• Title/Summary/Keyword: Size selectivity

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A Study on Integrated Small Signal Stability Analysis of Power Systems (계통의 종합적 미소신호 안정도해석에 관한 연구)

  • Nam, Ha-Kon;Song, Sung-Geun;Kim, Yong-Gu;Shim, Kwan-Shik
    • Proceedings of the KIEE Conference
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    • 1998.11b
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    • pp.685-688
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    • 1998
  • In this research project, two aspects of small signal stability are studied: improvement in Hessenberg method to compute the dominant electromechanical oscillation modes and siting FACTS devices to damp the low frequency oscillation. Fourier transform of transient stability simulation results identifies the frequencies of the dominant oscillation modes accurately. Inverse transformation of the state matrix with complex shift equal to the angular speed determined by Fourier transform enhances the ability of Hessenberg method to compute the dominant modes with good selectivity and small size of Hessenberg matrix. Any specified convergence tolerance is achieved using the iterative scheme of Hessenberg method. Siting FACTS devices such as SVC, STACOM, TCSC, TCPR and UPFC has been studied using the eigen-sensitivity theory of augmented matrix. Application results of the improved Hessenberg method and eigen-sensitivity to New England 10-machine 39-bus and KEPCO systems are presented.

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Etching and Polishing Behavior of Cu thin film according to the additive chemicals

  • Ryu, Ju-Suk;Eom, Dae-Hong;Hong, Yi-Koan;Park, Jum-Yong;Park, Jin-Goo
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.274-278
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    • 2002
  • The purpose of this study was to characterize the reaction of Cu surface with Cu slurry and CMP performance as a function of additives in CMP slurry. The polish rate of Cu was dependent on the kind of organic acids added in slurry. It was considered that polish rate of Cu was dependent on the concentration of carboxylates and mean particle size. When the etchant and oxidant were added in slurry, the highest removal rate and lower etch rate were measured at neutral pH. The addition of etchant, oxidant and pH adjustor played key roles of CMP ability in slurry. As the pH increased, polish rate of Cu was increased by the enhanced the mechanical effects due to effective dispersion of slurry particles. Alumina abrasives was more desirable for 1st step slurry because of high removal rate of Cu and high selectivity ratio among TaN and Cu.

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Polymer Electrolyte Membranes and their Applications to Membranes, Fuel Cells and Solar Cells

  • Kang, Yong-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.29-32
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    • 2003
  • Polymer electrolyte membranes are developed for the applications to facilitated transport membranes, fuel cells and solar cells. The polymer electrolyte membranes containing silver salt show the remarkably high separation performance for olefin/paraffin mixture in the solid state; the propylene permeance is 45 GPU and the ideal selectivity of propylene/propane is 15,000. For fuel cell membranes, the effects of the presence and size of the proton transport channels on the proton conductivity and methanol permeability were investigated. The cell performance for dye-sensitized solar cells employing polymer electrolytes are measured under light illumination. The overall energy conversion efficiency reaches 5.44 % at 10 ㎽/$\textrm{cm}^2$, to our knowledge the highest value ever reported in the polymer electrolytes.

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Chromatographic Characterization of Pentoxifylline and a Mixture of Caffeine-theophylline Imprinted Polymer (Pentoxifylline과 Caffeine-theophylline Imprinted Polymers의 크로마토그래피 특성)

  • 홍승표;왕덕선;구윤모;노경호
    • KSBB Journal
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    • v.18 no.1
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    • pp.65-69
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    • 2003
  • Two molecular imprinted polymers (MIPs) were prepared by using pentoxifylline and a mixture of caffeine-theophylline (2:1, mole ratio) as the templates, MAA as the monomer, and EDMA as the crosslinker The obtained polymer particles (particle size 25-35 $\mu\textrm{m}$) were packed into a HPLC column (150$\times$3.9mm). The selectivity and chromatographic characterization of the imprinted polymers were studied using pentoxifylline, caffeine, theophylline, theobromine as samples and acetonitrile as the mobile phase, Both imprinted polymers showed increased affinity for structural analogues. By using a mixture of caffeine-theophylline templates MIPs, good separations of caffeine, theobromine and theophylline were obtained, and pentoxifylline and caffeine were partly separated.

Fabrication of Electrically Switchable Bragg Gratings of The Transmission Mode From Holographic Polymer Dispersed Liquid Crystals

  • Kim, Kyung-Jin;Kim, Byung-Kyu;Kang, Young-Soo;Jang, Ju-Seog
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.63-69
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    • 2001
  • Holographic transmission gratings were performed by an Ar-laser( ${\lambda}$=514nm) intensity, the ratio fo LC contents to the surfactant. The addition of the surfactant to the LC and pre-polymer systems causes the droplet to maintain the ideal size at the high fraction(over 40wt%) of the LC contents that induce the films to be fabricated with high diffraction efficiency than that of no surfactant series. The image of these films was examined using a charge coupled device (CCD). We also studied the angular selectivity plots which support the important role in the multiplexer channel (MUX). Eventually, we showed the reconstructive optical image recorded in this transmission mode of HPDLCs.

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A Study on Integrated Small Signal Stability Analysis of Power Systems (계통의 종합적 미소신호 안정도해석에 관한 연구)

  • Nam, Ha-Kon;Song, Sung-Geun;Kim, Yong-Gu;Kim, Kwan-Shik
    • Proceedings of the KIEE Conference
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    • 1998.11a
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    • pp.365-368
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    • 1998
  • In this research project two aspects of small signal stability are studied: improvement in Hessenberg method to compute the dominant electromechanical oscillation modes and siting FACTS devices to damp the low frequency oscillation. Fourier transform of transient stability simulation results identifies the frequencies of the dominant oscillation modes accurately. Inverse transformation of the state matrix with complex shift equal to the angular speed determined by Fourier transform enhances the ability of Hessenberg method to compute the dominant modes with good selectivity and small size of Hessenberg matrix. Any specified convergence tolerance is achieved using the iterative scheme of Hessenberg method. Siting FACTS devices such as SVC, STACOM, TCSC, TCPR and UPFC has been studied using the eigen-sensitivity theory of augmented matrix. Application results of the improved Hessenberg method and eigen-sensitivity to New England 10-machine 39-bus and KEPCO systems are presented.

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Design and analysis of highly selective ultrawide stopband lowpass filter using lumped and distributed equivalent circuit models

  • Pankaj Singh Tomar;Manoj Singh Parihar
    • ETRI Journal
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    • v.46 no.4
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    • pp.716-726
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    • 2024
  • An ultrawide stopband lowpass filter is reported using three stepped impedance resonators with high selectivity. The filter extends the stopband frequency range and attenuation, and two quarter-wave open stubs and three circular ground slots are introduced. The lumped and distributed equivalent models are derived and analyzed. The corresponding results are validated experimentally in a fabricated prototype. The prototype lowpass filter has a 3 dB cutoff frequency (fc) of 2.9 GHz, and the stopband is extended up to 35 GHz (12.07fc), with an attenuation level better than 20 dB throughout. The passband-to-stopband transition (3 dB-20 dB) bandwidth is 0.18 GHz, and the roll-off factor is 135 dB/GHz at 30 dB. The insertion loss is 0.3 dB at 1.6 GHz. The normalized circuit size of the proposed filter with respect to the guided wavelength is 0.04.

Characteristics of Heat Stable Salts Treatment Using Anion Exchange Resins in CO2 Absorption Process (음이온교환수지를 이용한 CO2 흡수 공정시 발생하는 열안정성염 처리 특성)

  • Park, Kyung-Bin;Cho, Jun-Hyoung;Jeon, Soo-Bin;Lim, You-Young;OH, Kwang-Joong
    • Clean Technology
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    • v.21 no.1
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    • pp.22-32
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    • 2015
  • In this study, we studied the characteristics of ion exchange for treatment of HSS (heat stable salts) which cause performance reduction in CO2 gas capture amine solution using anion exchange resins. The optimum HSS removal efficiency, 96.1% was obtained when using strong base anion exchange resin SAR10 at dosage 0.05 g/mL, 316 K, pH 12 and the best resin regeneration efficiency, 78.8% was obtained using NaOH solution of 3 M at 316 K. The adsorption data were described well by the Freundlich model and the sorption intensity(n) was 2.0951 lying within the range of favorable adsorption. The adsorption selectivity coefficients were increased by increasing valences and size of ion and desorption selectivity coefficients showed a contradictory tendency to adsorption selectivity coefficients. By continuous HSS removal experiments, 13.3 BV of HSS contaminated solution was effectively treated and the optimum NaOH solution consumption was 5.2 BV to regenerate resins.

Effect of Mesoporous TiO2 in Facilitated Olefin Transport Membranes Containing Ag Nanoparticles (나노입자가 포함된 촉진수송 분리막에서의 메조기공 티타늄산화물의 영향)

  • Kim, Sang Jin;Jung, Jung Pyu;Kim, Dong Jun;Kim, Jong Hak
    • Membrane Journal
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    • v.25 no.5
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    • pp.398-405
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    • 2015
  • Facilitated transport is considered to be a possible solution to simultaneously improve permeability and selectivity, which is challenging in normal polymeric membranes based on solution-diffusion transport only. We investigated the effect of adding mesoporous $TiO_2$ ($m-TiO_2$) upon the separation performance of facilitated olefin transport membranes comprising poly(vinyl pyrrolidone), Ag nanoparticles, and 7,7,8,8-tetracyanoquinodimethane as the polymer matrix, olefin carrier, and electron acceptor, respectively. In particular, $m-TiO_2$ was prepared by means of a facile, mass-producible method using poly(vinyl chloride)-g-poly(oxyethylene methacrylate) graft copolymer as the template. The crystal phase of $m-TiO_2$ consisted of an anatase/rutile mixture, of crystallite size approximately 16 nm as determined by X-ray diffraction. The introduction of $m-TiO_2$ increased the membrane diffusivity, thereby increasing the mixed-gas permeance from 1.6 to 16.0 GPU ($1GPU=10^{-6}cm^3$(STP)/($s{\times}cm^2{\times}cmHg$), and slightly decreased the propylene/propane selectivity from 45 to 37. However, both the mixed-gas permeance and selectivity of the membrane containing $m-TiO_2$ rapidly decreased over time, whereas the membrane without $m-TiO_2$ had more stable long-term performance. This difference might be attributed to specific chemical interactions between $TiO_2$ and Ag nanoparticles, causing Ag to lose activity as an olefin carrier.

Gas Permeation Characteristics of CO2 and N2 through PEBAX/ZIF-8 and PEBAX/amineZIF-8 Composite Membranes (PEBAX/ZIF-8과 PEBAX/amineZIF-8 복합막을 통한 CO2와 N2의 기체투과 특성)

  • Hong, Se Ryeong;O, So Young;Lee, Hyun Kyung
    • Membrane Journal
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    • v.30 no.6
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    • pp.409-419
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    • 2020
  • In this study, PEBAX/ZIF-8 and PEBAX/amineZIF-8 composite membranes were prepared according to the content of zeolitic imidazolate framework-8 (ZIF-8), amine-modified ZIF-8 (amineZIF-8), the gas permeability properties of N2 and CO2 were investigated for each composite membrane. In the case of the PEBAX/ZIF-8 composite membrane, the permeability of N2 and CO2 increased as the ZIF-8 content increased, and in the case of the PEBAX/amineZIF-8 composite membrane, the permeability of N2 and CO2 increased up to 20 wt% of amineZIF-8, but decreased at the higher content. CO2/N2 ideal selectivity increased up to 20 wt% of ZIF-8 and amineZIF-8 contents in both PEBAX/ZIF-8 and PEBAX/ amineZIF-8 composite membranes, and then decreased thereafter, in the case of PEBAX/amineZIF-8 composite membrane was less decreased. The reason for the highest CO2/N2 ideal selectivity at 20 wt% of amineZIF-8 is that amine modification improved the compatibility between PEBAX and amineZIF-8, and thus amineZIF-8 was evenly dispersed in PEBAX, resulting in the greatest effect of the porous ZIF-8 with a 3.4 Å pore size and the amine with affinity for CO2.