• 한국세라믹학회지
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• 제43권7호
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• pp.408-414
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• 2006

Properties of slag cement that contained 50 wt% of blast furnace slag were studied when replaced blast furnace slag powder with electric arc furnace slag powder. Electric arc furnace slag was aged for about 2 months in the air by being crushed to be 1-3 mm in size. As a result of the experiment, it was proven that the water content for obtaining the same consistency became decreased as slag is replaced with electric arc furnace slag instead of blast furnace slag. Also, the workability of mortar increased about 30% at the same ratio of water to binder when blast furnace slag was completely replaced with electric arc furnace slag. The compressive strength of mortar on the 28 days increased when a slag replacement rate became 10 wt%, however, it rather decreased when the slag replacement rate exceeded 10 wt%. The heat of hydration became higher for the first 14 h in case of the replacement of slag cement by electric arc furnace slag. Yet, it decreased when 14 h had passed. Therefore, when all blast furnace slag was replaced with electric arc furnace slag, about 15 cal/g heat of hydration decreased when it passed about 72 h.

• 자원리싸이클링
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• 제18권3호
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• pp.36-41
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• 2009

본 연구에서는 철강 산업 부산물인 전기 아크로에서 발생되는 슬래그(이하 EAF-slag 표기)를 탄산화 반응에 따른 슬래그이 물성변화 및 몰탈 시험을 통해 콘크리트용 대체 골재로써의 가능성을 검토하였으며, 특히 본 연구에서는 탄산화 처리에 따른 EAF-slag의 물성 변화에 대하여 논하였다. 연구 결과 EAF-slag의 탄산화 처리에 따라 EAF-slag 입자 표면에 칼사이트가 생성되면서 골재로써의 표면 기공율을 감소하였으며, pH도 7까지 안정화되는 것을 확인할 수 있었다. EAF-slag를 모래 대체에 따른 몰탈 압축 강도실험 결과 EAF-slag의 모래 대체 50%의 경우 7일 강도뿐만 아니라 28일 강도 증가도 함께 관찰되었다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.537-541
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• 2001

For the development of reformation material of soft ground using the LD slag, the relation to the particle condition of LD slag and the pH behavior of slag dissolution water, extraction properties of slag, and origination of white water were investigated. When the LD slag is mixed with sea water, the pH of solution ranged between 9.47 and 10.0. On the other hand, when mixed with distilled water, the pH was about 10.4 to 12.1. For the as-received slag and the aged slag in sea water, a pH of 11.5 to 12.0 was observed when the particle size was less than 0.5mm. For the reoxidized slag in seawater, the pH of the solution was lower than 9.5 when the particle size was bigger than 0.075mm. For the aged slag and reoxidized slag, the pH of the solution remained constant when the addition ratio of sea water to the slag was higher than 500 times. The main elements dissolved from the slag were Ca and Mg ions. When the pH went over 9.0, the white water started to font which was caused by the CaCO$_3$and Mg(OH)$_2$.

• 한국세라믹학회지
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• 제36권1호
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• pp.30-35
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• 1999

155$0^{\circ}C$~1$650^{\circ}C$의 온도범위에서 stampwo의 원료로서 사용되는 돌로마이트 클링커의 Fe2O3의 함유유무에 따른 slag에 의한 침식거동을 연구하였다. Slag 성분중에서 CaO-SiO2계 저융점 화합물 보다는 Fe2O3가 선택적으로 돌로마이트 클링커의 입계로 깊숙히 침투되었다. 돌로마이트 클링커의 가동면에 존재하는 치밀한 magnesioferrite는 slag중의 Fe2O3 성분보다는 클링커중에 함유되어 있는 Fe2O3 성분에 의하여 우선적으로 생성되었다. 돌로마이트 클링커의 slag에 의한 손상은 돌로마이트 클링커의 입계에 존재하는 CaO가 slag중의 Fe2O3 성분과 반응하여 dicaciumferrite를 생성$\longrightarrow$dicalciumferrite가 slag 성분중의 CaO-SiO2계 화합물에 의하여 용출되는 단계로 진행되었다. Slag의 온도가 상승됨에 따라 Fe2O3가 함유되어 있지 않는 돌로마이트 클링커의 경우에는 돌로마이트 클링커의 가동면에 생성되는 magnesioferrite의 층은 미양하였다. 반면에, Fe2O3가 함유된 돌로마이트 클링커는 slag의 온도가 상승됨에 따라 magnesioferrite의 층이 두꺼울 뿐문아니라 magnesioferrite의 입성장도 수반되었다.

• 한국지반환경공학회 논문집
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• 제24권11호
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• pp.5-10
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• 2023

지하수 제어가 필요한 분야에서 다방면으로 활용되는 Slag-CB는 CB의 일종으로 CB에 혼합되는 시멘트의 일부를 GGBS 로 치환하여 사용하는 차수벽의 일종이다. 일반적으로 Slag-CB는 GGBS의 치환율이 증가함에 따라 압축강도, 차수성, 내구성 및 내화학성 등이 장기적으로 향상되는 장점이 있으나, 벽체의 유연성 및 변형에 대한 저항성이 저하되며 파괴 시 취성을 보이는 문제가 있다. 이러한 문제를 해결하기 위해 일부 품질기준에서는 Slag-CB를 저강도로 설계하도록 권장하고 있어 GGBS 치환율이 높은 고강도의 Slag-CB의 현장 적용에 다소 어려움이 있다. 이에 본 연구에서는 Slag-CB의 유연성 및 변형에 대한 저항성을 개선하여 취성파괴를 방지함으로 Slag-CB의 현장 활용성 및 적용성을 향상시키기 위해 나일론 섬유를 혼합한 Slag-CB 차수벽을 대상으로 압축거동 특성을 평가하고, 이를 비교·분석함으로 Slag-CB의 유연성 및 변형에 대한 저항성을 향상시킬 수 있는 방안을 제시하였다.

• Computers and Concrete
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• 제14권3호
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• pp.247-262
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• 2014

Partial replacement of Portland cement by slag can reduce the energy consumption and $CO_2$ emission therefore is beneficial to circular economy and sustainable development. Compressive strength is the most important engineering property of concrete. This paper presents a numerical procedure to predict the development of compressive strength of slag blended concrete. This numerical procedure starts with a kinetic hydration model for cement-slag blends by considering the production of calcium hydroxide in cement hydration and its consumption in slag reactions. Reaction degrees of cement slag are obtained as accompanied results from the hydration model. Gel-space ratio of hardening slag blended concrete is determined using reaction degrees of cement and slag, mixing proportions of concrete, and volume stoichiometries of cement hydration and slag reaction. Furthermore, the development of compressive strength is evaluated through Powers' gel-space ratio theory considering the contributions of cement hydration and slag reaction. The proposed model is verified through experimental data on concrete with different water-to-binder ratios and slag substitution ratios.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2001년도 봄 학술발표회 논문집
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• pp.453-458
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• 2001

Copper slag is produced about 700,000 tons annually though copper refining process in Korea. In the paper, a laboratory investigation was carried out to estimate the geotechnical properties of copper slag and examine the feasibility of using the copper slag as a substitute for conventional construction materials and the improvement of the soft clay deposit. The specific gravity of copper slag is 3.45, and pH is 7.83. And the size distribution of the copper slag is well graded, so usage of copper slag will be extended in Geotechnical engineering fields. Copper slag has the permeability of 3.502${\times}$10￣$^2$cm/sec, which is satisfied with the criterion of sand drainage materials.. At the same time, it is thought to be suitable material for sand mat since it meets JIS of grain size distribution. The content of CaO from steel slag is about 40 percent while that of CaO from copper slag is about 5 percent. Based on this fact, copper slag has less hardening property compared to steel slag. Therefore, copper slag can be used as vertical drains, filters, and sand mats for improving the soft deposit.

• Advances in concrete construction
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• 제6권5호
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• pp.545-560
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• 2018

The ever-increasing cost of natural sand and the environmental impacts of extracting manufactured sand (quarry sand) calls for exploring the potential to use alternative materials as fine aggregates in concrete. Copper slag and ferrous slag are industrial by products obtained from the smelting process of copper and iron respectively. A large quantity of copper slag and ferrous slag end up being disposed as waste in landfills and this poses a serious threat to the environment. Copper slag and ferrous slag have similar physical and chemical properties as natural sand and also exhibit pozzolanic activity. This paper studies the technical feasibility of industrial by-products such as copper slag and ferrous slag to replace the fine aggregate in concrete by evaluating the workability, strength and durability characteristics of concrete. The test results indicate that the strength properties are not affected by 40% or 100% replacement of quarry sand with iron slag or copper slag. However, 40% replacement of quarry sand with iron slag or copper slag in concrete is recommended considering the durability aspects of concrete.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.233-236
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• 1999

In this paper, we carried out fundamental experiments to use the steel manufacturing slag as a concrete aggregate. Generally there are two types of slag, the blast-furnace slag and the steel manufacturing slag. The latter is classified by the difference of manufacturing method of steel into the convertor slag and the electric-furnace slag. The steel manufacturing slag mainly contains SiO2 and CaO as the chmical composition. The reaction with water and a little of free CaO in the steel manufacturing slag makes the expansion of volume change. Therefore, we primarily investigated physical properties, expansion mechanism, pH value, aging effects and aging methods in the steel manufacturing slag. Then compressive strength of concrete with steel slag aggregate is measured.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.149-152
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• 2006

In this paper, we researched and compared the properties of steel slag(is divided with electric arc furnace slag and converter slag) as concrete aggregate by measuring physical and chemical characteristics of it. The steel slag mainly contains SiO2 and CaO as the chemical composition. The reaction with water and a little of free CaO in the slag causes slag's volume to expanse. Therefore, we used several aging methods in order to decrease the characteristics of slag volume expansion. The physical properties of steel slag aggregate is researched and then the strength of concrete with the steel slag aggregate is measured.