• 한국재료학회지
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• 제9권8호
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• pp.792-797
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• 1999

고체 산화물 연료전지의 전해질로 주로 사용되는 8mol.%$Y_2$$O_3$-$ZrO_2$는 전기 전도성은 우수하나 기계적 특성이 좋지 못하므로, 전기적 특성과 기계적 특성이 동시에 우수한 고체산화물 연료전지의 전해질의 개발이 요구되고 있다. 본 연구는 이러한 두 가지 요구조건을 충족시키기 위해서 수행되어졌다. 단위전지의 공기극 재료인 LSM(La(sub)0.75Sr(sub)0.25MnO$_3$) 기판과 Si wafer를 기판으로 기계적 성질이 우수한 3mol.%의 YSZ(3-YSZ)와 전기 전도성이 우수한 8mol.%의 YSZ(8-YSZ)를 각각 단층 및 다층 박막의 네 가지 형태로 전자빔 코팅에 의해 전해질 막을 제작하였다. 박막층의 분석결과, 결정조직은 증착된 3-YSZ 박막의 정방정 및 일부 단사정 구조, 8-YSZ 박막은 입방정 구조의 결정성이 나타났다. 단층막 보다 다층막이 낮은 내부 응력을 보였으며, 다층막이 기존의 8-YSZ 단층막의 열처리 전, 후와 비슷한 미세 경도 값을 보였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.2-2
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• 2011

Single-walled carbon nanotubes (SWNTs) have been considered as a promising candidate for nextgeneration electronics due to its extraordinary electrical properties associated with one-dimensional structure. Since diversity in electronic structure depends on geometrical features, the major concern has been focused on obtaining the diameter, chirality, and density controlled SWNTs. Despite huge efforts, the controlled synthesis of SWNTs has not been achieved. There have been various approaches to synthesize controlled SWNTs by preparation of homogeneously sized catalyst because the SWNTs diameter highly depends on catalyst nanoparticles size. In this study, geometrically controlled SWNTs were synthesized using designed catalytic layers: (a) morphologically modified Al2O3 supporting layer (Fe/Al2O3/Si), (b) Mo capping layer (Mo/Fe/Al/Si), and (c) heat-driven diffusion and subsequent evaporation process of Fe catalytic nanoparticles (Al2O3/Fe/Al2O3/Si). These results clearly revealed that (a) the grain diameter and RMS roughness of Al2O3 supporting layer play a key role as a diffusion barrier for obtaining Fe nanoparticles with a uniform and small size, (b) a density and diameter of SWNTs can be simultaneously controlled by adjusting a thickness of Mo capping layer on Fe catalytic layer, and (c) SWNTs diameter was successfully controlled within a few A scale even with its fine distribution. This precise control results in bandgap manipulation of the semiconducting SWNTs, determined by direct comparison of Raman spectra and theory of extended tight binding Kataura plot. We suggest that these results provide a simple and possible way for the direct growth of diameter, density, and bandgap controlled SWNTs by precise controlling the formation of catalytic films, which will be in demand for future electronic applications.

• 한국음향학회지
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• 제24권3호
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• pp.127-132
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• 2005

이식형 인공중이용 트랜스듀서는 주파수 특성 및 구동 성능이 우수해야 하고 크기가 작아야 한다. 이러한 트랜스듀서로서 단결정 압전 재료인 PMN-PT를 이용한 적층형 액츄에이터를 제안하였고, 유한요소해석 및 제작실험을 통해 그 타당성을 밝혔다. 실험에서는 두께 $0.2{\cal}mm$를 갖는 시편을 14층으로 쌓아 최종적으로 $1{\cal}mm{\times}1{\cal}mm{\times}2.8{\cal}mm$ 크기의 PMN-PT 적층형 액츄에이터를 제작하였다. 제작된 PMN-PT 액츄에이터의 성능은 Impedance Spectrum과 구동변위 측정을 통해 PZT 액츄에이터와 비교, 평가하였고, 이를 통해 단결정 재료인 PMN-PT를 이용할 경우 우수한 성능의 인공중이용 액츄에이터 제작이 가능함을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제35권10호
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• pp.2895-2900
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• 2014

We fabricated quantum dot-sensitized solar cells (QDSSCs) using cadmium sulfide (CdS) and cadmium telluride (CdTe) quantum dots (QDs) as sensitizers. A spin coated $TiO_2$ nanoparticle (NP) film on tin-doped indium oxide glass and sputtered Au on fluorine-doped tin oxide glass were used as photo-anode and counter electrode, respectively. CdS QDs were deposited onto the mesoporous $TiO_2$ layer by a successive ionic layer adsorption and reaction method. Pre-synthesized CdTe QDs were deposited onto a layer of CdS QDs using a direct adsorption technique. CdS/CdTe QDSSCs had high light harvesting ability compared with CdS or CdTe QDSSCs. QDSSCs incorporating single-walled carbon nanotubes (SWNTs), sprayed onto the substrate before deposition of the next layer or mixed with $TiO_2$ NPs, mostly exhibited enhanced photo cell efficiency compared with the pristine cell. In particular, a maximum rate increase of 24% was obtained with the solar cell containing a $TiO_2$ layer mixed with SWNTs.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.444-444
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• 2011

Recently, patterned magnetic films and elements attract a wide interest due to their technological potentials in ultrahigh-density magnetic recording and spintronic devices. Among those patterned magnetic structures, magnetic anti-dot patterning induces a strong shape anisotropy in the film, which can control the magnetic properties such as coercivity, permeability, magnetization reversal process, and magneto-resistance. While majority of the previous works have been concentrated on anti-dot arrays with a single magnetic layer, there has been little work on multilayered anti-dot arrays. In this work, we report on study of the magnetic properties of bilayered anti-dot system consisting of upper perforated Co layer of 40 nm and lower continuous Ni layer of 5 nm thick, fabricated by photolithography and wet-etching processes. The magnetic hysteresis (M-H) loops were measured with a superconducting-quantum-interference-device (SQUID) magnetometer (Quantum Design: MPMS). For comparison, investigations on continuous Co thin film and single-layer Co anti-dot arrays were also performed. The magnetic-domain configuration has been measured by using a magnetic force microscope (PSIA: XE-100) equipped with magnetic tips (Nanosensors). An external electromagnet was employed while obtaining the MFM images. The MFM images revealed well-defined periodic domain networks which arise owing to the anisotropies such as magnetic uniaxial anisotropy, configurational anisotropy, etc. The inclusion of holes in a uniform magnetic film and the insertion of a uniform thin Ni layer, drastically affected the coercivity as compared with single Co anti-dot array, without severely affecting the saturation magnetization ($M_s$). The observed changes in the magnetic properties are closely related to the patterning that hinders the domain-wall motion as well as to the magneto-anisotropic bilayer structure.

• 한국표면공학회지
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• 제45권3호
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• pp.111-116
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• 2012

Oblique angle deposition (OAD) is a physical vapor deposition method which utilizes non-normal angles between the substrate and the vaporizing source. It has been known that tilting the substrate changes the properties of the film deposited on it, which was thought to be a result of morphological change of the film. In this study, OAD has been applied to prepare single and multilayer Al films by magnetron sputtering. The magnetron sputtering source of 4 inch diameter was used to deposit the films. Al films have been deposited on Si wafers and cold-rolled steel sheets. The multilayer films were prepared by changing the tilting angle upside down at each layer interval, which means that when the first layer was deposited at an angle of $+45^{\circ}$, the second layer was deposited at an angle of $-45^{\circ}$, and vice versa. The microstructure, surface roughness and reflectance of the films were investigated using a scanning electron microscope, a surface profiler and a spectrophotometer, respectively. The corrosion resistance was measured and compared using the salt spray test. The single layer film prepared at an oblique angle of $60^{\circ}$ prepared at other angles. However, for the multilayer films, the film prepared at an oblique angle of $45^{\circ}$ showed the most compact and featureless structure. The multilayer films were found to exhibit higher corrosion resistance than the single layer films.

• Structural Monitoring and Maintenance
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• 제9권1호
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• pp.29-42
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• 2022

In mountainous areas of China, concrete poles with connectors are widely employed in power transmission due to its convenience of manufacture and transportation. The bearing capacity of the poles must have degenerated over time, and most of the steel connectors have been corroded. Carbon fiber reinforced polymer (CFRP) offers a durable, light-weight alternative in strengthening those poles that have served for many years. In this paper, the bearing capacity and failure mechanism of CFRP sheet strengthened existing reinforced concrete poles with corrosion steel connectors were investigated. Four poles were selected to conduct flexural capacity test. Two poles were strengthened by single-layer longitudinal CFRP sheet, one pole was strengthened by double-layer longitudinal CFRP sheets and the last specimen was not strengthened. Results indicate that the failure is mainly bond failure between concrete and the external CFRP sheet, and the specimens fail in a brittle pattern. The cross-sectional strains of specimens approximately follow the plane section assumption in the early stage of loading, but the strain in the tensile zone no longer conforms to this assumption when the load approaches the failure load. Also, bearing capacity and stiffness of the strengthened specimens are much larger than those without CFRP sheet. The bearing capacity, initial stiffness and elastic-plastic stiffness of specimen strengthened by double-layer CFRP are larger than those strengthened by single-layer CFRP. Weighting the cost-effective effect, it is more economical and reasonable to strengthen with single-layer CFRP sheet. The results can provide a reference to the same type of poles for strengthening design.

• 한국강구조학회 논문집
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• 제10권3호통권36호
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• pp.463-472
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• 1998

본 논문의 목적은 4각형네트워크 패턴을 가지는 단층래티스돔의 좌굴특성을 실험과 이론을 통하여 검토하고, 나아가 4각형 네트워크 단층돔에 대한 신뢰할 수 있는 이론해석법을 개발하기 위한 기초연구를 하는데 그 목적이 있다. 이론해석은 야마다의 연속체치환법과 유한요소법에 의한 프레임해석법으로 한다. 원주방향에 대한 불균일한 강성과 지붕재료의 강성이 돔전체 좌굴특성에 미치는 영향을 검토한다. 이론과 실험에 의한 결과는 불균일한 강성을 가지거나 또는 강성을 갖는 지붕재료를 사용하는 다양한 종류의 단층래티스돔에 대한 일반적인 이론해석법을 개발하기 위한 기초자료로 활용될 것이다.

• 한국강구조학회 논문집
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• 제21권2호
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• pp.145-154
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• 2009

이 논문에서는 새롭게 제안된 접합부를 적용한 단층 래티스 돔의 비탄성 거동에 대해 실험적으로 분석하였다. 구조적인 성능과 시공성을 모두 만족시키기 위해서 제안된 새로운 접합부를 적용하여 강관으로 구성된 스팬 7m의 단층 래티스 돔의 축소실험모델을 제작하였으며, 각 절점에 균일한 하중이 가력되도록 하중전이장치를 이용하여 정적재하실험을 수행하였다. 최대가력하중은 1,114kN이었고, 일부 접합부의 항복 이후에 강관부재의 좌굴이 발생하였다. 강관부재의 좌굴발생 이후에는 가력장치가 허용할 수 있는 변위까지 실험을 수행하였으며, 실험을 통해서 구해진 단층 래티스 돔의 비탄성거동을 하중 단계별로 분석하였다.

• 한국결정성장학회지
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• 제12권6호
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• pp.269-269
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• 2002

희박 자성 반도체 ZnMnTe를 장벽층으로 사용한 양질의 ZnTe/ZnMnTe 단일 양자우물 구조를 열벽적층 성장법으로 성장하였다. 고분해능 X-선 회절측정 결과 ZnTe 우물층이 강하게 스트레인을 받고 있음을 알 수 있었다. 광발광 측정으로부터 무거운 양공 엑시톤 (el-hhl)과 가벼운 양공 엑시톤 (el-lhl)의 매우 뾰족한 발광 크들이 나타남을 관측하였다. 또한 우물층의 두께가 증가함에 따라 (el-hhl)과 (el-lhl)의 엑시톤 관련 피크들은 낮은 에너지 쪽으로 이동하였다. 광발광 피크 세기의 온도에 따른 변화는 운반자들의 열적 활성화로 설명할 수 있었다.