• Title/Summary/Keyword: Smectic

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Synthesis and mesomorphic properties of biphenly thioester series in ferroelectric liguke crystal (Biphenyl thioester 계열 강유전성액정의 합성 및 물성에 관한 연구)

  • Jeon, Yeong-Jae
    • Korean Journal of Materials Research
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    • v.3 no.1
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    • pp.72-83
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    • 1993
  • Abstract A new and versatile method for the preparation of biphenyl thioester series was studied in ferroelectric liquid crystal. Many of the resulting liquid crystal showed a ferroelectric chiral smectic C phase in addition to the chiral nematic and smectic A phase. We obtained a large spontaneous polarization exceeding $10^{-8}$C/c$m^2$ in new biphenyl thioester series. It was found that the size and polarity of the substituent in chiral carbon influenced the magnitude of spontaneous polarization. The series allow us to determine the influence of substituent size in the chiral carbon the existence and the stability of the Sc* phase.

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Nes ferroelectric liquid crystal having bipeny1 ester core group (중심그룹으로 Bipheny1 ester기를 갖는 새로운 강유전성 액정)

  • Jeon, Yeong-Jae;Lee, Jong-Cheon;Kim, Yong-Bae
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.695-703
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    • 1994
  • Some 4-(4-alkyloxybenzoyloxy)-4'-(S)-$\alpha$-chloro-alkanoyloxybiphenyls have been synthesized and their mesomorphic properties were studied. They show a ferroelectric chiral smectic C phase in addition to the chiral nematic and smectic A phase. We obtained a large spontaneous polarization exceeding $10^{-7}\textrm{cm}^2$ in new biphenyl ester series.

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Thermo-Recording for The Composite System of (Disk-Like Molecules and Liquid Crystals)

  • Jeong, Hwan-Kyeong
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.3
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    • pp.245-249
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    • 2002
  • A (disk-like liquid crystal (DLC) monomer/liquid crystals(LCs)/chiral dopant/dichroic dye) composite was irradiated with ultraviolet (UV) light. The (DLC network/LCs/chiral dopant/dichroic dye) was formed in the homeotropically oriented smectic A(SA) phase by the surface orientation treatment and the electric field. A focal-conic texture exhibiting strong light scattering appeared in the heat-induced chiral nematic phase(N${\ast}$) of the composite upon heating. Thermo-recording in the composite system has been realized by using a He-Ne laser. The laser irradiation was induced the phase transitions from SA phase to chiral nematic(N${\ast}$) phase in the composite system.

Enhanced flexoelectric switching made from self-assembly of smectic liquid crystal and triallyl dopant

  • Lim, Tong-Kun;Lee, Ji-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.175-177
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    • 2006
  • Here we report an enhanced flexoelectric switching in a self-assembled system of smectic liquid crystal and some specific dopant. The assembled unit block seemed to have electric dipole and as a result induces large flexoelectric polarization due to its asymmetric shape and shows fast switching to the electric field. The unit blocks are oriented in a helical fashion in the cell with large gap (${\sim}5{\mu}m$) and shows selective reflection property. In the thin cell (${\sim}2{\mu}m$), the unit blocks are aligned homeotropically on the bare ITO substrate with no surface treatment and shows fast decaying time.

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Dependence of Retardation Dispersion on the Ultraviolet Polarization Direction During Photopolymerization of Self-organized Smectic Reactive Mesogen Molecules

  • Jeong, Jinyoung;Choi, Yu-Jin;Jeong, Kwang-Un;Lee, Ji-Hoon
    • Current Optics and Photonics
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    • v.2 no.3
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    • pp.286-290
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    • 2018
  • We investigated the dependence of the retardation dispersion on the polarization direction of ultraviolet (UV) light during the photopolymerization of self-organized smectic reactive mesogen (RM) molecules. RM retarder film that was photopolymerized with UV light linearly polarized parallel to the layer plane showed negative dispersion (ND) of retardation for a wide range of UV polymerization temperatures. On the other hand, film that was photopolymerized with unpolarized UV light showed negative dispersion in a narrow range of UV polymerization temperatures. With a certain UV polymerization temperature, the dispersion of retardation was converted from positive to negative, depending on the UV polarization.

Dimesogenic Compounds Consisting of Two Identical Terminal N-(4-Oxybenzylidene)-4-n-butylaniline Units and a Central Polymethylene Spacer

  • Jung-Il Jin;Bong Young Chung;Joo-Hoon Park
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.583-588
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    • 1991
  • A series of dimesogenic compounds having two identical, terminal Schiff base type mesogens and a central polymethylene spacer were prepared and their properties were compared with those of the corresponding monomesogenic compounds. The mesomorphic properties of the compounds were studied by differential scanning calorimetry and on a hot-stage of a polarizing microscope. All of the dimesogenic compounds formed mesophases enantiotropically with the exception of pentamethylene-1,5-bis(4-oxybenzylidene 4-n-butylaniline). This compound was monotropic and formed only a nematic phase on heating the solid, whereas it formed nematic as well as smectic A phases on cooling the isotropic liquid. Those compounds containing longer (octamethylene and decamethylene) spacers favored the formation of nematic phase whereas those having shorter (dimethylene and tetramethylene) spacers formed smectic phases. In general, the variety of mesophase forms exhibited by the dimesogenic compounds was significantly less than that shown by the corresponding monomesogenic compounds.