• Title/Summary/Keyword: Single-walled Carbon Nanotubes

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High-yield synthesis of thin multiwalled carbon nanotubes and their field emission characteristics

  • Jeong, Hee-Jin;Song, Young-Il;Choi, Ha-Kyu;Kim, Gil-Yong;Yu, Tong;Lim, Seong-Chu;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1443-1446
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    • 2005
  • We have synthesized thin multi-walled carbon nanotubes (t-MWCNTs) using a catalytic chemical vapor deposition (CCVD) method with FeMoMgO catalyst. The number of tube walls were 2 ${\sim}$ 6 with the corresponding diameters of 3 ${\sim}$ 6 nm. We obtained high production yield of over 3000 wt% compared to the weight of the supplied catalyst. These t-MWCNTs revealed the intermediate structural characteristics between single- and multi-walled carbon nanotubes (SWCNTs and MWCNTs). We have also characterized the field emission properties such as turn-on field and emission current, and current degradation from these t-MWCNTs together with SWCNTs and MWCNTs.

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Highly Stretchable and Sensitive Strain Sensors Fabricated by Coating Nylon Textile with Single Walled Carbon Nanotubes

  • Park, Da-Seul;kim, Yoonyoung;Jeong, Soo-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.363.2-363.2
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    • 2016
  • Stretchable strain sensors are becoming essential in diverse future applications, such as human motion detection, soft robotics, and various biomedical devices. One of the well-known approaches for fabricating stretchable strain sensors is to embed conductive nanomaterials such as metal nanowires/nanoparticles, graphene, conducting polymer and carbon nanotubes (CNTs) within an elastomeric substrate. Among various conducting nanomaterials, CNTs have been considered as important and promising candidate materials for stretchable strain sensors owing to their high electrical conductivity and excellent mechanical properties. In the past decades, CNT-based strain sensors with high stretchability or sensitivity have been developed. However, CNT-based strain sensors which show both high stretchability and sensitivity have not been reported. Herein, highly stretchable and sensitive strain sensors were fabricated by integrating single-walled carbon nanotubes (SWNTs) and nylon textiles via vacuum-assisted spray-layer-by-layer process. Our strain sensors had high sensitivity with 100 % tensile strain (gauge factor ~ 100). Cyclic tests confirmed that our strain sensors showed very robust and reliable characteristic. Moreover, our SWNTs-based strain sensors were easily and successfully integrated on human finger and knee to detect bending and walking motion. Our approach presented here might be route to preparing highly stretchable and sensitive strain sensors with providing new opportunity to realize practical wearable devices.

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Development of single walled-carbon nanotubes based pH sensor using ultra-precision spray method (초정밀 스프레이 방법을 이용한 단일벽 탄소나노튜브 pH센서 개발)

  • Kwon, Jae-Hong;Lee, Kyong-Soo;Lee, Yun-Hi;Ju, Byeong-Kwon
    • Journal of Sensor Science and Technology
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    • v.15 no.2
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    • pp.127-133
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    • 2006
  • Recent studies demonstrated the ability of carbon nanotube (CNT) to promote electron transfer reactions of important compounds and to impart higher stability onto electrochemical sensors. CNT-based sensors measured by hydroxyl radical concentration or pH value suggest great promise for biosensors. This paper describes a new method for fabricating a very simple and inexpensive pH sensor compose of single walled-carbon nanotubes (SW-CNTs) using an ultra-precision spray. CNT-based sensor shows pH sensitivity in buffer solution at different pH range. Our experimental results show the sensor responses to pH buffer solution and the conductance of depends on the pH values. These results support application possibility of SW-CNTs based pH sensor for mass production.

Characterization of Single-walled Carbon Nanotubes Synthesized by Water-assisted Catalytic Chemical Vapor Deposition

  • Lee, Yeon-Ja;Kim, Bawl;Yu, Zhao;Lee, Cheol-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.381-381
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    • 2011
  • The influence of the water vapor on the growth of single-walled carbon nanotubes (SWCNTs) was investigated. SWCNTs were synthesized by catalytic chemical vapor deposition of acetylene over Fe-Mo/MgO catalyst with injection of water vapor. The morphologies and structures of the water-assisted SWCNTs were investigated according to the growth conditions such as water vapor concentrations, flow rate of the gas, furnace temperature, and growth time. Water-assisted SWCNTs exhibited large bundle morphological features with well-alignment of each CNT, while SWCNTs synthesized in the absence of water vapor showed entangled CNT with the random orientation. We also found that the diameter of the SWCNT bundle could be controlled by the growth condition. In our optimal growth condition, the product yield and the purity were 300 wt. % and 75%, which were 7.5 and 2.5 times higher than those of SWCNTs synthesized without water vapor, respectively. More detail discussion will be offered at the poster presentation.

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Simulation of Hydrogen Transport in a Single-walled Carbon Nanotube for Storage Safety

  • Oh, Kyung-Su;Kim, Dong-Hyun;Park, Seung-Ho;Kim, Jung-Soo
    • International Journal of Safety
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    • v.6 no.1
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    • pp.16-21
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    • 2007
  • Carbon nanotubes hold much promise as future materials for safe storage of hydrogen. In this paper, hydrogen transport mechanisms in single-walled carbon nano-tubes (SWNTs) for various temperatures and chiral indices were studied using molecular dynamics simulation method. The SWNT models of zigzag (10,0), chiral (10,5) and armchair (10,10) with hydrogen molecules inside were simulated at temperatures ranging from 253K to 373K. Movements of hydrogen molecules ($H_2$) inside a SWNT were analyzed using mean-square displacements and velocity autocorrelation functions.

Effect of nitrogen doping and hydrogen confinement on the electronic properties of a single walled carbon nanotube

  • Bhat, Bashir Mohi Ud Din;Dar, Jehangir Rashid;Sen, Pratima
    • Carbon letters
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    • v.17 no.1
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    • pp.29-32
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    • 2016
  • This paper addresses the effect of dopants on the electronic properties of zigzag (8, 0) semiconducting single walled carbon nanotubes (SWCNTs), using extended Hückel theory combined with nonequilibrium Green’s function formalism. Through appropriate dopant concentrations, the electronic properties of SWCNTs can be modified. Within this context, we present our ongoing investigation on (8, 0) SWCNTs doped with nitrogen. Quantum confinement effects on the electronic properties of the SWCNTs have also been investigated. The obtained results reveal that the electronic properties of SWCNTs are strongly dependent on the dopant concentration and modification of electronic structures by hydrogen confinement.

Solution Processed Single Walled Carbon Nanotubes Transparent Conducting Films (투명전도막을 위한 용해 처리된 단일막 탄소나노튜브)

  • Manivannan, S.;Jeong, Il-Ok;Ryu, Je-Hwang;Jang, Jin;Park, Kyu-Chang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.45-45
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    • 2008
  • In recent years, new materials and technology has been developed using single-walled carbon nanotubes (SWCNTs) as an alternative to indium tin oxide (ITO) to fulfil the requirements towards novel technological drive. These technologies offer products having a broad range of conductivity, excellent transparency, neutral color tone, good adhesion, abrasion resistance as well as mechanical robustness. In addition, SWCNTs can be solution processed to replace the sophisticated vacuum techniques at high temperatures. In the present work, transparent conducting films were fabricated from the purified SWCNTs. Dispersion of purified SWCNTs was accomplished in 1,2-dichlorobenzene without using surfactants or polymers following ultrasonic process. We achieved coating of nanotubes film on poly ether suiphone (PES) for an average sheet resistance ~110 ${\Omega}/{\Box}$ of optical transmittance 80% at 550 nm. Conventional spin coating method was followed to fabricate films from the purified and dispersed nanotubes solution. The results will be presented.

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SWCNT/Nafion Composite Development for Improvement of Mechanical Properties of IPMC (IPMC의 기계적 특성향상을 위한 SWCNT/Nafion 복합체 개발)

  • Kwon, Hui-June;Lee, Heon-Sang;Lee, Jung-Hwa;Jun, Chan-Bong;Kang, Jung-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.1
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    • pp.47-53
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    • 2011
  • From recent research, it has revealed that Electroacitve polymer(EAP) has a physical limitation. Carbon nanotube(CNT) is known as the promising material which has excellent electro-mechanical characteristics and is mostly defect-free. It is expected that a successful synthesis of CNT and Nafion known as a primary material for IPMC would make a great improvement on its electro-mechanic feature. In this paper, we suggest the method of synthesis of CNT with Nafion which improves electro-mechanical characteristic. Using mechanical dispersion with Nafion and Isopropyl Alcohol(IPA), we disperse Single-walled carbon nanotubes(SWCNT). For a uniformly layer of CNT, we used a spray gun on a hot plate by a simplified method. In the result, we fabricated a disperse SWCNT/Nafion composite uniformly.