025 cycle.

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Enhancing Die and Wire Bonding Process Reliability: Microstructure Evolution and Shear Strength Analysis of Sn-Sb Backside Metal (다이 및 와이어 본딩 공정을 위한 Sn-Sb Backside Metal의 계면 구조 및 전단 강도 분석)

  • Yeo Jin Choi;Seung Mun Baek;Yu Na Lee;Sung Jin An
    • Korean Journal of Materials Research
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    • v.34 no.3
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    • pp.170-174
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    • 2024
  • In this study, we report the microstructural evolution and shear strength of an Sn-Sb alloy, used for die attach process as a solder layer of backside metal (BSM). The Sb content in the binary system was less than 1 at%. A chip with the Sn-Sb BSM was attached to a Ag plated Cu lead frame. The microstructure evolution was investigated after die bonding at 330 ℃, die bonding and isothermal heat treatment at 330 ℃ for 5 min and wire bonding at 260 ℃, respectively. At the interface between the chip and lead frame, Ni3Sn4 and Ag3Sn intermetallic compounds (IMCs) layers and pure Sn regions were confirmed after die bonding. When the isothermal heat treatment is conducted, pure Sn regions disappear at the interface because the Sn is consumed to form Ni3Sn4 and Ag3Sn IMCs. After the wire bonding process, the interface is composed of Ni3Sn4, Ag3Sn and (Ag,Cu)3Sn IMCs. The Sn-Sb BSM had a high maximum shear strength of 78.2 MPa, which is higher than the required specification of 6.2 MPa. In addition, it showed good wetting flow.

The effects of Zr on the mechanical workability in Cu-Ni-Mn-Sn connector alloys (커넥터용 Cu-Ni-Mn-Sn계 합금의 가공성에 미치는 Zr 첨가효과)

  • Han, Seung-Zeon;Kong, Man-Shik;Kim, Sang-Shik;Kim, Chang-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.246-249
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    • 2000
  • The effects of Zr on the mechanical workability and tensile strength of Cu-Ni-Mn-Sn-Al alloys have been investigated and the following results were obtained. The mechanical workability of Cu-Ni-Mn-Sn-Al alloys are increased with addition of Zr. And the surface cracks of specimen were not produced in Zr added Alloys. Especially in condition of hot-worked beyond the 90% working ratio, Zr contained specimen showed intra-granule crack propagation but Zr-free specimen showed inter-granule mode. The tensile strength have maximum value in 0.05% Zr contained alloy. The aging mechanism of Cu-Ni-Mn-Sn-Al alloys were varied by Zr addition.

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Comparing the methods of making $SnO_2$ nanomaterials with and without templates of anode material for Li-ion battery (Li-ion battery용 음극재료인 $SnO_2$의 합성법의 차이에 따른 음극 성능비교)

  • Shim, Young-Sun;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.132.2-132.2
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    • 2010
  • Mesoporous tinoxide ($SnO_2$) as anode materials for Li-ion battery were prepared by hydrothermal method and templating method using SBA-15 as template. And electrochemical properties of $SnO_2$ electrode were investigated with cyclic voltammogram (CV). The morphology and structures of $SnO_2$ were characterized by transmission electron microscopy (TEM) and X-ray diffractometer (XRD), respectively. The specific surface area was defined by $N_2$ adsorption with BET(Brunauer-Emmett-Teller) method. As a result, the surface area of mesoporous $SnO_2$ which was made from templating method is higher than the case of using hydrothermal method. In addition, in anodic performance, mesoporous $SnO_2$ which is prepared by templating method showed higher charge-discharge capasity compared to hydrothermal method and exhibited excellent stability over the entire cycle number. It was indicated that electrochemical performances of mesoporous $SnO_2$mainly affected to the structural features, such as specific surface area and porosity.

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