• Title/Summary/Keyword: Silicone gel

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Effect of Introducing EG on Foamed Cellular Structure and Properties in the Foaming Process of Rigid PU (경질 PU발포공정에 있어서 EG의 첨가가 발포체의 구조와 물성에 미치는 영향)

  • Baek, Woon-Seon;Lee, Kee-Yoon
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.528-535
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    • 2001
  • Polyurethane specimens were mainly composed of polyol, MDI, silicone surfactant, and water. The effects of ethylene glycol on the cell size, forming magnification, cream time, gel time, take free time, final free rising height, and reactive temperature were investigated. The cyclopentane was used for PU foam as a physical blowing agent. The components were hand-mixed at about 5000 rpm within 4 seconds at room temperature. The mixtures with various ethylene glycol contents were foamed in the wood mold. When the index of isocyanate was fixed, as the amount of ethylene glycol increased, cell size and thermal conductivity were decreased by about 5.1% and 14%, respectively.

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Response of a prototype brain material subjected to rotational acceleration (회전가속에 대한 프로토타입 뇌재료의 반응)

  • Lee, E. S.
    • Journal of the korean Society of Automotive Engineers
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    • v.11 no.5
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    • pp.76-89
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    • 1989
  • With the objective of studying the response of brain tissue in a transient rotational acceleration of the head, as occurs in car crash, the problem of a cylindrical case containing a prototype brain material of silicone gel and subjected to a rotational acceleration around the axis of the cylinder is analysed. The prototype material is considered to be homogeneous and isotropic, and is modeled alternatively as a linear elastic or a linear viscoelastic solid. The computational model for the present problem consists of a 3-dimensional isoparametric finite element model, wherein large deformations and large strains are treated through the updated Lagrangian approach. A comparison of the results of the present 3-dimensional computations, with the attendant assumptions on material data, is made with the results of independent experimental study. The deformation profiles and the major characteristics of response of the brain material are in good agreement with the test results. Moreover, the study suggests the possibility that the use of more accurate material data may yield very useful results even appropriate for accurate quantification of deformations.

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On the Pyrolysis of Polymers II. Identification of the Products from Polymer Pyrolysis by Gas Chromatography (高分子物質의 熱分解에 關한 硏究 (第2報) Gas Chromatography 에 依한 熱分解生成物의 檢索)

  • Chwa-Kyung Sung
    • Journal of the Korean Chemical Society
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    • v.7 no.2
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    • pp.106-114
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    • 1963
  • The products from polymer pyrolysis at $450^{\circ}$ are cooled with ice, then liquid and gaseous portions are analysed by gas chromatography. Di-2-ethyl hexyl sebacate column, silicone oil column, silica gel column and tetraethyleneglycol dimethylether column, which was most effective for the separation of hydrocarbon gases, are used. Identification of isomers could be secured more effectively by gas chromatography than mass spectrometry. Elucidation of the mechanism for thermal decomposition of polymers could be done through the identification of pyrolysis products. Although more extensive work is needed, some patterns of polymer pyrolysis are discussed.

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Nanoemulsions and Nanoparticles Employed as Delivery Vehicles for Topical Active Ingredients to Enhance Stability and Efficacy

  • Arthur Georgalas
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.307-307
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    • 2003
  • Strategies to make finished products more stable and efficacious can take advantage of formulation technologies- ingredients and techniques - to improve their delivery into the skin by both enhanced penetration and delayed release. Nanometer range particles and emulsion droplets can be formed with a selection of either silicone copolyol or conventional organic surfactants and dispersion shear rates sufficient to generate stable submicron droplets. By incorporating these into systems with biomimetic liquid crystalline gel networks in either simple or multiple phase emulsions the skin delivery can be enhanced as shown in tape stripping experiments. Such systems can stabilize labile actives, such as Vitamin C and retinol, and aid delivery. Laboratories in U.S and Europe investigated actives including green tea polyphenols, salicylic acid and methyl and benzyl nicotinate.

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Water Resistance and Thermal Properties of Resin Based on Silane-modified Vinyl Acetate-Acrylic Emulsion Copolymers (실리콘 수식 비닐아세테이트-아크릴 공중합체 수지의 방수성 및 열적 성질)

  • Naghash, Hamid Javaherian
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.306-312
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    • 2010
  • Triphenylvinylsilane (TPVS) containing vinyl acetate (VAc), butyl acrylate (BA), and Nmethylolacrylamide (NMA) copolymers were prepared by emulsion polymerization. The polymerization was performed at $80^{\circ}C$ in the presence of auxiliary agents and ammonium peroxodisulfate (APS) as the initiator. Sodium dodecyl sulphate (SDS) and Arkupal N-300 were used as anionic and nonionic emulsifiers, respectively. The resulting copolymers were characterized by using Fourier transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC), and dynamic light scattering (DLS). Thermal properties of the copolymers were studied by using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The morphology of copolymers was also investigated by scanning electron microscopy (SEM) and then the effects of silicone concentrations on the properties of the TPVS-containing VAc-acrylic emulsion copolymers were discussed. The obtained copolymers have high solid content (50%) and can be used in weather resistant emulsion paints as a binder.

Management of keloid scars: noninvasive and invasive treatments

  • Kim, Sang Wha
    • Archives of Plastic Surgery
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    • v.48 no.2
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    • pp.149-157
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    • 2021
  • Scars vary from mature linear scars to abnormal excessive scars such as hypertrophic scars and keloid scars. Keloid scars are fibro-proliferative disease entities that reflect an abnormal process of wound healing. They can cause pain, itching, stiffness, and psychological distress, all of which can affect quality of life. Various treatment options have been advocated as ways to prevent and treat keloid scars. These include noninvasive treatments such as use of silicone gel sheeting and compression therapy, and invasive treatments such as intralesional corticosteroid injections, surgery, and radiotherapy. Novel treatments include chemotherapy, immunotherapy, and anti-inflammatory therapies. Unfortunately, keloids continue to pose a significant challenge due to the lack of efficacious treatments. Therefore, clinicians should be familiar with various therapeutic options and apply the most suitable treatment plan for patients. In this review, we introduce the current therapeutic options for the management of keloid scars.

Improvement of existing drainage system for leakage treatment in exiting underground structures (운영중인 지하구조물의 누수처리를 위한 유도배수공법의 개선)

  • Kim, Dong-Gyou;Yim, Min-Jin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.4
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    • pp.669-683
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    • 2017
  • The objective of this study is to propose a modification of the previously proposed drainage system for catching the partial leakage of underground concrete structures. Two techniques were proposed for applying the drainage system only to the leaking parts. One was for conveying leaking groundwater to the collection point in the drainage system and the other was for conveying the collected groundwater to the primary drainage system of the underground concrete structure. Four waterproofing materials for conveying leaking groundwater to the catchment point of the drainage system, Durkflex made of porous rubber material, KE-45 silicone adhesive with super strong adhesion, Hotty-gel made of polymeric materials and general silicone adhesive were evaluated for waterproofing performance. Hotty-gel only showed perfect waterproof performance and the other three waterproof materials leaked. The modified drainage system with Hotty-gel and drainage pipe with fixed saddle to convey the leaking groundwater from the catchment point to the primary drainage system were tested on the concrete retaining wall. The waterproof performance and the drainage performance were evaluated by injecting 1,000 ml of water in the back of the modified drainage system at the 7-day, 14-day, 21-day, 28-day, 2-month and 3-month. There was no problem in waterproof performance and drainage performance of the modified drainage system during 3 months. In order to evaluate the construction period and construction cost of the modified drainage system, it was compared with the existing leaching repair method in surface cleaning stage, leakage treatment stage, and protective barrier stage. Total construction period and construction cost were compared in considering the contents of work, repair material, construction equipment, working time, and total number of workers. As a result of comparing and analyzing in each construction stage, it was concluded that the modified drainage system could save construction period and construction cost compared to the existing leaching repair method.

UV-cured Pressure Sensitive Adhesive for Protective Film Application (보호필름용 자외선경화형 점착제)

  • Jamaluddin, Jamarosliza;Lee, Myung Cheon
    • Journal of Adhesion and Interface
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    • v.18 no.3
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    • pp.134-140
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    • 2017
  • In this study, we made UV cured acrylic pressure sensitive adhesive containing silicone-urethane-acrylate (SUA) oligomer for a coating on protective film and investigated the effect of SUA oligomer content and UV-dose on adhesion properties. The results illustrated that peel strength decreases with increasing oligomer content and UV-dose, while holding power increases. The gel fractions sharply increased after UV irradiation and then remain constant with prolonged UV exposure. From peel-off test, sample S70 (70% oligomer content) shows the best peelability and removability without remaining any mark or adhesive material on the test substrate than S50 (50% oligomer content) and S60 (60% oligomer content). Sample S70 also showed a surface energy lower than $26mJ/m^2$ and a transmittance higher than 95% at UV-dose 1857 and $2270mJ/cm^2$ which met the required properties for protective film application.

Viscoelastic properties of electrorheological fluids (전기유변유체의 점탄성 특성에 관한연구)

  • Choe, Yun-Dae;Kim, Sang-Guk
    • Korean Journal of Materials Research
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    • v.2 no.3
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    • pp.220-227
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    • 1992
  • Electrorheological(ER) fluid's storage shear modulus(G') and loss factor(${\eta}$) have been directly measured using small amplitude forced oscillating rheometer as a function of oscillating frequency, strain amplitude and applied electric field. Two types of experiment were performed , (a) frequency sweep and (b) amplitude sweep. Two kinds of sample were employed for this experiment ; cornstarch particles in corn oil and zeolite particles in silicone oil. The storage shear modulus was a strong function of driving frequency. Generally, the modulus increased with driving frequency. On the other hand, the loss factor was not well behaved as storage modulus, but as the driving frequency increases the loss factor slightly decreases was the trend of the material's characteristics. Also the modulus was a strong function of strain amplitude. Generally, modulus decreased with increasing strain, but loss factor increases slightly with increasing strain amplitude. For G', cornstarch in corn oil ER fluid has higher values than zeolite based fluid as we increased applied electric field. On the other hand, zeolite based fluid has higher values for ${\eta}$. There is a reasonable agreement between theoretical calculation and experiment.

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Spherical UO2 Kernel and TRISO Coated Particle Fabrication by GSP Method and CVD Technique (겔침전과 화학증착법에 의한 구형 UO2 입자와 TRISO 피복입자 제조)

  • Jeong, Kyung-Chai;Kim, Yeon-Ku;Oh, Seung-Chul;Cho, Moon-Sung
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.590-597
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    • 2010
  • HTGR using a TRISO coated particles as nuclear raw fuel material can be used to produce clean hydrogen gas and process heat for a next-generation energy source. For these purposes, a TRISO coated particle was prepared with 3 pyro-carbon (buffer, IPyC, and OPyC) layers and 1 silicone carbide (SiC) layer using a CVD technique on a spherical $UO_2$ kernel surface as a fissile material. In this study, a spherical $UO_2$ particle was prepared using a modified sol-gel method with a vibrating nozzle system, and TRISO coating fabrication was carried out using a fluidized bed reactor with coating gases, such as acetylene, propylene, and methyltrichlorosilane (MTS). As the results of this study, a spherical $UO_2$ kernel with a sphericity of 1+0.06 was obtained, and the main process parameters in the $UO_2$ kernel preparation were the well-formed nature of the spherical ADU liquid droplets and the suitable temperature control in the thermal treatment of intermediate compounds in the ADU, $UO_3$, and $UO_2$ conversions. Also, the important parameters for the TRISO coating procedure were the coating temperature and feed rate of the feeding gas in the PyC layer coating, the coating temperature, and the volume fraction of the reactant and inert gases in the SiC deposition.