• Title/Summary/Keyword: Silver oxide

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Effect of annealing atmosphere on the properties of chemically deposited Ag2S thin films

  • Pawar, S.M.;Shin, S.W.;Lokhande, C.D.;Kim, J.H.
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.34.2-34.2
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    • 2009
  • The silver sulphide (Ag2S) thin films have been chemically deposited from an alkaline medium (pH 8 to 10) by using a silver nitrate and thiourea as a Ag and S ion precursor sources. Ethylene Damine tetraacetic acid (EDTA) was used as a complexing agent. The effect of annealing atmosphere such as Ar, N2+H2S and O2 on the structural, morphological and optical properties of Ag2S thin films has been studied. The annealed films were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical absorption techniques for the structural, morphological, and optical properties, respectively. XRD studies reveal that the as-deposited thin films are polycrystalline with monoclinic crystal structure, is converted in to silver oxide after air annealing. The surface morphology study shows that grains are uniformly distributed over the entire surface of the substrate. Optical absorption study shows the as-deposited Ag2S thin films with band gap energy of 0.92eV and after air annealing it is found to be 2.25 eV corresponding to silver oxide thin films.

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Temperature Dependance of Propagation Velocity in a Silver Sheathed Bi-family Superconducting Oxid Tape (Bi계 은시스산화물초전도테프의 쿠엔치전파특성의 온도의존성)

  • Kim, Seok-Beom;Aoki, Keisuke;Ishiyama, Atsushi
    • Proceedings of the KIEE Conference
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    • 1994.07a
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    • pp.76-78
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    • 1994
  • Owing to the discover of oxide superconducting over critical temperature100K, it is being made experimentally somewhere under the possibility that there is superconducting magnet by cooling liquid nitrogen. The issues of thermal stability and quench process of Low-Tc superconductor has been studied and used application of oxide superconducting magnets. However the quench propagation property of oxide superconductor, especially experimental data about thermal behavior has not been reported yet. Therefore we measured the effect of temperature dependance of quench propagation velocity, Vq, by using the short samples made up of silver sheathed Bismuth-family (2223phase) superconducting oxide tape.

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Screen-printed Source and Drain Electrodes for Inkjet-processed Zinc-tin-oxide Thin-film Transistor

  • Kwack, Young-Jin;Choi, Woon-Seop
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.6
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    • pp.271-274
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    • 2011
  • Screen-printed source and drain electrodes were used for a spin-coated and inkjet-processed zinc-tin oxide (ZTO) TFTs for the first time. Source and drain were silver nanoparticles. Channel length was patterned using screen printing technology. Different silver nanoinks and process parameters were tested to find optimal source and drain contacts Relatively good electrical properties of a screen-printed inkjet-processed oxide TFT were obtained as follows; a mobility of 1.20 $cm^2$/Vs, an on-off current ratio of $10^6$, a Vth of 5.4 V and a subthreshold swing of 1.5 V/dec.

Fabrication of $TiO_2$-silver transparent thin films low-e coated on glass substrate by ink-jet printing (잉크젯 프린팅을 이용한 low-e $TiO_2$-silver 투명박막형성)

  • Yoon, Cho-Rong;Oh, Hyo-Jin;Lee, Nam-Hee;Guo, Yupeng;Kim, Byung-Whan;Kim, Sun-Jae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.511-511
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    • 2007
  • Low-emissivity (low-e) coatings with visible transparency have attracted increased interest m reducing heat radiation loss through window panes from ecological and sustainable aspects. $TiO_2$-silver transparent thin films for low-e have good properties for UV and IR blocking as well as photocatalyst compared to that with commercial UV blocking films such as fluorine doped oxide (FTO), antimony doped tin oxide (ATO), etc. In this study, transparent $TiO_2$-silver thin films were prepared by successive ink-jet printing of commercial nano silver and $TiO_2$ sol. The $TiO_2$ sol, as ink for ink-jet printing, were synthesized by hydrothermal process in the autoclave externally pressurized with $N_2$ gas of 200 bar at $120^{\circ}C$ for 10 hrs. The synthesized $TiO_2$ sols were all formed with brookite phase and their particle size was several to 30 nm. At first nano sized silver sol was coated on glass substrate, after that $TiO_2$ sol was coated by ink-jet printing. With increasing coating thickness of $TiO_2$-silver multilayer by repeated ink-jet coating, the absorbance of UV region (under 400nm) and IR region (over 700nm) also increase reasonably, compared to that with commercial UV blocking films.

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Enhancement of Electrical Conductivity in Silver Nanowire Network for Transparent Conducting Electrode using Copper Electrodeposition (구리 전기도금 방법을 이용한 은 나노와이어 투명전극의 전기전도도 향상)

  • Ji, Hanna;Jang, Jiseong;Lee, Sangyeob;Chung, Choong-Heui
    • Korean Journal of Materials Research
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    • v.29 no.5
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    • pp.311-316
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    • 2019
  • Transparent conducting electrodes are essential components in various optoelectrical devices. Although indium tin oxide thin films have been widely used for transparent conducting electrodes, silver nanowire network is a promising alternative to indium tin oxide thin films owing to its lower processing cost and greater suitability for flexible device application. In order to widen the application of silver nanowire network, the electrical conductance has to be improved while maintaining high optical transparency. In this study, we report the enhancement of the electrical conductance of silver nanowire network transparent electrodes by copper electrodeposition on the silver nanowire networks. The electrodeposited copper lowered the sheet resistance of the silver nanowire networks from $21.9{\Omega}{\square}$ to $12.6{\Omega}{\square}$. We perform detailed X-ray diffraction analysis revealing the effect of the amount of electrodeposited copper-shell on the sheet resistance of the core-shell(silver/copper) nanowire network transparent electrodes. From the relationship between the cross-sectional area of the copper-shell and the sheet resistance of the transparent electrodes, we deduce the electrical resistivity of electrodeposited copper to be approximately 4.5 times that of copper bulk.

Synthesis and Crystal Structure of Asymmetric Dimer of 1,2-Benzothiazine Derivatives Using Silver Oxide (Silver Oxide를 이용한 1,2-벤조티아진 유도체의 비대칭 중합체 합성 및 결정 구조)

  • Park, Myung Suk
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.657-663
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    • 1998
  • New asymmetric dimer, 7,7'-substituted (or H)-4-oxo-2,2'- dialkyl-l,l',2,2'-dibenzothiazine-3,3'dicarboxylic acid methyl ester-1,1,1',1'-tetraoxide 3,4'-yl ethers 2a-d were synthesized through the oxidative dimerization of 7-substituted (or H)-4-hydroxy-2-alkyl-1,2-benzothiazine-3-carboxylic acid methyl ester 1,1-dioxides la-d using silver oxide($Ag_2O$). 4-Oxo-2,2'-dialkyl-1,1'2,2'-dibenzothiazine-3,3'-dicarboxylic acid methyl ester-1,1,1',l'-tetraoxide 3,4'-yl ether 2c was identified by X-ray crystal structure determination.

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A Study on the Leaching of Valuable Metals from Spent Silver-Oxide Battery (폐산화은 전지로부터 유가금속의 침출에 관한 연구)

  • 박경호;손정수
    • Resources Recycling
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    • v.4 no.1
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    • pp.46-51
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    • 1995
  • After removal of mercury in the silver oxide batteries with the distillation process, the leaching of valuable metals from the residue was studied. The distilled residue was reacted with the various HNO, concentration, reactlon temperature, readion time and pulp density. It was found that the optimum condition for leachmg was 2N HNO,, 40-60% reaction temperature, 6 hours reaction tlme and 10g/200ml pulp density. More than 99% of silver and zinc were dissolved in this process while less than 50% of iron and nickel were leached

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Easy Preparation of Nanosilver-Decorated Graphene Using Silver Carbamate by Microwave Irradiation and Their Properties

  • Yun, Sang-Woo;Cha, Jae-Ryung;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2251-2256
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    • 2014
  • We have successfully decorated reduced graphene oxide (RGO) with silver nanoparticles (AgNPs) by microwaving silver alkylcarbamate for 13 seconds using 1-amino-4-methylpiperazine. Uniform AgNPs (20-40 nm) were effectively prepared, and 1-amino-4-methylpiperazine acted as a reaction medium, reducing agent, and stabilizer. Particle size and morphology were correlated with the silver alkylcarbamate concentration and microwave time. The graphene/AgNPs composites were characterized by Raman, X-ray diffraction, and scanning electron microscopy to confirm that the AgNPs were uniformly decorated onto the graphene. Measurements of the transparent conductive property at room temperature indicated that these graphene/AgNPs nanosheets with 55.45% transmittance were electrically continuous with a sheet resistance of approximately $43{\Omega}/{\Box}$.

Joule Heating of Metallic Nanowire Random Network for Transparent Heater Applications

  • Pichitpajongkit, Aekachan;Eom, Hyeonjin;Park, Inkyu
    • Journal of Sensor Science and Technology
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    • v.29 no.4
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    • pp.227-231
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    • 2020
  • Silver nanowire random networks are promising candidates for replacing indium tin oxide (ITO) as transparent and conductive electrodes. They can also be used as transparent heating films with self-cleaning and defogging properties. By virtue of the Joule heating effect, silver nanowire random networks can be heated when voltage bias is applied; however, they are unsuitable for long-term use. In this work, we study the Joule heating of silver nanowire random networks embedded in polymers. Silver nanowire random networks embedded in polymers exhibit breakdown under the application of electric current. Their surface morphological changes indicate that nanoparticle formation may be the main cause of this electrical breakdown. Numerical analyses are used to investigate the temperatures of the silver nanowire and substrate.

A Study on the Thermal Aging and SOx Poisoning Characteristics on Alumina Supported Silver Catalyst under Diesel Engine Emission Condition (디젤엔진 배기가스조건하에서의 Pt 및 Ag 담지 알루미나 촉매의 열적 노화 특성과 SOx 피독 특성에 관한 연구)

  • 신병선
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.2
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    • pp.199-208
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    • 2000
  • In this study we investigated on the possibility of platinum and silver catalysts as de-NOx catalyst for activity test of supported metal oxide catalysts. the study was performed with the change of amount of metal and support types. The catalyst was prepared the activity of alumina supported silver catalyst produced by dry and wet impregnation method respectively and the resistance of sulfur for optimum supported silver catalyst,. As a result the activity of alumina supported platinum catalyst was showed at low temperature region but the case of silver catalyst activated at high temperature region. So we finally chose alumina supported silver catalyst as de-NOx target catalyst because alumina supported catalyst showed higher activity than alumina supported platinum catalyst.

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