• Fisheries and Aquatic Sciences
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• 제8권3호
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• pp.177-181
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• 2005

Fishing selectivity is determined by the level of voluntary escaping behavior in accordance with decision-making based on the relationship between fish size and mesh size. This study examined movement during the swimming behavior of black porgy in a trawl's towing cod-end and analyzed the movement components such as swimming speed, angular velocity of turning, and distance to the net over time. Most of the observed fish exhibited an optomotor response, maintaining position and swimming speed without changing direction. Others exhibited erratic or 'panic' behavior with sudden changes in swimming speed and direction. The latter behavior involved very irregular and aperiodic variations in swimming speed and angular velocity, termed 'chaotic behavior.' Thus, the results of this study can be applied to a chaotic behavior model as a time series of swimming movements in the towing cod-end for the fishing selectivity.

• 한국표면공학회지
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• 제50권2호
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• pp.98-107
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• 2017

Pd-based membranes have been widely used in hydrogen purification and separation due to their high hydrogen diffusivity and infinite selectivity. However, it has been difficult to fabricate thin and dense Pd-based membranes on a porous stainless steel(PSS) support. In case of a conventional PSS support having the large size of surface pores, it was required to use complex surface treatment and thick Pd coating more than $6{\mu}m$ on the PSS was required in order to form pore free surface. In this study, we could fabricate thin and dense Pd membrane with only $3{\mu}m$ Pd layer on a new PSS support manufactured by metal injection molding(MIM). The PSS support had low surface roughness and mean pore size of $5{\mu}m$. Pd membrane were prepared by advanced Pd sputter deposition on the modified PSS support using fine polishing and YSZ vacuum filling surface treatment. At temperature $400^{\circ}C$ and transmembrane pressure difference of 1 bar, hydrogen flux and selectivity of $H_2/N_2$ were $11.22ml\;cm^{-2}min^{-1}$ and infinity, respectively. Comparing with $6{\mu}m$ Pd membrane, $3{\mu}m$ Pd membrane showed 2.5 times higher hydrogen flux which could be due to the decreased Pd layer thickness from $6{\mu}m$ to $3{\mu}m$ and an increased porosity. It was also found that pressure exponent was changed from 0.5 on $6{\mu}m$ Pd membrane to 0.8 on $3{\mu}m$ Pd membrane.

• Korean Chemical Engineering Research
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• 제58권4호
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• pp.658-664
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• 2020

Zeolite HY is wet impregnated with Ni (0.1, 0.3, 0.4, 0.5 wt%), Pt (0.1 wt%) and reduced in presence of hydrogen to form nanosized particles of Ni and Pt. All the catalysts were characterized by XRD, TEM, ESCA, NH₃-TPD, Pyridine adsorbed FT-IR and BET. Characterization results confirm that the Ni and Pt fractions effectively rehabilitated the physio-chemical properties of the zeolite HY catalysts. Further, all the reduced catalyst were screened with hydroisomerization of m-xylene at LHSV = 2.0 h^-1 in the temperature range 250-400 ℃ in steps of 50 ℃ in hydrogen atmosphere (20 ml/g). The addition of Ni to Pt catalyst increases hydroisomerization conversion, as well as maximizes p-xylene selectivity by restricting the pore size. The increasing trend in activity continues up to 0.3 wt% of Ni and 0.1 wt% Pt addition over zeolite HY. The increasing addition of Ni increases the total number of active metallic sites to exposed, which increases the metallic sites/acid sites ratio towards the optimum value for these reactions by better balance of synergic effect for stable activity. The rate of deactivation is pronounced on monometallic catalysts. The results confirm the threshold Ni addition is highly suitable for hydroisomerization reaction for product selectivity over Ni-Pt bimetallic/support catalysts.

• 수산해양기술연구
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• 제52권4호
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• pp.281-289
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• 2016

Spinyhead sculpin Dasycottus setiger, a species of cold water fish, is distributed along the eastern coastal waters of Korea. A series of fishing experiments was carried out in the waters near Uljin from June, 2002 to November, 2004, using the experimental monofilament gill nets of different mesh sizes (82.2, 89.4, 104.8, and 120.2 mm) to describe the selectivity of the gill net for the fish. The SELECT (Share Each Length's Catch Total) analysis with maximum likelihood method was applied to fit the different functional models (normal, lognormal, and bi-normal models) for selection curves to the catch data. The bi-normal model with the fixed relative fishing intensity was selected as the best-fit selection curve by AIC (Akaike's Information Criterion) comparison. For the best-fit selection curve, the optimum relative length (the ratio of fish total length to mesh size) with the maximum efficiency and the selection range ($R_{50%,large}-R_{50%,small}$) of 50% retention were obtained as 2.363 and 0.851, respectively. The ratios of body girth to mesh perimeter at 100% retention where the selection curve of each mesh size represented the optimum total length were calculated as the range of 0.86 ~ 0.87.

• 공업화학
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• 제17권3호
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• pp.235-242
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• 2006

Liquid phase alkylation of biphenyl (BP) was studied over large pore zeolites. Selective formation of the least bulky products, 4,4'-diisopropylbiphenyl (4,4'-DIPB) occurred only in the isopropylation of BP over some large pore molecular sieves. H-mordenites (MOR) gave the highest selectivity among them. The dealumination of MOR enhanced catalytic activity and the selectivity of 4,4'-DIPB because of the decrease of coke-deposition. Non-selective catalysis occurs on external acid sites over MOR with the low $SiO_2/Al_2O_3$ ratio because severe coke-deposition deactivates the acid sites inside the pores by blocking pore openings. The selectivity of DIPB isomers was changed with reaction temperature. Selective formation of 4,4'-DIPB was observed at moderate temperatures such as $250^{\circ}C$, whereas the decrease of the selectivity of 4,4'-DIPB occurred at higher temperatures as $300^{\circ}C$. However, 4,4'-DIPB was almost exclusive isomer in the encapsulated DIPB isomers inside the pores even at high temperatures. These decreases of the selectivity of 4,4'-DIPB are due to the isomerization of 4,4'-DIPB on the external acid sites. Some 12-membered molecular sieves, such as SSZ-24, MAPO-5 (M:Mg, Zn, Si), SSZ-31, and ZSM-12, which have straight channels, gave 4,4'-DIPB with moderate to high selectivity; however; SSZ-55, SSZ-42, and MAPO-36 (M: Mg, Zn) gave lower selectivity because of cages in 12-membered one dimensional channels. Three dimensional H-Y and Beta zeolites also yield 4,4'-DIPB in low yield because of their wide circumstances for the isopropylation of BP. The increasing the size of alkylating agent enhanced the shape-selective alkylaiton even for the zeolites, such as UTD-1. The ethylation of BP to ethylbiphenyls (EBPs) and diethylbiphenyls (DEBPs) over MOR was non-selective. The ethylation of BP to EBPs was controlled kinetically. However, there was difference in reactivity of EBPs and DEBPs for their further ethylation. 4-EBP was ethylated preferentially among the isomers, although the formation of 4,4'-DEBP was less selective. The least bulky 4-EBP and 4,4'-DEBP have the highest reactivity among EBPs and DEBPs for the ethylation to polyethylbiphenyls (PEBPs). These results show that the environments of MOR pores are too loose for shape selective formation of the least bulky isomers, 4-EBP and 4,4'-DEBP in the ethylation of BP, and that MOR pores have enough space for the further ethylation of 4,4'-DEBP.

• 한국수산과학회지
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• 제18권6호
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• pp.506-510
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• 1985

충무, 남해, 기장 등지에서 사용하고 있는 멸치 자망어구에 대한 조사를 근거로 망목이 23.1mm, 21.6mm, 20.0mm인 세 가지 망지로서 성형률이 각각 0.65 및 0.55가 되도록 각 1폭씩, 6폭짜리 시험어구를 제작하고, 울산 근해에서 부산-404호(160ps, 800ps)로서 시험조업(1983년 7월 28일)한 어획결과를 가지고서 Ishida(1962)의 방법으로 망목선택성을 검토한 결과는 다음과 같다. 1. 어획미수 161마리 중 $90\%$이상(148마리)이 경주부위에서 이망되었 다. 2. 경주 $C_n(cm)$와 체장 L(cm)와의 관계는 L=1.5 $C_n+4.1$로 표시할 수 있고 이때의 상관계수는 0.7로 나타났다. 3. 체장 L(cm)과 적정망목 M(cm)와의 관계는 L=4.8M으로 나타낼 수 있다.

• 수산해양기술연구
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• 제38권2호
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• pp.91-100
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• 2002

삼중자망의 망목 선택성 및 적정망목을 추정하기 위하여 강원도 주문진 해역에서 2000년 8월 10~13일, 11월 9~13일 (18회), 부산 수영만에서 2001년 6월 1일~27일(21회), 시험조업을 행하였다. 또한 주문진 해역에서는 60, 75, 90 105, 135, 150, 180mm의 7가지의 삼중자망으로 조업하였고, 수영만에서는 60, 75, 90mm의 삼중자망과 홑자망으로 비교실험을 행하였다. 망목 선택성 곡선의 분석은 전체 어획량의 약 60%를 차지하는 물가자미(Eopsetta grigorjewi) 를 대상으로 하였으며, Master curve의 다항식이 포함된 Kitahara(1968)방법을 사용하여 작성하였다. 그 결과를 요약하면 다음과 같다. 1. 총 어획미수는 삼중자망이 2,331미였고, 홑자망이 1,433미였으며, 가자미류가 59.8%~60%였다. 2. 최적 l/m값은 삼중자망이 2.56이었으며, 흩자망이 2.47로 삼중자망이 약 0.1 정도 크게 나타났다. 3. 50% 선택구간은 삼중자망이 1.88~3.36(1.48)로 나타났으며, 홑자망은 2.00~3.02(1.02)로 삼중자망이 약 1.5배 정도 넓게 나타났다. 4. 가자미의 최소성숙체장 265mm에 대한 적정망목은 삼중자망이 약 141mm, 홑자망이 약 132mm로 삼중자망이 약 10mm 정도 크게 나타났다. 5. 적정망목을 사용했을 경우 50% 선택 체장범위는 삼중자망이 265mm~474mm, 흩자망이 265mm~398mm로 삼중자망의 체장범위가 76mm 정도 넓은 것으로 나타났다.

• 수산해양교육연구
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• 제8권1호
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• pp.41-47
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• 1996

우리 나라 주변해역의 새로운 어업질서의 개편과 국제어업환경의 변화에 대처하기 위하여 다획을 위한 어구어법의 발전적 모색에서부터 선택적어업기술과 이와 관련한 연구가 보다 많이 요구되고 있으며, 우리 나라와 같이 원양어업을 대상으로 급진적으로 성장해 온 어업국은 연근해어업의 중요성이 새롭게 제고되고 있다. 본 연구에서는 1991년 6월부터 1992년 12월중에 시험조업기간을 통해 어획된 홍치를 대상으로 망목선택성을 분석하였다. 그 결과를 요약하면 다음과 같다. 1. 전장과 체고의 관계식은 BH=0.2562TL+2.9628, 전장과 체위의 관계식은, BG=0.6204TL+8.6402, 전장과 체중의 성장관계식은 $BW=7.34{\times}10^{-5}TL^{2.6956}$이었다. 2. 시험끝자루의 망목내경이 51.2mm, 7.02mm, 77.6mm 및 88.0mm에서 50% 선택체장과 선택계수는 각각 94.8mm, 1.85; 159mm, 2.27 ; 204mm, 2.09 ; 217.3mm, 2.18이었다. 3. 망목의 내경이 51.2mm, 88.0mm 끝자루의 범위내에서 규준곡선의 기울기와 절편은 각각 2.70, -5.7이었으며, 선택계수는 2.11이었다.

• 수산해양기술연구
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• 제40권4호
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• pp.247-254
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• 2004

동해안의 연안성 어족인 빨간횟대에 대해 망목크기 등을 달리한 8종류의 장구형 통발을 사용하여, 2003년 6월부터 12월까지 총 6차례에 걸쳐 어선 2척을 용선하여 조업한 어획실험으로부터 망목선택성 곡선을 구하여 합리적인 자원관리에 대한 기초 자료를 구하고자 하였다. 망목 크기가 20mm와 35mm인 두 통발의 빨간횟대 어획물로부터 체장에 따른 어획비율의 차이에 대해 특별한 경향을 발견할 수 없었다. 망목 크기가 20mm와 55mm인 두 통발의 경우에 대해 SELECT방법을 이용하여 equal split model 과 estimated split model을 적용한 결과, AIC 값이 적은 전자가 더 적절한 모델이므로, 빨간횟대의 경우는 이들 두 통발에 대한 입망률의 차이는 없는 것으로 나타났다. 망목 55mm의 통발에서 SELECT 모델로 구한 50% 어획될 빨간횟대의 전장은 22.0cm였다. 망목 크기가 20mm, 35mm, 55mm인 통발의 어획 자료에 Kitahara의 방법으로 logistic식을 적용하여 추정된 선택성 곡선식은 $s(R)\;=\;\frac{1}{1+exp(-0.3545R+2.141)$와 같았고, 현재 규정 망목 크기인 35mm 장구형 통발에 대해 50% 어획될 빨간횟대의 전장은 21.4cm이었다.

• 수산해양기술연구
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• 제46권4호
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• pp.281-291
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• 2010

To estimate the mesh selectivity of monofilament and multifilament gill net for Marbled sole, Pleuronectes yokohamae, the field testes were carried out 12 times with five different mesh sizes (86.6, 101.0, 121.2, 137.7, 151.5mm) in the western sea of Korea, 2007-2009. The master curve of selectivity was estimated by the extended Kitahara's method. In the field testes, the total number of species and catch were 26 and 987, respectively. The catch number of marbled sole was 728 and occupied 73.8% in total catch. The optimum values of l/m for 1.0 of retention probability in monofilament and multifilament gill net were estimated 0.288 and 0.307, respectively and l/m was estimated to be 0.189, 0.203, 0.213, 0.222 and 0.230 in case of monofilament gill net and 0.171, 0.191, 0.205, 0.216 and 0.227 in case of multifilament gill net when the retention probability were 0.1, 0.2, 0.3, 0.4 and 0.5, respectively. The 0.5 selection range of multifilament gill net was wider about 1.5 times than that of monofilament gill net according as multifilament gill net was 0.216 and monofilament gill net was 0.148. So the multifilament gill net has a low selectivity than that of the monofilament gill net. To estimate the optimum mesh size on first maturity length 19.5cm of marbled sole, the retention probability value of 0.1 was adopted in consideration of using the gill net for marbled sole at present. The optimum mesh size were estimated to be 103.2mm and 114.0mm in monofilament gill net and multifilament gill net, respectively, on first maturity length 19.5cm of marbled sole.