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Studies on the Fixation of Acetaldehyde by Freeze Drying (냉동건조방법에 의한 Acetaldehyde 고정에 관한 연구)

  • Lee, Young-Chun;Lee, Kyung-Hae
    • Korean Journal of Food Science and Technology
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    • v.21 no.1
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    • pp.13-16
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    • 1989
  • Attempts were made to fix acetaldehyde on base materials, which were selected from carbohydrates, by freeze drying. More acetaldehyde was fixed, in general, on combined base materials than single base materials, and mannitol+lactose were the best among the combined base materials tested. But the combination of mannitol and maltodextrin appeared to be more economical for the mass production. Loss of acetaldehyde during freeze drying was decreased as the concentration of the combined base material was increased, and it reached minimum at 40% of the base material. As dryer chamber pressure was reduced, loss of acetaldehyde during drying was decreased.

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The Annealing Effect on Magnetocaloric Properties of Fe91-xYxZr9 Alloys

  • Kim, K.S.;Min, S.G.;Zidanic, J.;Yu, S.C.
    • Journal of Magnetics
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    • v.12 no.4
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    • pp.133-136
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    • 2007
  • We have carried out the study of magnetocaloric effect for as-quenched and annealed $Fe_{91-x}Y_xZr_9$ alloys. Samples were prepared by arc melting the high-purity elemental constituents under argon gas atmosphere and by single roller melt spinning. These alloys were annealed one hour at 773 K in vacuum chamber. The magnetization behaviours of the samples were measured by vibrating sample magnetometer. The Curie temperature increases with increasing Y concentration (x=0 to 8). Temperature dependence of the entropy variation ${\Delta}S_M$ was found to appear in the vicinity of the Curie temperature. The results show that annealed $Fe_{86}Y_5Zr_9$ and $Fe_{83}Y_8Zr_9$ alloys a bigger magnetocaloric effect than that those in as-quenched alloys. The value is 1.23 J/kg K for annealed $Fe_{86}Y_5Zr_9$ alloy and 0.89 J/kg K for as-quenched alloy, respectively. In addition, the values of ${\Delta}S_M$ for $Fe_{83}Y_8Zr_9$ alloy is 0.72 J/Kg K for as-quenched and 1.09 J/Kg K for annealed alloy, respectively.

Preparation and Characterization of Blue Thin Film Phosphors by Pulsed Laser Deposition (PLD(Pulsed Laser Deposition)를 이용한 청색 박막 형광체의 제조 및 특성분석)

  • Cho, Sang-Ho;Jung, Yu-Sun;Kwak, Jung-Ho;Sohn, Kee-Sun
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.852-858
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    • 2006
  • It is well known that $BaMgAl_{10}O_{17}:Eu^{2+}$ (BAM) and $CaMgSi_2O_6:Eu^{2+}$ (CMS) are a highly efficient blue phosphor. However, these phosphors in the form of thin films have not yet been realized clue to technical difficulties. We prepared thin film type BAM and CMS phosphors on quartz glass substrate using a pulsed laser deposition technique. The luminescent and structural properties of thin film phosphors were monitored as a function of key processing parameters such as oxygen partial pressure inside the deposition chamber, deposition time, laser energy density and the type of post-deposition treatments used. Even though we could not obtain single homogenous phases, thin films with large homogenous areas and a high photoluminescence could be produced by optimizing these processing parameters.

Growth characteristics of 4H-SiC homoepitaxial layers grown by thermal CVD

  • Jang, Seong-Joo;Jeong, Moon-Taeg;Seol, Woon-Hag;Park, Ju-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.3
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    • pp.303-308
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    • 1999
  • As a semiconductor material for electronic devices operated under extreme environmental conditions, silicon carbides(SiCs) have been intensively studied because of their excellent electrical, thermal and other physical properties. The growth characteristics of single-crystalline 4H-SiC homoepitaxial layers grown by a thermal chemical vapor deposition (CVD) were investigated. Especially, the successful growth condition of 4H-SiC homoepitaxial layers using a SiC-uncoated atmospheric pressure chamber and carried out using off-oriented substrates prepared by a modified Lely method. In order to investigate the crystallinity of grown epilayers, Nomarski optical microscopy, Raman spectroscopy, photoluninescence(PL), scanning electron microscopy(SEM) and other techniques were utilized. The best quality of 4H-SiC homoepitaxial layers was observed in conditions of growth temperature $1500^{\circ}C$ and C/Si flow ratio 2.0 of $C_{3}H_{8}\;0.2\;sccm\;&\;SiH_{4}\;0.3\;sccm$. The growth rate of epilayers was about $1.0\mu\textrm{m}/h$ in the above growth condition.

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Analysis of the Negative Skin Friction Acting on a Model Pile (모형말뚝에 작용하는 부마찰력 거동 해석)

  • Lee, Song;Lee, Kyu-Hwan;Yi, Chang-Tok
    • Journal of the Korean Geotechnical Society
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    • v.15 no.2
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    • pp.81-93
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    • 1999
  • This paper investigated the negative skin friction acting on the model piles driven in the cylindrical chamber filled with remolded marine clay. In model tests, three load cells were installed on the model piles consisting of three parts to measure the negative skin friction forces independently. Pore pressures and ground movements were monitored throughout the period of investigation. Finite element analysis was used to simulate the behavior of a model pile. This paper describes the comparison of the behavior of negative skin friction on the single model pile with a numerical analysis by CRISP.

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Pulverization and Densification Behavior of YAG Powder Synthesized by PVA Polymer Solution Method

  • Im, Hyun-Ho;Lee, Sang-Jin
    • Korean Journal of Materials Research
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    • v.30 no.11
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    • pp.573-580
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    • 2020
  • YAG (Yttrium Aluminum Garnet, Y3Al5O12) has excellent plasma resistance and recently has been used as an alternative to Y2O3 as a chamber coating material in the semiconductor process. However, due to the presence of an impurity phase and difficulties in synthesis and densification, many studies on YAG are being conducted. In this study, YAG powder is synthesized by an organic-inorganic complex solution synthesis method using PVA polymer. The PVA solution is added to the sol in which the metal nitrate salts are dissolved, and the precursor is calcined into a porous and soft YAG powder. By controlling the molecular weight and the amount of PVA polymer, the effect on the particle size and particle shape of the synthesized YAG powder is evaluated. The sintering behavior of the YAG powder compact according to PVA type and grinding time is studied through an examination of its microstructure. Single phase YAG is synthesized at relatively low temperature of 1,000 ℃ and can be pulverized to sub-micron size by ball milling. In addition, sintered YAG with a relative density of about 98 % is obtained by sintering at 1,650 ℃.

Superconducting Characteristics of Bi Thin Film by Co-deposition (동시 스퍼터 법에 의한 Bi 박막의 초전도 특성)

  • 이희갑;박용필;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.278-280
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    • 2001
  • BSCCO thin films have been fabricated by co-deposition at an ultralow growth rate using ion beam sputtering(IBS) method. The growth rates of the films was set in the region from 0.17 to 0.27 nm/min. MgO(100) was used as a substrate. In order to appreciate stable existing region of Bi 2212 Phase with temperature and ozone pressure, the substrate temperature was varied between 655 and 820$^{\circ}C$ and the highly condensed ozone gas pressure(PO$_3$) in vacuum chamber was varied between 2.0x10$\^$-6/ and 2.3x10$\^$-5/ Torr. Bi 2212 Phase appeared in the temperature range of 750 and 795$^{\circ}C$ and single phase of Bi 2201 existed in the lower region than 785$^{\circ}C$. Whereas, PO$_3$ dependance on structural formation was scarcely observed regardless of the pressure variation. And high quality of c-axis oriented Bi 2212 thin film with T$\sub$c/(onset) of about 70 K and T$\sub$c/(zero) of about 45 K is obtained. Only a small amount of CuO in some films was observed as impurity, and no impurity phase such as CaCuO$_2$ was observed in all of the obtained films.

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SPRAY CHARACTERISTICS OF DME IN CONDITIONS OF COMMON RAIL INJECTION SYSTEM(II)

  • Hwang, J.S.;Ha, J.S.;No, S.Y.
    • International Journal of Automotive Technology
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    • v.4 no.3
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    • pp.119-124
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    • 2003
  • Dimethyl Ether (DME) is an excellent alternative fuel that provides lower particulate matter (PM) than diesel fuel under the same engine operating conditions. Spray characteristical of DME in common rail injection system were investigated within a constant volume chamber by using the particle motion analysis system. The injector used in this study has a single hole with the different orifice diameter of 0.2, 0.3 and 0.4 mm. The injection pressure was fixed at 35MPa and the ambient pressure was varied from 0.6 to 1.5 MPa. Spray characteristics such as spray angle, spray tip penetration and SMD (Sauter mean diameter) were measured. Spray angle was measured at 30d$_{0}$, downstream of the nozzle tip. The measured spray angie increased with increase in the ambient pressure. Increase of the ambient pressure results in a decrease of spray penetration. The experimental result, of spray penetration were compared with the predicted one by theoretical and empirical models. Increase in the ambient pressure and nozzle diameter results in an increase of SMD at a distance 30, 45 and 60d$_{0}$, downstream of the nozzle, respectively.ely.

Three-Dimensional Analysis on Induction Port and In-cylinder Flow for Various Valve Lifts in an SI Engine (SI 엔진의 밸브 리프트에 따른 흡입 포트 및 실린더내 정상 3차원 유동장 해석)

  • Kim, Y.N.;Lee, K.H.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.5
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    • pp.82-89
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    • 1995
  • The three-dimensional fluid motion through the intake port and cylinder of a single DOHC SI engine was investigated with a commercial computational fluid dynamics simulation program, STAR-CD. This domain includes the intake port, intake valves and combustion chamber. Steady induction port flows for various valve lifts have been simulated for an actual engine configuration. The geometry was obtained by direct interface with a three-dimensional CAD software for complicated port and valve shape. The computational grid was generated using the commercial preprocessor ICEM CFD/CAE. Detailed procedures were presented on the generation of the geometry and the block-structured mesh. A standard k-${\varepsilon}$ turbulent model was applied to consider the complexity of the geometry and the fluid motion. The global flow patterns and the distributions of various quantities, such as pressure, velocity magnitude around the valve seat etc., were examined. The computational results, such as mass flow rate, discharge coefficient etc., for various valve lifts were compard with the experimental results and the computational results were found in good agreement with the experiment.

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IN-CYLINDER FLOW ANALYSIS USING WAVELET ANALYSIS

  • Park, D.;Sullivan, P.E.;Wallace, J.S.
    • International Journal of Automotive Technology
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    • v.7 no.3
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    • pp.289-294
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    • 2006
  • Better fundamental understanding of the interactions between the in-cylinder flows and combustion process is an important requirement for further improvement in the fuel economy and emissions of internal combustion(IC) engines. Flow near a spark plug at the time of ignition plays an important role for early flame kernel development(EFKD). Velocity data measurements in this study were made with a two-component laser Doppler velocimetry(LDV) near a spark plug in a single cylinder optical spark ignition(SI) engine with a heart-shaped combustion chamber. LDV velocity data were collected on an individual cycle basis under wide-open motored conditions with an engine speed of 1,000rpm. This study examines and compares the flow fields as interpreted through ensemble, cyclic and discrete wavelet transformation(DWT) analysis. The energy distributions in the non-stationary engine flows are also investigated over crank angle phase and frequency through continuous wavelet transformation(CWT) for a position near a spark plug. Wavelet analysis is appropriate for analyzing the flow fields in engines because it gives information about the transient events in a time and frequency plane. The results of CWT analysis are provided and compared with the mean flows of DWT first decomposition level for all cycles at a position. Low frequency high energy found with CWT corresponds well with the peak locations of the mean velocity. The high frequency flows caused by the intake jet gradually decay as the piston approaches the bottom dead center(BDC).