• Title/Summary/Keyword: Simultaneous Reduction

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A Facile Electrochemical Fabrication of Reduced Graphene Oxide-Modified Glassy Carbon Electrode for Simultaneous Detection of Dopamine, Ascorbic Acid, and Uric Acid

  • Yu, Joonhee;Kim, Tae Hyun
    • Journal of Electrochemical Science and Technology
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    • v.8 no.4
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    • pp.274-281
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    • 2017
  • This paper describes the simple fabrication of an electrode modified with electrochemically reduced graphene oxide (ERGO) for the simultaneous electrocatalytic detection of dopamine (DA), ascorbic acid (AA), and uric acid (UA). ERGO was formed on a glassy carbon (GC) electrode by the reduction of graphene oxide (GO) using linear sweep voltammetry. The ERGO/GC electrode was formed by subjecting a GO solution ($1mg\;mL^{-1}$ in 0.25 M NaCl) to a linear scan from 0 V to -1.4 V at a scan rate of $20mVs^{-1}$. The ERGO/GC electrode was characterized by Raman spectroscopy, Fourier transform infrared spectroscopy, contact angle measurements, electrochemical impedance spectroscopy, and cyclic voltammetry. The electrochemical performance of the ERGO/GC electrode with respect to the detection of DA, AA, and UA in 0.1 M PBS (pH 7.4) was investigated by differential pulse voltammetry (DPV) and amperometry. The ERGO/GC electrode exhibited three well-separated voltammetric peaks and increased oxidation currents during the DPV measurements, thus allowing for the simultaneous and individual detection of DA, AA, and UA. The detection limits for DA, AA, and UA were found to be 0.46, 77, and $0.31{\mu}M$ respectively, using the amperometric i-t curve technique, with the S/N ratio being 3.

ZanF를 이용한 카드뮴(Cd)과 6가 크롬(Cr(VI))의 동시제거

  • 이승학;이광헌;명동일;박준범
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.143-146
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    • 2004
  • Natural zeolites have exhibited high sorption capacity for inorganic cations including heavy metals and ammonium. Moreover, they were proven to be effective for environmental applications such as permeable barriers for controlling the spread of cation-contaminated groundwater. However zeolites have little or no affinity for anionic species like chromium, as they possess a net negative structural charge. To achieve the simultaneous sorption for anionic contaminants, surfactant-modified zeolite (SMZ) has been employed as the possible sorbents. Current study focuses on simultaneous removal of heavy metals having different ionic form in aqueous solution, cadmium (C $d^{2+}$) and chromium (Cr $O_{4}$$^{2-}$), using newly developed materials, ZanF. ZanF, a potential alternative to SMZ, was derived from zeolite modified by Fe(II) chloride followed by reduction with sodium borohydride. Batch experiments were performed to estimate the removal efficiency of ZanF at different conditions. Under different pH ranging from 2 to 6, removal efficiency was investigated. And C $d^{2+}$ removal efficiency was estimated by varying background concentration of Cr $O_{4}$$^{2-}$, and vice versa. With the test results, ZanF was expected to be a possible reactive materials alternative to SMZ in permeable reactive barriers (PRBs) for treating the contaminated groundwater with cationic and anionic heavy metals.als.

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Simultaneous precision positioning and vibration suppression of reciprocating flexible manipulators

  • Ma, Kougen;Ghasemi-Nejhad, Mehrdad N.
    • Smart Structures and Systems
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    • v.1 no.1
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    • pp.13-27
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    • 2005
  • Simultaneous precision positioning and vibration suppression of a reciprocating flexible manipulator is investigated in this paper. The flexible manipulator is driven by a multifunctional active strut with fuzzy logic controllers. The multifunctional active strut is a combination of a motor assembly and a piezoelectric stack actuator to simultaneously provide precision positioning and wide frequency bandwidth vibration suppression capabilities. First, the multifunctional active strut and the flexible manipulator are introduced, and their dynamic models are derived. A control strategy is then proposed, which includes a position controller and a vibration controller to achieve simultaneous precision positioning and vibration suppression of the flexible manipulator. Next, fuzzy logic control approach is presented to design a fuzzy logic position controller and a fuzzy logic vibration controller. Finally, experiments are conducted for the fuzzy logic controllers and the experimental results are compared with those from a PID control scheme consisting of a PID position controller and a PID vibration control. The comparison indicates that the fuzzy logic controller can easily handle the non-linearity in the strut and provide higher position accuracy and better vibration reduction with less control power consumption.

Experimental Study on the Performance Improvement of a Simultaneous Heating and Cooling Heat Pump in the Cooling-main Operating Mode (냉방주체 운전모드에서 동시냉난방 열펌프 성능향상에 관한 실험적 연구)

  • Chung, Hyun-Joon;Joo, Young-Ju;Kang, Hoon;Kim, Yong-Chan;Choi, Jong-Min
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.5
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    • pp.314-320
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    • 2008
  • The cooling load in winter is significant in buildings and hotels because of the usage of office equipments and the improved wall insulation. Hence, a multi~heat pump is required to cover heating and cooling simultaneously for each indoor unit. In this study, the operating characteristics and performance of a simultaneous heating and cooling heat pump in the cooling-main operating mode were investigated experimentally. The system adopted a variable speed compressor using R410A with four indoor units and one outdoor unit. In the cooling-main mode, the heating capacity decreased due to reduction of flow rate to the indoor unit under heating mode operation. The EEV opening was adjusted to increase flow rate to the indoor unit under heating mode operation. The total capacity and COP in the cooling-main mode increased by 20.5% and 29.2%, respectively, compared with those in the cooling-only mode.

Reduction of Nitrotoluenes and Simultaneous Removal of Hydrogen Sulfide and Nitrotoluenes by Co3+-centered Hematoporphyrin (포피린의 촉매작용에 의한 니트로톨루엔의 환원 및 니트로톨루엔과 황화수소의 동시 제거)

  • Cho, Jeong-Guk;Kang, An-Soo
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.37-43
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    • 1994
  • Mononitrotoluenes were reduced to aminotoluenes using porphyrin as a catalyst in the presence of several types of reductants including hydrogen sulfide and 1, 4-dithiothreitol(DTT). Intermediates and final products of porphyrin-catalyzed reduction of mononitrotoluenes were identified and a pathway for the reduction of the nitro group to the corresponding amino group was proposed. The optimum pH for the reduction was determined. The catalytic activity of the porphyrin was confirmed by UV/VIS absorption spectra and basic kinetics of porphyrin-catalyzed reduction were studied. Of several types of reductants tested, DTT sodium hydrosulfite, and hydrogen sulfide were seen to give significant reduction of nitrobodies. When hydrogen sulfide was used as a reductant hydrogen sulfide and nitrotoluenes were removed simultaneously.

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Reduction of Gaseous Acetone by using TiO2 Coated Woven Filters (TiO2 담지 세라믹 필터를 활용한 아세톤 제어에 관한 연구)

  • 윤정호;박덕신;이주열;조영민
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.1
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    • pp.85-92
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    • 2003
  • A new type of catalytic filers has been developed in this work. A porous photocatalytic filter was prepared by coating the titania (anatase phase) powder onto the woven metal mesh. The coating sol was prepared with unique cera-mic binder, and would assist drying condition and enhance the mechanical strength of the final ceramic filers. As a result of the test for acetone decomposition, it was found to be quite effective for the photocatalytic reaction as good at conventional glass reactors which were coated inside. The present filter type reactor is expected as one of plausible devices for the simultaneous treatment of gas - particulate materials.

Method of SSO Noise Reduction on FPGA of Digital Optical Units in Optical Communication

  • Kim, Jae Wan;Eom, Doo Seop
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.1
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    • pp.97-101
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    • 2013
  • There is a growing need for optical communication systems that convert large volumes of data to optical signals and that accommodate and transmit the signals across long distances. Digital optical communication consists of a master unit (MU) and a slave unit (SU). The MU transmits data to SU using digital optical signals. However, digital optical units that are commercially available or are under development transmit data using two's complement representation. At low input levels, a large number of SSOs (simultaneous switching outputs) are required because of the high rate of bit switching in two's complement, which thereby increases the power noise. This problem reduces the overall system capability because a DSP (digital signal processor) chip (FPGA, CPLD, etc.) cannot be used efficiently and power noise increases. This paper proposes a change from two's complement to a more efficient method that produces less SSO noise and can be applied to existing digital optical units.

A Novel OLED Inspection Process Method with Simultaneous Measurement for Standard and Deposition Pattern (기준패턴과 증착패턴의 동시 측정을 통한 OLED 공정 검사 방법)

  • Kwak, Byeongho;Cheoi, Kyungjoo
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.15 no.4
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    • pp.63-70
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    • 2019
  • The subject of the simultaneous measuring system of base pattern and deposition pattern is a new research topic on a defect inspection of OLED. In this paper, we propose a new OLED inspection method that simultaneously measures standard and deposition pattern images. This method reduces unnecessary processes and tac time during OLED inspection. For an additional reduction of the tac time during pattern measurement, the ROI was configured to measure only in the designated ROI area instead of measuring the entire area of an image. During the ROI set-up, the value of effective deposition pattern area is included so that if the deposition pattern is out of the ROI zone, it would be treated as a defect before measuring the size and center point of the pattern. As a result, the tac time and inspection process could be shortened. The proposed method also could be applied to the OLED manufacturing process. Production of OLED could be increased by reducing tac time and inspection process.

Gate Freezing, Gate Sizing, and Buffer Insertion for reducing Glitch Power Dissipation (단일화된 게이트 프리징, 사이징 및 버퍼삽입에 의한 저 전력 최적화 알고리즘)

  • Lee, Hyung-Woo;Shin, Hak-Gun;Kim, Ju-Ho
    • Proceedings of the IEEK Conference
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    • 2004.06b
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    • pp.455-458
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    • 2004
  • We present an efficient heuristic algorithm to reduce glitch power dissipation in combinational circuits. In this paper, the total number of glitches are reduced by replacing existing gates with functionally equivalent ones and by gate sizing which classified into three types and by buffer insertion which classified into two types. The proposed algorithm combines gate freezing, gate sizing. and buffer insertion into a single optimization process to maximize the glitch reduction. Our experimental results show an average of $67.8\%$ glitch reduction and $32.0\%$ power reduction by simultaneous gate freezing, gate sizing, and buffer insertion.

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Synthesis of FePt Nanoparticles by Chemical Reduction Process (화학적인 환원 공정에 의한 FePt 나노입자의 합성)

  • 김순길;이창우;이재성
    • Journal of Powder Materials
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    • v.11 no.3
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    • pp.242-246
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    • 2004
  • FePt nanoparticles for high-density magnetic recording media were synthesized by the simultaneous chemical reduction of Fe(acac) $_2$ and Pt(acac) $_2$ with 1,2-hexadecanediol as the reducing reagent. TEM images showed that the shape of as-synthesized FePt nanoparticle was spherical and average particle size was 3 nm. Also, SAD pattern showed that crystal structure was disordered FCC (face centered cubic). These FCC structured nanoparticles were transformed FCT (face centered tetragonal) structure by annealing at 55$0^{\circ}C$ for 30 min in Ar atmosphere. XRD analysis revealed that as-synthesized FePt nanoparticles were transformed from disordered FCC to ordered FCT. Finally, the coercivity of 2 kOe for FePt nanoparticles with FCT structure was obtained by VSM measurement.