• Title/Summary/Keyword: Small fuel cells

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Development of Microbial Fuel Cells Using Proteus vulgaris

  • Kim, Nam Jun;Choe, Yeong Jin;Jeong, Seon Ho;Kim, Seong Hyeon
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.44-48
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    • 2000
  • Microbial fuel cells comprising the microorganism P. vulgaris, thionin as a mediator, and various mono- and disaccharides in an anodic compartment have been developed. A cathodic compartment containing a Pt electrode and Fe$(CN)_6^{3-}$ was separated from an anode by the Nafion membrane. From absorbance-time measurements, it was found that the absorbance of thionin was not altered by the addition of P. vulgaris, even in the presence of sugars. However, thionin was effectively reduced when P. vulgaris was present. These results differ substantially from the case of safranine O, a phenazine-derivative, indicating that thionin takes up electrons during the metabolic oxidation processes of carbohydrates. Maximum fuel cell efficiency was observed at 37 $^{\circ}C$, optimum temperature for the growth of P. vulgaris, and 0.5 V cell voltage was obtained, which indicates that the metabolism of the microorganism directly affects the efficiency. Thionin concentration was closely related to cell performance. When the charging-discharging characteristics were tested with glucose, galactose, sucrose, maltose, and trehalose as carbon sources, galactose was found to give the highest coulombic efficiency. Cell performance was almost fully recovered with only small degradation when glucose and sucrose were used in the repetitive operation. Current was maintained nearly twice as long for sucrose than in the case of glucose.

A Conceptual Design Study for a Spent Fuel Pyroprocessing Facility of a Demonstration Scale (사용후핵연료 파이로 처리공정 실증시설의 개념설계 연구)

  • Yoo, Jae-Hyung;Hong, Kwon-Pyo;Lee, Han-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.3
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    • pp.233-244
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    • 2008
  • A conceptual design study for a pyroprocesing facility, has been carried out in this study, which is available for the recovery of uranium and transuranic elemental group(TRU), that is, reusable as a nuclear fuel especially in a next generation-type reactor. The scale of this facility has been chosen as 20 kg HM/batch, comparatively small engineering size in order to collect scale-up data for the design of a commercial facility as well as to get operational experience. The spent fuel to be handled in this process is as follows : 3.5 % enriched uranium fuel, 35,000MWd/tU and 5-year cooled. The major items considered in the conceptual study are a building lay-out including various hot cells, safety management of the process operation in conjunction with material balance control, radiation safety, inert atmosphere control in shielded hot cells, and criticality control of uranium and TRU products.

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The Performance Evaluation of Metallic Bipolar Plates of Fuel Cells for a Small Reconnaissance UAV (소형 정찰 UAV를 위한 연료전지 금속 분리판의 성능 평가)

  • Kim, Ki-In;Lee, Jong-Kwang;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.278-281
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    • 2009
  • The performance of aluminum bipolar plates was evaluated for the lightweight fuel cell system as a power source for a small reconnaissance UAV. Higher performance per weight was obtained from aluminum bipolar plates than the graphite bipolar plates. To check the influence of operating temperature, the performance of a single cell using aluminum bipolar plates was evaluated at 40 / 50 / $60^{\circ}C$. When dry hydrogen and air were used, the finest performance was obtained at $40^{\circ}C$, a lower operating temperature compared with usual operating temperatures.

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A Study on Performance Improvement in PEMFC (소면적 PEM연료전지 성능개선 연구)

  • Chon, Kwang Wu;Park, Chang Kwon;Lee, Ho Yeol;Oh, Byeong Soo
    • Journal of Hydrogen and New Energy
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    • v.15 no.4
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    • pp.291-300
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    • 2004
  • Performance of PEMFC is affected by many factors such as that of MEA, configuration of flow field, operating conditions, humidification, cooling and so on. In this study, in order to improve the performance of fuel cell, a small area fuel cell stack was made and its performance was tested under various operating conditions. Stack consists of 3 single PEM fuel cells. Channel is serpentine type and the active area of the electrode is $50cm^2$. The test results show that the peak power is 60W at $70^\circ{C}$ of stack temperature with humidification condition.

A Study on the Optimum Design for LTCC Micro-Reformer: Design and performance evalution of monolith fuel reformer/PROX (LTCC를 소재로 하는 마이크로 리포머의 최적 설계에 관한 연구 ; 일체형 Reformer/PROX 반응기의 설계 및 성능평가)

  • Chung, C.H.;Oh, J.H.;Jang, J.H.;Jeong, M.K.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.10a
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    • pp.615-616
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    • 2006
  • A micro-fuel processor system integrating steam reformer and partial oxidation reactor was manufactured using low temperature cofired ceramic (LTCC). A CuO/ZnO/$Al_2O_3$ catalyst and Pt-based catalyst prepared by wet impregnation were used for steam reforming and partial oxidation, respectively. The performance of the LTCC micro-fuel processor was measured at various operating conditions such as the effect of the feed flow rate, the ratio of $H_2O/CH_3OH$, and the operating temperature on the LTCC reformer and CO clean-up system. The catalyst layer was loaded with "Fill and Dry" coating for small volume. The product gas was composed of $70\sim75%$ hydrogen, $20\sim25%$ carbon dioxide, and $1\sim2%$ carbon monoxide at $250\sim300^{\circ}C$, respectively.

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A Study on the Catalysts for Hydrogen Generation Reaction Using NaBH4 Solution (NaBH4를 이용한 수소발생반응의 촉매에 관한 연구)

  • Jeong, SeougUk;Cho, EunAe;Oh, In-Hwan;Hong, Sunn-Ahn;Kim, Sung-Hyun;Seo, Yong Gyo
    • Journal of Hydrogen and New Energy
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    • v.14 no.2
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    • pp.114-121
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    • 2003
  • Hydrogen generation system using aqueous $NaBH_4$ solution was developed for feeding small polymer electrolyte membrane fuel cells (PEMFCs). Ru was selected as a catalyst with its high activity for the hydrogen generation reaction. Hydrogen generation rate was measured with changing the solution temperature, amount of catalyst loading, $NaBH_4$ concentration, and NaOH (a base-stabilizer) concentration. A passive air-breathing 2 W PEMFC stack was operated on hydrogen generated using $20wt%\;NaBH_4+5wt%$ NaOH solution and Ru catalyst.

Enhancement of the energy efficiency of hydrogen SOFC system by integrated cold energy utilization and waste heat recovery method

  • Nguyen Quoc Huy;Duong Phan Anh;Ryu Bo Rim;Lee Jin Uk;Kang Ho Keun
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2022.11a
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    • pp.160-161
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    • 2022
  • Hydrogen is bridge fuel with high energy content and environmentally friendly to satisfy the stringent IMO regulation relating to greenhouse gas (GHG) emissions. There is growing interest in hydrogen in numerous nations and regions illustrated by an extensive range of research and development in technology. Regarding maritime applications, researchers have recognized the utilization of hydrogen as a fuel for fuel cells, a device that converts the chemical energy of the fuel to electrical energy. Solid oxide fuel cell (SOFC), with high working temperature, is easy to combine with the waste heat recovery cycles/devices to increase output power and thermodynamic performances as well. Furthermore, the cold energy from liquid hydrogen supplied to SOFC can also be used to generate more power. In this study, we proposed a SOFC integrated system with the idea of combining the waste heat recovery from the SOFC exhaust stream and cold energy utilization from LH2. The designation is aimed to target small-scale vessel which uses electric propulsion for short distances voyage.

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Thermal-Hydraulic Analysis and Parametric Study on the Spent Fuel Pool Storage (기사용 핵연료 저장조에 대한 열수력 해석 및 관련 인자의 영향 평가)

  • Lee, Kye-Bock;Nam, Ki-Il;Park, Jong-Ryul;Lee, Sang-Keun
    • Nuclear Engineering and Technology
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    • v.26 no.1
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    • pp.19-31
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    • 1994
  • The objective of this study is to conduct a thermal-hydraulic analysis on the spent fuel pool and to evaluate a parametric effect for the thermal-hydraulic analysis of spent fuel pool. The selected parameters are the Reynolds Number and the gap flow through the oater gap between fuel cell and fuel bundle. The simplified flow network for a path of fuel cells is used to analyze the natural circulation phenomenon. In the flow network analysis, the pressure drop for each assembly from the entrance of the fuel rack to the exit of the fuel assembly is balanced by the driving head due to the density difference between the pool fluid and the average fluid in each spent fuel assembly. The governing equations ore developed using this relation. But, since the parameters(flow rate, pressure loss coefficient, decay heat, density)are coupled each other, iteration method is used to obtain the solution. For the analysis of the YGN 3&4 spent fuel rack, 12 channels are considered and the inputs such as decay heat and pressure loss coefficient are determined conservatively. The results show the thermal-hydraulic characteristics(void fraction, density, boiling height)of the YGN 3&4 spent fuel rack. There occurs small amount of boiling in the cells. Fuel cladding temperature is lower than 343.3$^{\circ}C$. The evaluation of parametric effect indicates that flow resistances by geometric effect are very sensitive to Reynolds number in the transition region and the gap flow is negligible because of the larger flow resistance in the gap flow path than in the fuel bundle.

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A Fuel Cell Generation Modeling and Interconnected Signal Analysis using PSCAD/EMTDC (연료전지 발전시스템의 PSCAD/EMTDC 모델링 및 계통연계에 따른 전력신호 분석에 관한 연구)

  • Choi, Sang-Yule;Park, Jee-Woong;Lee, Jong-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.5
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    • pp.21-30
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    • 2008
  • The fuel cell generation convert fuel source, and gas directly to electricity in an electro-chemical process. Unlike traditional and conventional turbine engines, the process of fuel cell generation do not burn the fuel and run pistons or shafts, and it has not revolutionary machine, so have fewer efficiency losses, low emissions and no noisy moving parts. A high power density allows fuel cells to be relatively compact source of electric power, beneficial in application with space constraints. In this system, the fuel cell itself is nearly small-sized by other components of the system such as the fuel reformer and power inverter. So, the fuel cell energy's stationary fuel cells produce reliable electrical power for commercial and industrial companies as well as utilities. In this paper, a fuel cell system has been modeled using PSCAD/EMTDC to analyze its electric signals and characteristics. Also the power quality of the fuel cell system has been evaluated and the problems which can be occurred during its operation have been studied by modeling it more detailed. Particularly, we have placed great importance on its power quality and signal characteristics when it is connected with a power grid.

Miniature planar stack using the flexible Printed Circuit Board as current collectors (연성 기판을 전류 집전체로 사용한 평판형 연료전지 스택)

  • Kim, Sung-Han;Cha, Hye-Yeon;Miesse, Craig M.;Cha, Suk-Won;Jang, Jae-Hyuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.1-4
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    • 2008
  • Fuel cells have the potential of providing several times higher energy storage densities than those possible using current state-of-the-art lithium-ion batteries, but current energy density of fuel cell system is not better than that of lithium-ion batteries. To achieve the high energy density, volume and weight of fuel cell system need to be reduced by miniaturizing system components such as stack, fuel tank, and balance-of-plant. In this paper, the thin flexible PCB (Printed circuit board) is used as a current collector to reduce the stack volume. Two end plates are made from light weight aluminum alloy plate. The plate surface is wholly oxidized through the anodizing treatment for electrical insulation. The opening rate of cathode plate hole is optimized through unit cell performance measurement of various opening rates. The performances are measured at room temperature and ambient pressure condition without any repulsive air supply. The active area of MEA is 10.08 $cm^2$ and active area per a unit cell is 1.68 $cm^2$. The peak power density is about 210 mW/$cm^2$ and the air-breathing planar stack of 2 Wis achieved as a small volume of 18 cc.

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