• Title/Summary/Keyword: Sintering condition

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Suppression of Interfacial Segregation and Control of Microstructure for Improvement of Mechanical Properties of W-Ni-Fe Heavy Alloy (계면편석 억제와 미세구조 조절에 의한 중합금의 기계적성질 향상)

  • 강석중
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 1993.11a
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    • pp.3-3
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    • 1993
  • In mechanical testing of W-Ni-Pe heavy alloys, the cracks nucleate at W/W interface and propagate through W/ Imatrix interface or through matrix phase together with the cleavage of W grains. The mechanical properties can therefore be improved by control of the interfacial strength and area. In this presentation, some experimental result and techniques on this subject will be reviewed and discussed. The hydrogen embrittlement caused by the hydrogen segregation at interfaces during sintering in an hydrogen atmosphere can be removed by an heat-treattnent in vacuum or in an inert atmosphere. The heat-treatment condition can be estimated by using a diffusion equation for a cylindrical shape. The mechanical properties, in particular the impact property, are degraded by the segregation of non-metallic impurities, such as Sand P. The degradation can be prevented by adding a fourth element, such as La or Ca, active with the non-metallic impurities. The cyclic heat-treatment at usual heat-treattnent tempemture causes the penetration of matrix between W/W grain boundaries and results in remarkable increase in impact energy. This is due to an increase in the area of ductile failure during the impact test. The instability of W/matrix interface casued by addition of Mo or Re can be controlled by using W powders of different size. The increase in the interfacial area in found to be related to the presence of non-equilibrium pure W gmins among W(Mo or Re) solid solution gmins.

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Electrical Characteristics and Performance Evaluation with Manufacturing Process of Zinc Oxide Varistors (산화아연소자의 성형공정에 따른 전기적 특성과 성능평가)

  • Cho, Han-Goo;Yoon, Han-Soo;Kim, Suk-Soo;Choi, In-Hyuk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.11
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    • pp.1061-1066
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    • 2006
  • This paper presents the electrical characteristics with manufacturing process and performance evaluation of high performance zinc oxide varistors. ZnO varistors were fabricated with typical ceramic production methods with different thickness and the structural and electrical characteristics of ZnO varistors were investigated. All varistors exhibited high density, which was in the range of $5.41{\sim}5.49g/cm^3$. In the electrical properties, the reference voltage increased in the range of $4.410{\sim}5.250kV$ with increasing their thickness and the residual voltage exhibited the same trends as the reference voltage. In the long duration current impulse withstand test, E-2 and F-1 samples failed at the two and four shots of impulse current, respectively, but E-1 and F-2 samples survived 18 shots during the test. Before and after this test, the variation ratio of residual voltage of E-1 and F-2 samples were -0.34 % and 0.05 %, respectively, which were in the acceptance range of 5 %. According to the results of tests, it is thought that if the fabrication process such as insulating coating, sintering condition, and soldering method is improved, these ZnO varistors would be possible to apply to the station class arresters in the near future.

Effect of Residual Impurity on Magnetic Properties of the Permalloy Soft Magnet by Powder Injection Molding (분말사출성형으로 제조된 퍼말로이 연자성체에서 잔류 불순물이 자기특성에 미치는 영향)

  • 정원용;최준환;정우상
    • Journal of the Korean Magnetics Society
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    • v.10 no.6
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    • pp.291-296
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    • 2000
  • The manufacturing method of permalloy soft magnet with the Ni contents of 46.6 and 47.2 wt% was investigated by powder injection molding technology. The magnetic properties of permalloy were greatly affected on the residual carbon and oxygen content of the sintered magnet. Solvent extraction and thermal debinding process to minimize the residual carbon content in sintered magnet were developed by controlling the debinding atmosphere. The residual carbon content depends on the debinding condition of the binder system for powder injection molding and the residual oxygen content on the sintering atmosphere. The sintered magnet produced by powder injection molding process had a 50 ppm. residual carbon, 150 ppm. residual oxygen. The coercivity and maximum relative permeability of permalloy soft magnet were 0.46 Oe and 14,600 respectively.

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A Stydy on Steel Wire Fiber Reinforced Refractory Castable (철근 캐스터블 내화물의 고온특성에 관한 연구)

  • 박금철;최영섭;한문희;장영재;박근원
    • Journal of the Korean Ceramic Society
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    • v.17 no.2
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    • pp.69-74
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    • 1980
  • This study deals with the wire content, wire diameter, aspect ratio , it's arrangement of steel, wire fiber and the sorts of castable which affected the character of steel wire fiber reinformced refractory castable. Two kinds of alumina based refractory castables, one is for 1650℃ and the other is for 1800℃, and stainless steel which is SUS 304 type 0.25, 0.34 , 0.37 and 0.50m/min diameter were used respectively. Aspect ratio was adjusted to 50, 75, 100 and steel fiber content was also adjusted to 1-4wt% each. The results of the experiment were as follows : 1. At firing temperature around 1,000℃, MOR is increased with increasing wire content and aspect ratio with decreasing firing temperature, which depends on the Romualdi's Fiber Spacing Theory. But for calculation of the fiber spacing, Swamy equation is more a aplicable to the extensive fiber mixing conditions. However, the condition differs from the above at firing temperature around 1,350℃ ,because of the degradation of wire and the progress of sintering of castable. 2. Linear change is getting larger corresponding to the increase of wire content, and the spaling resistivity is increasing corresponding to the increase of wire content and to aspect ratio, and with decreasing wire diameter. 3. Firing shrinkage under load is getting greater as higher wire content, and the shrinkage of the test pieces which fiber is vertically oriented is getting greater than the test pieces which fiber is randomly oriented.

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The Design and Manufature by Analysis of AC Loss of high temperature supercondutor wire of Ag-sheath Bi-2223 (Ag-sheath Bi-2223 고온 초전도 선재 AC 손실 해석에 따른 설계 및 제작)

  • Jang, Mi-Hae;Chu, Yong;Lee, Joon-Young;Ko, Tae-Kuk
    • Proceedings of the KIEE Conference
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    • 1998.07a
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    • pp.349-352
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    • 1998
  • In future superconducting electrical machines and device. AC loss in the superconducting windings are one of the most impotent design paramenters. This paper descriptions a series of Characteristic of a high-Tc superconducting Bi-Pb-Sr-Ca-Cu-O Ag-sheathed filament. In the case simulation and design to reduce ac loss is considered the filament number, twitch pith number and diameter of filament. A filament sample with Tc of 78K is made by $835^{\circ}C$ sintering for 50h and $0.33^{\circ}C$/min heating rate in an atmosphere. The experiment observations are compared with self-field loss and AC losses of Bi-Pb-Sr-Ca-Cu-O filament at 77K in following environments ; (i)AC external parallel magnetic field in different frequencies. And an analytical expression of the loss the derivation of transposition from an optimum condition was derived for the external AC magnetic field, theoretical predictions were found to coincide with the experimental observations.

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Machining characteristics on ultrasonic vibration assisted micro-electrical discharge machining of carbon-nanotube reinforced conductive Al2O3 composite (전도성을 가지는 탄소나노튜브강화 알루미나복합소재의 마이크로방전가공에서 초음파진동 부가에 의한 가공특성)

  • Kang, Myung-Chang;Tak, Hyun-Seok;Lee, Chang-Hoon;Kim, Nam-Kyung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.13 no.6
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    • pp.119-126
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    • 2014
  • Micro-holes of conductive ceramic are required in micro structures. Micro-electrical discharge machining (Micro-EDM) is an effective machining method since EDM is as process for shaping hard metals and complex-shaped holes by spark erosion in all kinds of electro-conductive materials. However, as the depth of micro hole increases, the machining condition becomes more unstable due to inefficient removal of debris between the electrode and the workpiece. In this paper, micro-EDM was performed to evaluate machining characteristic such as electrode wear, machining time, taper angle, radial clearance with varying voltage and ultrasonic vibration on 10 vol.% Carbon-nanotube reinforced conductive $Al_2O_3$ composite fabricated by spark plasma sintering in previous research.

An analysis of the Wi-Ni Carbide Alloy Diffusion Bonding technique in its application for DME Engine Fuel Pump

  • Chun, Dong-Joon
    • International Journal of Advanced Culture Technology
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    • v.8 no.2
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    • pp.246-251
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    • 2020
  • Dimethyl Ether(DME) engine use a highly efficient alternative fuel having a great quantity of oxygen and has a advantage no polluting PM gas. The existing DME fuel cam material is a highly expensive carbide alloy, and it is difficult to take a price advantage. Therefore the study of replacing body area with inexpensive steel material excluding piston shoe and contact area which demands high characteristics is needed. The development of WC-Ni base carbide alloy optimal bonding composition technique was accomplished in this study. To check out the influence of bonding temperature and time, bonding characteristics of sintering temperature was experimented. The hardness of specimen and bonding rate were measured using ultrasound equipment. The bonding state of each condition was excellent, and the thickness of mid-layer, temperature and maintaining time were measured. The mid-layer thickness according to bonding temperature and maintaining time were observed with optical microscope. We analyzed the micro-structural analysis, formation of bonding specimen, wafer fabrication and fuel cam abrasion test. Throughout this study, we confirmed that the fuel cam for DME engine which demands high durability against velocity and pressure is excellent.

The Power Supply System for Xenon Lamp Light Sintering (광소결용 제논 램프 구동을 위한 파워 서플라이 시스템)

  • Cho, Chan-Gi;Song, Seung-Ho;Park, Su-Mi;Park, Hyeon-Il;Bae, Jung-Soo;Jang, Sung-Roc;Ryoo, Hong-Je
    • Proceedings of the KIPE Conference
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    • 2017.07a
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    • pp.327-328
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    • 2017
  • This paper presents the power supply system which is made of three units: the capacitor charging and main pulse unit, simmer power supply unit, and series trigger unit. The capacitor charging and main pulse unit charges the capacitor bank by using the series parallel resonant converter and the generated main pulses apply to the lamp. The series trigger unit ionize the xenon gas located in the lamp and the simmer power supply unit sustains the ionized condition. It means that the lamp lifetime and efficiency are advanced by reducing the number of triggering. Not only the operation of the proposed system but also the performance of each unit will be verified by the experimental results.

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Research for Solder Paste in Metallic Glass System for Thermoelectric Modules (고온열전모듈용 금속유리계 페이스트 연구)

  • Seo, Seung-Ho;Son, Geun Sik;Seo, Kang Hyun;Choi, Soon-Mok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.4
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    • pp.249-254
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    • 2018
  • We researched about a bulk metallic glass system as an additive to an Ag paste for high temperature thermoelectric modules. Bulk metallic glass (BMG) ribbons were produced by using a rapid solidification process (RSP) under a cooling rate condition higher than $10^{\circ}C/sec$. We investigated BMG characteristics of the ribbons by means of x-ray diffraction (XRD) and differential scanning calorimetry (DSC) in order to evaluate the glass transition temperature ($T_g$) and the recrystallization temperature ($T_x$) lower than $400^{\circ}C$. A milling process was also developed to apply the BMG ribbons to a commercial Al paste as an additive for lower sintering temperature.

Effects of Gd2O3 Addition on Optical and Electrical Properties of MgO Films as a Protective Layer for AC PDPs (Gd2O3 첨가에 따른 AC PDP 보호막용 MgO 박막의 광학적.전기적 특성)

  • Kim, Chang-Il;Lim, Eun-Kyeong;Park, Young-Jun;Lee, Young-Jin;Paik, Jong-Hoo;Choi, Eun-Ha;Juang, Seok;Kim, Jeong-Seok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.7
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    • pp.620-625
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    • 2007
  • The effects of $Gd_2O_3$ addition and sintering condition on optical and electrical properties of MgO films as a protective layer for AC plasma display panels were investigated. Doped MgO films prepared by the e-beam evaporation have a higher ${\Upsilon}$ (secondary electron emission coefficient) than pure MgO protective layer. Relative density and grain size increased with amount of $Gd_2O_3$ up to 100 ppm and then decreased further addition. These results showed that discharge properties and optical properties of MgO protective layers seemed to be closely related with microstructure factors such as relative density and grain size. Good optical and electrical properties of ${\Upsilon}$ of 0.138, surface roughness of 5.77 nm and optical transmittance of 95.76 % were obtained for the MgO+100 ppm $Gd_2O_3$ protective layer sintered at $1700^{\circ}C$ for 5 hrs.