• Membrane Journal
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• v.25 no.5
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• pp.373-384
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• 2015

In the past few decades, polymeric membrane has played an important role in gas separation applications. For the separation of $CO_2$, one of greenhouse gases, high permselectivity, long-term stability and scale-up are needed. However, conventional polymeric membranes have shown a trade-off relation between permeability and selectivity while inorganic materials are highly permeable but expensive. Mixed matrix membranes (MMMs) combining the advantages of both polymeric and inorganic materials have become a possible breakthrough for the next-generation gas separation membranes. The MMMs could be either symmetric or asymmetric but the latter is more preferred to improve the permeance. Important factors influencing the MMM fabrication include homogeneous distribution of inorganic particles and good interfacial contact between inorganic filler and organic matrix. Recently, metal organic frameworks (MOFs) have received much attention as a new class of porous crystalline materials and a potential candidate for $CO_2$ separation. Zeolitic imidazolate frameworks (ZIFs), a sub-branch of MOFs, are the most widely used in MMMs due to small particle size and appropriate pore size for $CO_2$ separation. One of the major issues associated with the incorporation of porous particles in a polymeric membrane is to control the microstructure of the porous particle materials such as particle size, orientation, and boundary conditions etc. In this review, major challenges surrounding MMMs and the strategies to tackle these challenges are given in detail.

• Analytical Science and Technology
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• v.6 no.4
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• pp.383-390
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• 1993

Retention behaviors of aliphatic and aromatic compounds were investigated with Van der Waals volume which represented the molecular size. The organic solvents, methanol, acetonitrile and tetrahydrofuran, were mixed with water at various ratio, respectively. The selectivity of organic solvents were tested by change of column temperature. The capacity factor was increased linearly according to the enlargement of molecular size. Therefore, Van der Waals volume was useful to predict the elution of organic molecules in reversed-phase column. The order of elution capacity of solvents was methanol

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.54 no.3
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• pp.193-203
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• 2018

Capture efficiencies of commercial shrimp trawls may improve if their designs took into better account behavioral responses of wild shrimp to approaching cod-end of the trawls. Here we report results of water tunnel-based experimental studies of responses of wild California target prawns to several different near-realistic netting configurations over a range of water velocities (0.3-0.7 m/s). Netting panels were oriented at parallel to water flows (FP) on the bottom of test section, vertical (VT) or diagonal sloping backward (DG), bottom to top. Behavioral responses were recorded by video camera and analyzed frame by frame. Measured responses included rates of penetrating through netting by behavioral features and tail-flip frequencies. Frequencies of prawn passing through the nets increased with flow speed for both orientations and were higher at given speeds for sloped nets. Other behavioral features (e.g., passage head-or tail-first) also varied significantly with water velocities and netting orientation. Interactions of penetrating rates between netting orientations and flow speeds also were significantly dependent, except for prawn size. Additional studies are needed of other shrimp species and at higher water velocities more similar to actual field operations using trawls to improve size selectivity.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.44 no.1
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• pp.10-19
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• 2008

This paper focuses on the mackerel's visual ability and swimming capability, and aims to describe the behavior in capture and escape process by trawl. The visual sensory systems and reaction behavior based locomotory capability were analyzed and simulated. The ability of fish to see an object depends on the light intensity and the contrast and size of the object. Swimming endurance of the fish is dependent on the swimming speed and the size of the fish. Swimming speeds of the fish are simulated 3 types of the burst speed, the prolonged speed and the sustained speed according to the time they can maintain to swim. The herding and avoiding is typical reaction of the fish to the stimuli of trawl gear in the capture process. These basic behavior patterns of the virtual mackerel to the gear are simulated. This simulation will be helpful to understand the fishing processes and make high selectivity of fishing.

• Fisheries and Aquatic Sciences
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• v.14 no.2
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• pp.130-137
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• 2011

Visual stimuli of nets, which affect fishing selectivity, vary by twine diameter, color, and material under different light conditions and visual geometries. In this study, two cylindrical model codends of two mesh sizes, 28 and 43 mm, were made of high-contrast, dark brown polyethylene (PE) netting twine and low contrast, light-blue polyamid (PA) monofilament twine. Each model codend was filled with juvenile seabream and set in the water channel of a light-blue circular tank under a flow speed 0.8 m/s for 30 min. Light conditions were set to relatively bright, dim, and dark. The resulting retention rates of juvenile seabream were 15-35% lower for the low-contrast codend with PA monofilament than for the high contrast PE twine netting under bright and dim light conditions, while no difference was observed under dark conditions. The effects of mesh size and netting contrast on the retention rate were dependent on the light level, while the retention rate due to netting contrast was independent of mesh size. Therefore, low-contrast nets in the codend could help to reduce juvenile bycatch by disturbing the orderly optomotor response.

• ETRI Journal
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• v.31 no.3
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• pp.254-262
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• 2009

This paper presents a novel simple filter design method based on a parallel short-ended coupled-line structure with capacitive loading for size reduction and ultra-broad rejection of spurious passbands. In addition, the introduction of a cross-coupling capacitor into the miniaturized coupled-line can create a transmission zero at the second harmonic frequency for better frequency selectivity and attenuation level. The aperture compensation technique is also applied to achieve a strong coupling in the coupled-line section. The influence of using the connecting transmission line to cascade two identical one-stage filters is studied for the first time. Specifically, such a two-stage bandpass filter operating at 2.3 GHz with a fractional bandwidth of 10% was designed and realized with low-temperature co-fired ceramic technology for application in base stations that need high power handling capability. It achieved attenuation in excess of -40 dB up to $4f_0$ and low insertion loss of -1.2 dB with the size of 10 mm ${\times}$ 7 mm ${\times}$ 2.2 mm. The measured and simulated results showed good agreement.

• Bulletin of the Korean Chemical Society
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• v.24 no.9
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• pp.1339-1344
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• 2003

Flow field-flow fractionation (FlFFF) is a technology to separate the molecules by size in an open channel. Molecules with different size have different diffusivities and are located vertically in different positions when passing through an open channel. In this study, hollow fiber membranes instead of conventional rectangular channels have been used as materials for the open channel and this change would decrease the cost of manufacturing. FlFFF is a useful technique to characterize the biopolymeric materials. Retention time, diffusion coefficients and Stokes radius of analysis can be calculated from the related simple equations. Hollow-fiber flow field-flow fractionation (HF-FlFFF) has been used for the characterization and separation of protein mixture in a phosphate buffer solution and has demonstrated the potential to be developed into a disposable FlFFF channel. The important indexes for the analytical separation are selectivity, resolution and plate height. The optimized separation condition for protein mixture of Ovalbumin, Alcohol dehydrogenase, Apoferritin and Thyroglobulin is ${\dot V}_{out}/{\dot V}_{rad}=0.65/0.85\;mL/min$.

• Animal cells and systems
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• v.16 no.4
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• pp.343-349
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• 2012

A variety of fish species undergo an ontogenetic change in prey selectivity, and several potentially interacting factors, including nutrient requirement, microhabitat change, and foraging ability, may account for the occurrence of the shift. Here we examine the foraging ecology and ontogenetic diet shift of a micro-carnivorous goby, Pterogobius elapoides (serpentine goby), dominant component of fish assemblage in shallow rocky areas off the coast in Korea and Japan. Although most other gobies are primarily benthic carnivores, P. elapoides is a semipelagic fish; however, little is known about how those species change their foraging tactics with growth. In our diet analyses, the most common diet was pelagic copepods and benthic amphipods, and diet shift was observed from pelagic to benthic with growth. The ontogenetic diet shift seems to be the result of the preference for energetically more profitable prey in larger-size classes as well as the results of different prey availability due to among-habitat variation in diet. However, differential food preference does not appear to affect individual scope for searching food. Several factors such as predation pressures and interspecific resource partitioning might contribute to the changes in diet observed among size classes, which were included in our ongoing tests.

• Proceedings of the Membrane Society of Korea Conference
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• 2003.07a
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• pp.91-94
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• 2003

In this work, the physicochemical properties for permeant molecules and polyion complex membrane prepared by complexation between SA and chitosan were determined by using molecular modeling methods, and the permeation behaviors of water and alcohol molecules through the PIC membrane have been investigated. In the case of penetrant molecule, the experimental results showed that the prepared membrane was excellent pervaporation performance result in most solution, and the selectivity and permeability of the membrane were dependent on the molecular size, the polarity and the hydrophilic surface of permeant organics. However, the separation behavior of methanol aqueous solution exhibited other permeation tendency with other feed solutions and contradictory result. That is, the membrane were preferentially permeable to methanol over water despite water molecule has stronger polarity and small molecular size than methanol molecule. In this study, the results were discussed from the viewpoint of chemical and physical properties between permeant molecules and membrane in the diffusion state.

• Journal of Biosystems Engineering
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• v.41 no.2
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• pp.75-84
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• 2016

Purpose: In-situ water quality monitoring based on ion-selective electrodes (ISEs) is a promising technique because ISEs can be used directly in the medium to be tested, have a compact size, and are inexpensive. However, signal drift can be a major concern with on-line management systems because continuous immersion of the ISEs in water causes electrode degradation, affecting the stability, repeatability, and selectivity over time. In this study, a computer-based nitrate monitoring system including automatic electrode rinsing and calibration was developed to measure the nitrate concentration in water samples in real-time. Methods: The capabilities of two different types of poly(vinyl chloride) membrane-based ISEs, an electrode with a liquid filling and a carbon paste-based solid state electrode, were used in the monitoring system and evaluated on their sensitivities, selectivities, and durabilities. A feasibility test for the continuous detection of nitrate ions in water using the developed system was conducted using water samples obtained from various water sources. Results: Both prepared ISEs were capable of detecting low concentrations of nitrate in solution, i.e., 0.7 mg/L $NO_3-N$. Furthermore, the electrodes have the same order of selectivity for nitrate: $NO_3{^-}{\gg}HCO_3{^-}$ > $Cl^-$ > $H_2PO_4{^-}$ > $SO{_4}^{2-}$, and maintain their sensitivity by > 40 mV/decade over a period of 90 days. Conclusions: The use of an automated ISE-based nitrate measurement system that includes automatic electrode rinsing and two-point normalization proved to be feasible in measuring $NO_3-N$ in water samples obtained from different water sources. A one-to-one relationship between the levels of $NO_3-N$ measured with the ISEs and standard analytical instruments was obtained.