• Title/Summary/Keyword: Slurry density

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Characteristics of Large Green and Sintered Alumina Ceramics by Filter Pressing (필터 프레싱으로 제조한 대형 알루미나 세라믹스 성형체 및 소결체의 특성)

  • Lee, Hyun-Kwuon;Cho, Kyeong-Sik;Jang, Min-Hyeok;Jang, Chul-Woo;Kim, Sang-Mo;Kim, Mi-Young
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.306-312
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    • 2009
  • The size of various alumina ceramics used in semiconductor and display industry is also required to increase with increase in wafer and panel size. In this research, large alumina ceramics was fabricated by filter pressing of alumina slurry using commercial powder and thereafter sintering at $1600^{\circ}C$ in gas furnace. The characteristics of large alumina ceramics thereby were compared to those of small alumina ceramics prepared by pressure forming such as uniaxial pressing and CIP. Careful control of properties of alumina slurry and filter pressing made the fabrication of large alumina ceramics possible, and its characteristics were equivalent to those of small alumina ceramics. The large alumina ceramics, prepared by sintering the green body of 63% relative density at $1600^{\circ}C$, exhibited both dense microstructure corresponding to 98.5% of relative density and 99.8% of high purity as in starting powder.

Effect of Dispersion on Tape Casted Green Sheet Prepared from Bimodal-Type AlN Powders (Bimodal 입도분포를 보이는 AlN 분말의 테이프캐스팅 성형을 위한 분산효과)

  • Choi, Hong-Soo;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.566-571
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    • 2010
  • Dispersion behavior of the slurries consisted of bimodal-type AlN powders was examined in non-aqueous solvent system. Azotropic solvent system and copolymer acidic dispersant were applied to the slurries. Measurements of the sedimentation height and the viscosity of the each slurry, and the test of particle size distribution of the each powder sample were conducted as examinations for the dispersion behavior at the various dispersant contents. The bimodal-type particle size distribution was continued after addition of the dispersant and small particle portions were increased as the dispersant content increases. The density of the green sheet was also increased as the dispersant content increases and a green density of $2.114\;g/cm^3$ was obtained at the sample prepared from 2.4 wt% dispersant content. The increase of large particle portions resulted in the surface defects of the green sheets.

Effect of $MnO_2$ Additives on the Thermal Properties of Infrared Radiator of Cordierite System Fabricated by Slurry Casting Method (주입성형법으로 제조된 Cordierite계 적외선 방사체의 열적특성에 미치는 $MnO_2$의 영향)

  • 신용덕
    • Journal of the Korean Ceramic Society
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    • v.32 no.7
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    • pp.769-776
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    • 1995
  • Infrared radiators of a cordierite system [cordierite (2MgO.2Al2O3.5SiO2)+30wt% clay+X wt% MnO2 (X=0, 0.1, 0.25, 0.5, 1.0, 1.5, 2.0, 2.5)] were manufactured by a slurry casting method. Thermal and physical properties of these infrared radiators were studied by the measurement of spectra emissivity, thermal expansion coefficient and apparent density, SEM and EPMA analyses were also carried out. The thermal expansion coefficient and apparent density were decreased with increasing amouonts of MnO2 additives. On the other hand, the spectral emissivity was increased in the wavelength below 4.5${\mu}{\textrm}{m}$. Also, infrared radiators of the cordierite system, of which the spectral emisivity was 0.8, could be attainable in the wavelength above 4.5${\mu}{\textrm}{m}$. The infrared radiator of the cordierite system with 2.0wt% MnO2, of which the spectral emissivity was approximately 1.0, could be attainable in the wavelength between 4.5${\mu}{\textrm}{m}$ and 8${\mu}{\textrm}{m}$. The spectral emissivity of the specimen containing 2.0wt% MnO2 was higher than others in the wavelength between 8${\mu}{\textrm}{m}$ and 14${\mu}{\textrm}{m}$.

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Unconfined compressive strength property and its mechanism of construction waste stabilized lightweight soil

  • Zhao, Xiaoqing;Zhao, Gui;Li, Jiawei;Zhang, Peng
    • Geomechanics and Engineering
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    • v.19 no.4
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    • pp.307-314
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    • 2019
  • Light construction waste (LCW) particles are pieces of light concrete or insulation wall with light quality and certain strength, containing rich isolated and disconnected pores. Mixing LCW particles with soil can be one of the alternative lightweight soils. It can lighten and stabilize the deep-thick soft soil in-situ. In this study, the unconfined compressive strength (UCS) and its mechanism of Construction Waste Stabilized Lightweight Soil (CWSLS) are investigated. According to the prescription design, totally 35 sets of specimens are tested for the index of dry density (DD) and unconfined compressive strength (UCS). The results show that the DD of CWSLS is mainly affected by LCW content, and it decreases obviously with the increase of LCW content, while increases slightly with the increase of cement content. The UCS of CWSLS first increases and then decreases with the increase of LCW content, existing a peak value. The UCS increases linearly with the increase of cement content, while the strength growth rate is dramatically affected by the different LCW contents. The UCS of CWSLS mainly comes from the skeleton impaction of LCW particles and the gelation of soil-cement composite slurry. According to the distribution of LCW particles and soil-cement composite slurry, CWSLS specimens are divided into three structures: "suspend-dense" structure, "framework-dense" structure and "framework-pore" structure.

A Mechanism Study on Formation and Reduction of Residual Li of High Nickel Cathode for Lithium-ion Batteries (층상계 하이니켈 양극재의 잔류 리튬 생성 및 저감 메커니즘 연구)

  • MinWook, Pin;Beom Tak, Na;Tae Eun, Hong;Youngjin, Kim
    • Journal of Industrial Technology
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    • v.42 no.1
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    • pp.7-12
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    • 2022
  • High nickel layered oxide cathodes are gaining increasing attention for lithium-ion batteries due to their higher energy density and lower cost compared to LiCoO2. However, they suffer from the formation of residual lithium on the surface in the form of LiOH and Li2CO3 on exposure to ambient air. The residual lithium causes notorious issues, such as slurry gelation during electrode preparation and gas evolution during cell cycling. In this review, we investigate the residual lithium issues through its impact on cathode slurry instability based on deformed polyvinylidene fluoride (PVdF) as well as its formation and reduction mechanism in terms of inherently off-stoichiometric synthesis of high nickel cathodes. Additionally, new analysis method with anhydrous methanol was introduced to exclude Li+/H+ exchange effect during sample preparation with distilled water. We hope that this review would contribute to encouraging the academic efforts to consider practical aspects and mitigation in global high-energy-density lithium-ion battery manufacturers.

Development, validation and implementation of multiple radioactive particle tracking technique

  • Mehul S. Vesvikar;Thaar M. Aljuwaya;Mahmoud M. Taha;Muthanna H. Al-Dahhan
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4213-4227
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    • 2023
  • Computer Automated Radioactive Particle Tracking (CARPT) technique has been successfully utilized to measure the velocity profiles and mixing parameters in different multiphase flow systems where a single radioactive tracer is used to track the tagged phase. However, many industrial processes use a wide range of particles with different physical properties where solid particles could vary in size, shape and density. For application in such systems, the capability of current single tracer CARPT can be advanced to track more than one particle simultaneously. Tracking multiple particles will thus enable to track the motion of particles of different size shape and density, determine segregation of particles and probing particle interactions. In this work, a newly developed Multiple Radioactive Particle Tracking technique (M-RPT) used to track two different radioactive tracers is demonstrated. The M-RPT electronics was developed that can differentiate between gamma counts obtained from the different radioactive tracers on the basis of their gamma energy peak. The M-RPT technique was validated by tracking two stationary and moving particles (Sc-46 and Co-60) simultaneously. Finally, M-RPT was successfully implemented to track two phases, solid and liquid, simultaneously in three phase slurry bubble column reactors.

The Three -Dimensional Stability Analysis of the Diaphragm Wall under the Influence of External Loads (상재하중의 영향을 고려한 Diaphragm Wall의 3차원 안정도 해석)

  • Gu, Ja-Gap;Lee, Sang-Deok;Jeon, Mong-Gak
    • Geotechnical Engineering
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    • v.7 no.3
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    • pp.43-50
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    • 1991
  • To analyze the effects of ground water levels and external loads on the stability of a Dia- phragm wall, the three models of Bell, Piaskowski/kowalewski, and Washbourne were modified and extended to develop a new program SL3D. Comparing to the other two models, Washbourne's model shows the stability in on safes at the beginning of the excavation and increase as the excavation continue . Also the effects of various design factors, such as the density of slurry, ground water levels, the friction angle of soil, external loads and the length of trench, have been analyzed and a nomogram was developed.

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Spray Drying of Zirconia/Alumina Composite Powder Using PVP as a Binder (PVP 결합제를 이용한 지르코니아/알루미나 복합분말의 분무건조)

  • Shim, Hyung-Bo;Moon, Joo-Ho;Kim, Dae-Joon
    • Journal of the Korean Ceramic Society
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    • v.39 no.5
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    • pp.446-451
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    • 2002
  • Zirconia/alumina mixture powder was spray-dried various degree of dispersion, type of dispersants and powder content in the slurry. The quality of the granule was determined by observation of the granule shapes after spray drying and fracture of intergranular boundaries during pressing. Defect-free granules were obtained from the powders that formed weak flocs in the slurry. The granules, spray-dried from the slurry containing 32.5 vol% powder mixture and PVP as binder, were fractured completely during shaping and the sintered specimens showed a density of 99.7% and a flexural strength of 850 MPa.

The thermal stabilization characteristics of electrolyte membrane in high temperature electrolysis[HTE] (고온 수전해 전해질 막의 열안정화 특성 고찰)

  • Choi, Ho-Sang;Son, Hyo-Seok;Sim, Kyu-Sung;Hwang, Gab-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.16 no.2
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    • pp.150-158
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    • 2005
  • Added ratio of 8YSZ powder and organic compounds (solvent, plasticizer, dispersant, binder) properly. It manufactured electrolysis membrane by wet process that make slurry and dry process that do not use organic compounds. In the case of wet process, harmony combination and method of organic compound are an importance element in slurry manufacture. This slurry did calcine at temperature of 140$^{\circ}C$ in Furnace and manufactured electrolyte disk by Dry pressing method. Like this, manufacturing disk sintered at temperature of $1300^{\circ}C,\;1400^{\circ},\;1500^{\circ}C$ in Furnace and completed electrolysis membrane. Confirmed change of crystal structure and decision form through analysis of density, SEM, XRD according to change of sintering temperature, and considered relation with ion conductivity.

Processing of Al2O3 Ceramics with a Porous Cellular Structure (셀 다공구조를 갖는 Al2O3세라믹스의 제조)

  • Lim, Byong-Gu;Lee, Lak-Hyoung;Ha, Jung-Soo
    • Journal of the Korean Ceramic Society
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    • v.44 no.10
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    • pp.574-579
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    • 2007
  • Porous $Al_2O_3$ ceramics were prepared by the gelcasting foams method (a slurry foaming process) with acrylamide monomer. The foaming and gelation behavior was investigated with the parameters such as the type and concentration of surfactant, solid loading of slurry, and the concentrations of initiator and catalyst. Density, porosity, microstructure, and strength of the green and sintered samples were characterized. Of the four kinds of surfactants tested, Triton X-114 showed the highest foaming ability for the solid loading of 55-30 vol%. The gelation condition giving the idle time off min was found to set the foamed structure without significant bubble enlargement and liquid lamella thinning. The green samples were fairly strong and machinable and showed maximum strength of 2.4 MPa in diametral compression. The sintered samples showed densities of 10-36% theoretical (i.e. porosity 90-64%) with a highly interconnected network of spherical pores with sizes ranging from 30 to $600{\mu}m$. The pore size and connectivity increased but the cell strut thickness decreased with decreasing the solid loading. Flexural strength of 37.8-1.7 MPa was obtained for the sintered samples.