• 제목/요약/키워드: Small Reaction Volume

검색결과 88건 처리시간 0.023초

효율적인 Micromixer의 통합된 기능 평가 및 Glucose-Catalysts 반응에 적용 (Integrated function evaluation of efficient micromixer and application to glucose-catalysts reaction)

  • 김덕중;백주열;이상훈
    • 센서학회지
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    • 제14권5호
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    • pp.291-296
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    • 2005
  • In this paper, the PDMS based micromixer having 3-dimension triangular structure has been developed for the reaction of samples in the micro volume. The mixing efficiency was measured according to the change of Reynolds number (Re: 0.08, 0.8, 8, 16) and channel height (100, 200, $300{\mu}m$). Total length of mixing region is 7.4 mm and the measured mixing efficiencies at the outlet were over 85 %. Within the mixing length 2.4 mm, the mixing efficiencies were more than 70 % at any Reynolds numbers, and this indicates the strong mixing has occurred inside the mixing channel due the triangular structures. By employing these 2 mixers, we have fabricated the microreactor to detect the glucose-catalysts reaction. The microreactor showed good reactivity of glucose and enzymes with the small amount of sample solution.

중.소형 폐기물소각로 및 배연탈황공정용 홍합(Hard-Shelled Mussel) 패각페기물 Sorbent 적용에 관한 연구 (A Study on Sorbent Application of Hard-Shelled Mussel Waste Shell on the Medium/small Scale Waste Incinerator and Flue Gas Desulfurization Process)

  • 정종현
    • 한국환경보건학회지
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    • 제29권1호
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    • pp.34-42
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    • 2003
  • The objective of this study is to investigate the waste recycling possibility, practicability, economic efficiency and acid gas sorbent use of the hard-shelled mussel. This study is to investigate the hydration/calcination reaction and fixed bed reactor. The physical-chemical characteristics of the hard-shelled mussel were analyzed by ICP SEM-EDX, BET and pore volume. Thus, the results could be summarized as follows; Hard-shelled mussel can be used as iron-manufacture and chemical sorbents considering more than 53.7% of the mussel is lime content. The SO$_2$removal efficiency of the hard-shelled mussel after calcined hydration increased thirty times as a result of the higher pore size, specific surface area and pore volume. Also, the CaO content, pore volume, pore size distribution and specific surface area greatly influenced the SO$_2$ and NOx removal reactivity. The optimum particle diameter average of hard-shelled mussel was $\pm$100 mesh, which was applied to the sorbent on the medium/small scale waste incinerator and flue gas desulfurization processes.

Radiographic patterns of periosteal bone reactions associated with endodontic lesions

  • Poorya Jalali;Jessica Riccobono;Robert A. Augsburger;Mehrnaz Tahmasbi-Arashlow
    • Restorative Dentistry and Endodontics
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    • 제48권3호
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    • pp.23.1-23.8
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    • 2023
  • Objectives: The formation of new bone by periosteum due to an insult is called periosteal bone reaction (PBR). This study assessed the cone beam computed tomography (CBCT) patterns of periosteal bone reactions associated with periapical inflammatory lesion (apical periodontitis/periapical rarefying osteitis). Materials and Methods: Twenty-two small field of view CBCT images of patients with PBR were selected from a database of a private practice limited to endodontics. The volume of the periapical inflammatory lesion, the presence of cortical fenestration, the distance of the root apices to the affected cortex, and the location, pattern, and longest diameter of the periosteal reaction were recorded. Statistical analysis was performed using Wilcoxon Ranksum, Fischer's exact, Spearman Correlation Coefficient, and paired t-test. Results: In all cases, periosteal bone reaction manifested as either parallel (90.9%) or irregular (9.1%). No correlation was found between periapical inflammatory lesion volume and the periosteal reaction's longest diameter (p > 0.05). Cortical fenestration was noted in 72.7% of the cases. In addition, the findings showed that periosteal reactions were located mostly on the buccal and were present 53.8% and 100% of the time in the mandible and maxilla, respectively. Conclusions: The periosteal reactions of endodontic origin had a nonaggressive form (i.e., parallel or irregular), and none of the lesions resulted in a periosteal reaction with an ominous Codman's triangle or spicule pattern.

홍조류인 한국산 김종에서의 염색체 DNA 분리방법 (Rapid and Efficient Purification of Nucleic Acids from the Macroalga Porphyra(Rhodophyta))

  • 류태형;최학선;최경희;이춘환
    • 한국식품영양과학회지
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    • 제27권6호
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    • pp.1166-1172
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    • 1998
  • A method for the isolation and purification of DNA from a red algae, Porphyra was innovated. The innovation of the method consists mainly of three steps that include sodium acetate treatment, chloroform extraction, and 0.2 volume isopropanol precipitation step. The sodium acetate treatment was designed to remove polysaccharide contamination, and the isopropanol step to remove proteins and salts contaminents. Genomic DNA,s of several species(for example, P. tenera, P. yezoensis, P. seriata, and P. pseudolinearis) was successfully isolated by the innovated method. The amount of DNA purified from one g of sample material with the innovated method was 53 g in average. The resulting DNA was characterized to include high molecular weight and showed no nuclease activity. The DNA was pure enough to be digested directly by various restriction enzymes without any difficulties. Porphyra DNA was pure enough and adequate for amplification reaction through the polymerase chain reaction (small nuclear rDNA PCR amplification).

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비담지 촉매를 이용한 NaBH4 가수분해반응에서 부산물의 특성 (Characteristics of Byproduct After NaBH4 Hydrolysis Reaction Using Unsupported Catalyst)

  • 이혜리;박대한;주원;나일채;박권필
    • Korean Chemical Engineering Research
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    • 제55권1호
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    • pp.13-18
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    • 2017
  • 무인항공기용 고분자전해질 연료전지의 수소발생용으로써 $NaBH_4$는 많은 장점을 갖고 있다. 무인항공기용으로 이용하기 위해서는 $NaBH_4$ 가수분해 반응 후 부산물의 무게와 부피가 작아야 한다. 그래서 본 연구에서는 비담지 촉매를 사용한 $NaBH_4$ 가수분해 반응 후 부산물의 무게와 부피에 대해 연구하였다. 촉매 형태, $NaBH_4$ 농도, NaOH 농도, 촉매팩 두께 등이 부산물의 무게와 부피에 미치는 영향에 대해 연구하였다. 본 실험 조건에서 발생한 부산물은 대부분 $NaB(OH)_4$였고, 거품이 발생하여 부피가 증가하였다. 안정화제인 NaOH 농도는 부산물의 무게와 부피에 별 영향을 주지 않았다. $NaBH_4$ 농도가 증가하면 부산물 무게가 감소하였으나, $NaBH_4$ 농도 23 wt%에서 최고 부피를 나타냈다. 소포제를 이용해 부산물의 부피를 감소시킬 수 있었다.

석영관 광촉매 반응기를 이용한 Rhodamine B의 색도 제거 (Decolorization of Rhodamine B Using Quartz Tube Photocatalytic Reactor)

  • 박영식
    • 한국환경보건학회지
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    • 제30권5호
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    • pp.358-365
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    • 2004
  • The photocatalytic oxidation of Rhodamine B(RhB) was studied using photocatalytic reactor filled with module of quartz tube. Module of quartz tube consisted of small quartz tube (inner diameter, 1.5 mm; outer diameter, 3 mm) bundle coated with powder $TiO_2$ and uncoated large quartz tube (inner diameter, 20 mm; outer diameter, 22 mm). Two 30 W germicidal lamp was used as the light source and the reactor volume was 0.5 l. The effects of parameters such as the coating materials and numbers, initial concentration, $H_{2}O_2$ dose and metal deposition (Ag, Pt and Fe) and simultaneous application of $H_{2}O_2$ and metal deposition. The results showed that the initial reaction constant of quartz module coated with powder $TiO_2$ was higher 1.4 time than that of the $TiO_2$ sol and optimum coating number is twice. In order to increase reaction rate, simultaneous application of photocatalytic and photo-fenton reaction using Fe coating and dose $H_{2}O_2$ dose increased reaction rate largely.

수중 환경에서 고분자 전해질 연료전지(PEMFC) 공급용 수소 생산을 위한 가압 디젤 개질시스템에 관한 연구 (Study on Pressurized Diesel Reforming System for Polymer Electrolyte Membrane Fuel Cell in Underwater Environment)

  • 이광호;한광우;배중면
    • 한국군사과학기술학회지
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    • 제20권4호
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    • pp.528-535
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    • 2017
  • Fuel cells have been spotlighted in the world for being highly efficient and environmentally friendly. A hydrogen which is the fuel of fuel cell can be obtained from a number of sources. Hydrogen source for operating the polymer electrolyte membrane fuel cell(PEMFC) in the current underwater environment, such as a submarine and unmanned underwater vehicles are currently from the metal hydride cylinder. However, metal hydride has many limitations for using hydrogen carrier, such as large volume, long charging time, limited storage capacity. To solve these problems, we suggest diesel reformer for hydrogen supply source. Diesel fuel has many advantages, such as high hydrogen storage density, easy to transport and also well-infra structure. However, conventional diesel reforming system for PEMFC requires a large volume and complex CO removal system for lowering the CO level to less than 10 ppm. In addition, because the preferential oxidation(PROX) reaction is the strong exothermic reaction, cooling load is required. By changing this PROX reactor to hydrogen separation membrane, the problem from PROX reactor can be solved. This is because hydrogen separation membranes are small and permeable to pure hydrogen. In this study, we conducted the pressurized diesel reforming and water-gas shift reaction experiment for the hydrogen separation membrane application. Then, the hydrogen permeation experiments were performed using a Pd alloy membrane for the reformate gas.

일차원 액적 배열의 화염 퍼짐에 있어서 연료의 혼합 효과에 관한 연구 (A Study on Blend Effect of Fuel in Flame Spread Along An One-Dimensional Droplet Array)

  • 박정;소림수소;신강숭
    • 한국연소학회지
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    • 제3권2호
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    • pp.1-11
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    • 1998
  • Experimental investigation on flame spread of blended fuel droplet arrays has been conducted for droplet diameters of 1.0mm and 0.75mm using high-speed chemiluminescence images of OH radical. The flame spread rate is measured with blended fuel composition, droplet diameter, and droplet spacing. Flame spread is categorized into two: a continuous mode and an intermittent one. There exist a limit droplet spacing, above which flame does not spread, and a droplet spacing of maximum flame spread, which is closely related to flame diameter. It is seen that flame spread rate is mainly dependent upon the relative position of flame zone within a droplet spacing. In case of large droplet, the increase of % volume of Heptane induces the shift of limit droplet spacing to a larger spacing since volatile Heptane plays a role of an enhancer of flame spread rate. In case of small droplet, the increase of % volume of Heptane leads to the shift of limit droplet spacing to a smaller droplet spacing. This is so because of the delayed chemical reaction time by the rapid increase of mass flux of fuel vapor for small droplet.

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편심된 실의 누설량 및 동특성계수 해석 (Rotordynamic and Leakage Analysis for Eccentric Annular Seal)

  • 하태웅;이용복;김창호
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2001년도 춘계학술대회논문집
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    • pp.528-534
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    • 2001
  • Basic equations and its solution procedure are derived for the analysis of an annular pump seal in which the rotor has a large static displacement from the centered position. The Bulk-flow is assumed for a control volume set in the seal clearance and the flow is assumed to be completely turbulent in axial and circumferential direction. Moody's wall-friction-factor formula is used for the calculation of wall shear stresses in the control volume. For the reaction force developed by the seal, linearized zeroth-order and first-order perturbation equations are developed for small motion about an eccentric position. Flow variables are expanded by using Fourier series for the solution procedure. Integration of the resultant first-order pressure distribution along and around the seal defines the 12 elements of rotordynamic coefficients of the eccentric annular pump seal. The results of leakage and rotordynamic coefficients are presented and compared with the Marquette's experimental results and the San Andres' theoretical analysis.

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압축기용 계단식 래버린스 실의 누설 및 동특성해석 (Rotordynamic and Leakage Analysis for Stepped-Labyrinth Gas Seal)

  • 하태웅;이안성
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2000년도 춘계학술대회논문집
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    • pp.1084-1089
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    • 2000
  • The basic equations are derived for the analysis of a stepped labyrinth gas seal which are generally used in high performance compressors, gas turbines, and steam turbines. The Bulk-flow is assumed for a single cavity control volume and the flow is assumed to be completely turbulent in circumferential direction. Moody's wall-friction-factor formula is used for the calculation of wall shear stresses in the single cavity control volume. For the reaction force developed by the seal, linearized zeroth-order and first-order perturbation equations are developed for small motion about a centered position. Integration of the resultant first-order pressure distribution along and around the seal defines the rotordynamic coefficients of the stepped labyrinth gas seal. The leakage and rotordynamic characteristic results of the stepped labyrinth gas seal are presented and compared with Scharrer's theoretical analysis using Blasius' wall-friction-factor formula.

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