• Title/Summary/Keyword: Small molecule

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Concepts for solution-processable OLED materials at Merck

  • Hayer, A.;Anemian, R.;Eberle, T.;Heun, S.;Ludemann, A.;Schulte, N.;Buchholz, H.
    • Journal of Information Display
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    • v.12 no.1
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    • pp.57-59
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    • 2011
  • Drastic performance increase and accelerated progress in organic light-emitting diodes from solutions are shown using solution-processable small molecules based on the core structures of vacuum-evaporable materials. Systematic modification of small-molecule materials toward better processability from solutions at identical electro-optical properties is shown. This is demonstrated to lead to a significant improvement in the device performance.

Theoretical Study on Structures and Energetics of Small Water Clusters

  • Park Yeong Jae;Kang Young Kee;Yoon Byoung Jip;Jhon Mu Shik
    • Bulletin of the Korean Chemical Society
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    • v.3 no.2
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    • pp.50-55
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    • 1982
  • A study of small water clusters composed of two to seven molecules has been performed by using the revised empirical potential function for conformational analysis (REPFCA). Various structures of clusters have been investigated and the relative probability of cluster per molecule is discussed. In general, cyclic structures of water clusters are more favorable than open structures. It is found that cyclic pentamer is the most favorable unit structure in the water cluster.

About the Influence of the Molecular Structure of selected classes of small molecules on their thermal behavior

  • Richter, Andreas M.;Lischewski, Volker;Felicetti, M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.812-815
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    • 2004
  • The molecular structure influences the thermal behavior of HTM. For OLED the glass transition temperature and evaporation temperature are critical. We report how changes in structure cause changes on both parameters. The results may be of interest for chemists when they design new molecule structures for OLED.

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Current Status of OLEDs Technology

  • Kim, Sung-Tae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.229-230
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    • 2000
  • The current status of OLEDs technology is reviewed. Comparison has been made between small molecule based OLEDs and polymer LEDs. In addition, advantages of OLEDs technology and technical issues for commercialization are addressed. Details of these issues will be discussed at the meeting.

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Recent Advances in Performance of Solution Processed Small Molecule OLEDs at DuPont Displays

  • LeCloux, Daniel D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.340-343
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    • 2007
  • We describe the DuPont Displays full color OLED printing and materials technologies. The process is more cost-effective and scalable than thermal evaporation through shadow masks. The materials lifetime is sufficient for most portable applications and is nearing that required for stationary displays. Recently, 4.3" WQVGA displays were demonstrated.

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Pre-Clinical Research with Biotechnology Products

  • Berryman, Leigh
    • Proceedings of the Korean Society of Toxicology Conference
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    • 2003.10b
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    • pp.84-85
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    • 2003
  • The process of drug development has seen major changes over the last two decades with the movement away from standard small molecule drug discovery programs, through computer-assisted drug design methodologies towards biotechnologically derived products. The aim of duplication of endogenously active materials to be administered exogenously has enormous impact on development practices and evaluation of safety.(omitted)

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A New Analytical Method to Determine the Purity of Synthetic Fluorophores using Single Molecule Detection Technique

  • Song, Nam-Yoong;Kim, Hyong-Ha;Park, Tae-Sook;Yoon, Min-Joong
    • Journal of Photoscience
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    • v.12 no.2
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    • pp.87-93
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    • 2005
  • A new assay technique to distinguish between pure compounds and the isomeric mixtures has been suggested using single molecule (SM) fluorescence detection technique. Since the number of emission spots in a fluorophorespread film prepared from a genuine dye solution was determined by experimental condition, the deviation of spot numbers from the expected values could be considered to be an indication of lower purity of the sample solution. The lower limit of sample concentration for this assay was determined to be $5{\times}10^{-10}$ M to show uniform number of expected spots within 10% uncertainties in our experimental condition. An individual fluorescence intensity distribution for a mixture of isomers having doubly different emissivities was simulated by adding distributions obtained from Cy3 and nile red (NR) independently. The result indicated that the mixture could be identified from the pure compounds through the difference in the number of Gaussian functions to fit the distribution. This new assay technique can be applied to the purity test for synthetic biofluorophores which are usually prepared in small quantities not enough for classical ensemble assays.

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Self-Assembled Chiral Structures of Discoid Organic Molecule on Au(111)

  • Kim, Ji-Hoon;Khang, Se-Jong;Kwon, Young-Kyun;Park, Yongsup
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.280-280
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    • 2013
  • Using both experimentaland theoretical methods, we have investigated the structural and electronic properties of self-assembled two-dimensional organic molecule (hexaaza-triphenylene-hexacarbonitrile, HATCN), which is used as an efficient OLED hole injection material, on Au(111) surfaces. Low-temperature scanning tunneling microscope (STM) measurements revealed that self-assembled linear and hexagonal porous structures are formed at atomic steps and terraces of Au(111), respectively. We also found that the hexagonal porous structure have chirality and forms only small (<1,000 nm2) phase-separated chiral domains that can easily change their chiral phase in subsequence STM images at 80 K. To explain these observations, we calculated the molecular-molecular and molecule-surface interaction energies by using first-principles density functional theory method. We found that the change of their chiral phase resulted from the competition between the two energies. These results have not only verified our experimental observations, but also revealed the delicate balance between different interactions that caused the self-assembed structures at the surface.

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