• Title/Summary/Keyword: Slag behavior

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Study on the Reaction Behavior of Self-reducing TiO2 Briquette (자기 환원성 TiO2 단광의 반응특성에 관한 연구)

  • Baek, S.J.;Shin, D.Y.;Min, J.W.;Choi, S.O.;Yun, D.J.;You, B.D.
    • Transactions of Materials Processing
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    • v.15 no.8 s.89
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    • pp.615-620
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    • 2006
  • The reduction behavior of $TiO_{2}$ in Al and Al/CaSi containing self-reducing $TiO_{2}$ briquettes(SRTB) was investigated. The maximum yield of Ti was expected with the slag composition of 45-55%CaO in the $CaO-Al_{2}O_{3}$ system. When $CaCO_{3}$ was used as a flux, the oxidation loss of reducing agent by $CO_{2}$ should be compensated, and therefore it leads to excessive requirement of the reducing agent. By using Al and CaSi mixture as a reducing agent of $TiO_{2}$, the reaction products both oxide and metal could be liquefied, and separated effectively with each other. As a result, the yield of Ti increases remarkably. The optimum mixing ratio of CaSi to Al is 78%CaSi-22%Al.

Reduction Behavior of Self-Reducing Pellets of Chromite and Si Sludge with and without Carbon

  • Jung, Woo-Gwang;Hossain, Sakib Tanvir;Kim, Jong-Ho;Chang, Young-Chul
    • Korean Journal of Materials Research
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    • v.29 no.10
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    • pp.592-602
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    • 2019
  • Feasibility is investigated for reduction of chromium ore by Si sludge with mixed silicothermic and carbothermic reaction. The reduction behavior of chromium ore using Si sludge is investigated precisely to determine the effects of carbon addition, reaction time, and reaction temperature. The pellets are dropped into the furnace after temperature stabilized. As the amount of C addition increases, the amounts of CO and $CO_2$ gas generation increase. After the dropping of the pellets, the pellets are heated and the reaction starts at about 1,573 K or higher. The pellets maintain their shape until 10 min after the drop, and then melted. As the holding time increased, the size of the reduced metal particles increased. The chromium ore is rapidly reduced by the Si sludge, and the slag penetrated into the chromium ore and reduction progressed inside. As the reduction temperature increased, the reaction initiation time is shortened and the reaction fraction of the reduction reaction increased. As the reaction temperature increased, agglomeration of reduced ferrochrome metal is promoted.

Tribological behavior of concrete with different mineral additions

  • Belaidi, Amina;Hacene, Mohammed Amine Boukli;Kadri, El-Hadj;Taleb, Omar
    • Advances in concrete construction
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    • v.11 no.3
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    • pp.231-238
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    • 2021
  • The present work aims at investigating the effects of using various fine mineral additions as partial replacement to Portland cement on the tribological properties of concrete. To achieve this goal, concrete mixtures were prepared with different percentages (10, 20 and 30%) of limestone fillers (LF) and natural pozzolana (NP), and (20, 40 and 60%) of blast furnace slag (BFS). The interface yield stress (τ0) and viscous constants (η) that allow characterizing friction at the concrete-pipe wall interface were determined using a rotational tribometer. In addition, the compositions of the boundary layers that formed in the pumping pipes of the different concretes under study were also identified and analyzed. The experimental results obtained showed that the concretes studied have a linear tribological behavior that can be described by the Bingham model. Furthermore, the use of different mineral additions, especially limestone fillers and blast furnace slags, even at high rates, had a beneficial effect on the optimization of the volume of paste present in the boundary layer, which made it possible to significantly reduce the viscous constant of concrete. However, a maximum rate of 10% of natural pozzolana was recommended to achieve tribological properties that are favorable to the pumpability of concrete.

An Experimental Study on the Mechanical Behavior of Concrete Using Non-Sintered Cement (비소성 시멘트 콘크리트의 역학적 거동에 대한 실험 연구)

  • Yoo, Sung-Won;Min, Gyeong-Oan
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.1
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    • pp.115-121
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    • 2012
  • If cement could be manufactured with industrial byproducts such as granulated blast furnace slag, phosphogypsum, and waste lime rather than clinker, there would be many advantages, including the maximization of the use of these industrial byproducts for high value-added resources, the conservation of natural resources and energy by omitting the use of clinker, the minimization of environmental pollution problems caused by $CO_2$ discharge, and the reduction of the production cost. For this reason, in this study, mechanical behavior tests of non-sintered cement concrete were performed, and elasticity modulus and stress-strain relationship of non-sintered cement concrete were proposed. Nine test members were manufactured and tested according to reinforcement ratio and concrete compressive strength. According to the test results, there was no difference between general cement concrete and non-sintered cement concrete in terms of flexure and shear behavior.

Mechanical Properties and Flexural Behavior of Recycled PET Fiber Reinforced Eco-Friendly Hwang-toh Concrete (재생 PET 섬유로 보강된 친환경 황토 콘크리트의 역학적 특성과 휨 거동)

  • Kim, Sung-Bae;Yi, Na-Hyun;Kim, Hyun-Young;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.3
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    • pp.152-159
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    • 2010
  • Recently, the public interest in eco-friendly material and structure has been increasing and many Hwang-toh researches are being actively performed. Hwang-toh is one of the traditional environment friendly construction materials used as a construction and plastering material. Hwang-toh has many advantages as construction material due to its high heat storage capacity, auto-purification, antibiotic ability, and infrared ray emission characteristics. But, currently it has not been developed into construction material and used in modern construction due to its low strength and dry shrinkage cracking prone characteristics. According to the recent researches and study results, Hwang-toh can be used as a natural pozzolanic material like fly-ash or pozzolan. In this study, mechanical properties and structural flexure behavior experiments of slag, recycled PET fiber, and Hwang-toh added concrete are carried out. The test results showed that drying shrinkage of concrete mixed with Hwang-toh has lower compressive strength and elastic modulus than those of control cement concrete specimen, but it has the similar flexural behavior in reinforced concrete beams.

Structural Capacity of Poles Using Crack Self-healing Concrete (균열자기치유용 콘크리트를 사용한 전주의 구조 성능)

  • Yoo, Sung-Won;Kim, Sang-Jun;Park, Hong-Gi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.222-227
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    • 2018
  • Recently, due to the deterioration and various natural disasters caused by the passage of concrete pole for 20~30 years or more, damage and destruction of the poles have increased the demand for maintenance. In this paper, 10 flexural strength test specimens were fabricated by using crack self - healing concrete of Fly ash, GGBS, CA, etc. The compressive strength of the concrete with slag was found to be excellent, but the concrete with fly ash was slightly below the reference strength. In addition, the crack loadings of the specimens satisfied the criteria of KS F 4304. In the case of the load-deflection and strain relations, the behavior of the fly ash specimens was similar, but in the specimens containing the blast furnace slag, The results showed that a large amount of strain occurred.

Comparison of Design Concepts for Four Different Entrained-Bed Coal Gasifier Types with CFD Analysis (CFD 해석을 통한 4종의 건식 분류층 석탄가스화기 설계개념 비교)

  • Yun, Yongseung;Ju, Jisun;Lee, Seung Jong
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.566-574
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    • 2011
  • Coal gasifier is a key component for achieving high efficiency in integrated gasification combined cycle and indirect coal liquefaction. Although there have been several successful coal gasifiers that were commercially proven, many different design configurations are still possible for a simple and reliable gasifier operation. Four different gasifier design concepts of dry-feeding were compared in terms of residence time, exit syngas temperature and syngas composition. First, cold-flow simulation was applied to pre-select the configuration concepts, and the hot-flow simulation including chemical reactions was performed to compare the concepts at more actual gasifier operating conditions. There are many limitations in applying CFD method in gasifier design, particularly in estimating slag behavior and slag-tap design. However, the CFD analysis proved to be useful in comparing the widely different gasifier design concepts as a pre-selection tool.

Rheological Properties of Binder Pastes for Self-Compacting Concrete

  • Park, Yon-Dong
    • KCI Concrete Journal
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    • v.13 no.1
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    • pp.35-41
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    • 2001
  • This paper investigated rheological properties of binder pastes for self-compacting high performance concrete. Six mixtures of self-compacting concrete were initially prepared and tested to estimate self-compacting property. Then, the binder pastes used in self-compacting concrete were tested for rheological properties using a rotary type rheometer. Binder pastes with different water-binder ratios arid flow values were also examined to evaluate their rheological characteristics. The binders were composed of ordinary Portland cement, fly ash, two types of pulverized blast-furnace slag, and limestone powder. The flow curves of binder pastes were obtained by a rotary type rheometer with shear rate control. Slump flow, O-funnel time, box, and L-flow teats were carried out to estimate self-compacting property of concrete. The flow curves of binder pastes for self-compacting concrete had negligible yield stresses and showed an approximately linear behavior at higher shear rates beyond a certain limit. Test results also indicated that the binders incorporating fly ash are more appropriate than the other types of binders in quality control of self-compacting concrete.

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Long-Term Measurement under the Moving train at the Test Reinforced Roadbed Site in Railway (철도강화노반 시험부설구간에서의 열차 주행시 장기거동 계측)

  • 황선근;신민호;이성혁;최찬용;이시한
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.223-230
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    • 2001
  • Nine different types of the reinforced railroad roadbeds which . are located in between Suwon-Chunan station of Kyongbu line were constructed in order to increase the bearing capacity of railroad roadbed and to improve the ridability as a part of speed-up project of conventional railroad systems. Each three sections were composed of weathered granite soil, crushed stone and furnace slag(HMS25), and fully instrumented with earth pressure cells, settlement plates and geophones to monitor the behavior of roadbeds under actual train loads. Field measurement has continued since October 31, 2000 and presently with rather longer measurement interval. The measurement data such as settlement, earth pressure and vibration levels are currently under analysis process. In this paper, only cumulative measurement data of railroad roadbeds were introduced. In the near future, comprehensive measurement data and result of analysis will be presented and design technique for the reinforced railroad roadbed will be proposed as a final product of this study.

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Kinetics of the water absorption in GGBS-concretes: A capillary-diffusive model

  • Villar-Cocina, E.;Valencia-Morales, E.;Vega-Leyva, J.;Antiquera Munoz, J.
    • Computers and Concrete
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    • v.2 no.1
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    • pp.19-30
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    • 2005
  • We study the kinetics of absorption of water in Portland cement concretes added with 60, 70 and 80% of granulated blast furnace slag (GGBS) cured in water and at open air and preheated at 50 and $100^{\circ}C$. A mathematical model is presented that allows describing the process not only in early ages where the capillary sorption is predominant but also for later and long times where the diffusive processes through the finer and gel pores are considered. The fitting of the model by computerized methods enables us to determine the parameters that characterize the process: i.e., the sorptivity coefficient (S) and diffusion coefficient (D). This allows the description of the process for all times and offers the possibility to know the contributions of both, the diffusive and capillary processes. The results show the influence of the curing regime and the preheating temperature on the behavior of GGBS mortars.