• Title/Summary/Keyword: Silicone composite

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Shape Control of Silica-Polymethylsilsesquioxane (PMSQ) Composites by Varying Ratios of Precursors (전구체 비율에 따른 실리카-폴리메틸실세스퀴옥세인(PMSQ) 복합분체의 형태 제어)

  • Choi, Yigun;Choi, Jongmin;Kim, Hyojoong
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.45 no.4
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    • pp.409-414
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    • 2019
  • Silica and polymethylsilsesquioxane (PMSQ) are silicone powders widely used as cosmetics. We synthesized silica-PMSQ composites via sol-gel method using tetraethoxysilane (TEOS) and methyltrimethoxysilane (MTMS) as precursors of silica and PMSQ, respectively. Shape of the composites was controlled by varying the ratios of TEOS and MTMS, which were used as silane monomers. Silica-PMSQ composites showed three different shapes, which were sphere-shape, raspberry- shape, and donut- shape. All of them had soft touch, easy water dispersion, and soft focus effect in common. However, each shape showed some differences in sense of use, adhesion, and strength of the soft focus effect. Raspberry-shape composite had the strongest soft focus effect, donut-shape one had the strongest adhesion, and sphere-shape one had the best in softness. Thus, it is concluded that by varying the ratios of TEOS and MTMS silica-PMSQ composites could be easily synthesized into different shapes, providing various functions. This method can be applied to manufacture functional cosmetics.

A Studies on Aging Properties for Transmission Line Polymer Insulators which are Installed in service (실계통에 포설된 송전용 고분자 애자의 AGING 특성 연구)

  • Kim, So-Yeon;Lee, Sang-Jin;Ha, Young-Kil;Kim, Dong-Wook
    • Proceedings of the KIEE Conference
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    • 2001.11a
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    • pp.152-154
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    • 2001
  • Recently the extensive use of composite insulators for transmission lines can ultimately be justified only on long-term qualification tests. Especially, it is possible for the Polymer insulator to be aged in according to the environment in which it is used this may bring about the decrease of the duration of voltage application. So, this paper deals with aging property of the polymer insulator installed at real transmission line in the industry area. The contact angle, arc test, tracking test were measured for acquiring the degradation characteristics of silicone rubber and the SEM, XRF, FT-IR tests were measured for analyzing the crack and components. Also the surface leakage current of the polymer insulator was compared with that of the porcelain insulator. Finally, we knew that the aging property was not appeared during seven months at real transmission line in the industry area.

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The concept of hybride phenomean is to selected to describe the fashiontrend of ‘98-00’. (‘98-00’ Fashion Trend에 나타난 Hybrid 현상에 관한 고찰)

  • 정미혜
    • Journal of the Korea Fashion and Costume Design Association
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    • v.1 no.1
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    • pp.5-16
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    • 1999
  • The purpose of this study is to identify the distinctive characterics HYBRID, strictly defined, an offspring that is a cross between different species, genera, or, in rare cases, families, More loosely defined, a hybrid can also be a cross between parents of different subspecies or varieties of a species. Hybrid varieties of plants and animals are of economic value because the hybrid is nearly always more vigorous, larger, and more fertile than either of its parents. Plant and animal hybrids may arise spontaneously in nature or may be produced intentionally by man. Forward-looking fashion explores progress. Adjusting to a world that has integrated genetics and its mutations, the new silhouette seems without references, as if born from a spontaneous generation. A slightly bizarre composite, asymmetrical, discreetly technological aesthetic, it draws on the latest technological details. the pursuit of performance and ergonomics, yet also of comfort and amusement that takes into account the body and its articulations, generates strange garments. Inspired by medical protheses. Focos on fabric touches, their weightiness and surface effects obtained with silicone, rubber or wax. in a range that highlights yellows but can also contrast with colder, slightly surgical hues, the hybrid woman doesn't necessarily want to stand out.

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Improvement of surface insulation properties of engineering thermoplastics by using nano/micro composite (나노/마이크로 컴포지트를 이용한 엔지니어링 열가소성 플라스틱의 표면 절연 개선)

  • Jung, Eui-Hwan;Lim, Kee-Joe;Hur, Jun;Jeong, Jong-Hun;Kim, Pyung-Jung;Jeong, Su-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.29-29
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    • 2010
  • Engineering plastics have excellent electrical properties, mechanical strength and various characteristic which include chemical resistance, environmental resistance, weatherability at a wide temperature range. It has good characteristic(light weight, good productivity) as compare with epoxy or porcelain insulators. However, engineering plastics not suited to outdoor insulator because it isn't hydrophobic. Therefore, to over come these critical problems, we improve the surface insulation characteristics of engineering plastic by coating micro-, nano- size inorganic fillers added to RTV-SIR(Room temperature vulcanized-silicone rubber) at this plastic surface. The effect is analyzed through salt-fog test, tracking test. In conclusion, the engineering plastic coated RTV with micro-$Al_2O_3$20[phr], nano-Al(OH)3 1 ~ 3[phr] improved much better than the others.

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Elastomeric High Barrier Materials for Vehicle (고차단성 자동차 부품용 고무소재)

  • Kim, Jin-Kuk
    • Elastomers and Composites
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    • v.46 no.1
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    • pp.2-9
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    • 2011
  • Permeability to gases and vapors is an important function in tires, rubber tubes and diaphragms. It mainly depends on the rubber material. Generally, permeability increases in the following order: silicone rubber > NR > EPDM > SBR > NBR > FPM > ECO > IIR. And, for an elastomer permeability is also very much dependent on compounding. Many research works are reported in the area of gas permeability for formed rubber,$^{1-7}$ however, few studies are found for unformed elastomer products. Incorporation of nano-particles, use of thermoplastic elastomers and applying high barrier multilayer coatings are the main approaches to obtain a high barrier elastomeric product. In this paper, barrier article for vehicle is introduced.

MEMBRANES FOR GAS AND LIQUID SEPARATIONS

  • Golemme, Giovanni;Bove, Lucia;Clarizia, Gabriele;Muzzalupo, Rita;Ranieri, Giuseppe;Nam, Sang-Yong;Drioli, Enrico
    • Proceedings of the Membrane Society of Korea Conference
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    • 1999.07a
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    • pp.27-30
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    • 1999
  • Poly(phenylene oxide)s were used to prepare flat, integrally skinned self-supporthed asymmetric membranes by dry-wet phase separption. The intrinsic ideal gas selectivity of poly- (2,6-dimethy-1,4-phenylene oxide) (PMPO) was retained in the membranes, and improved by a coating with silicone rubber. Polymers of the same class were coated of UF supports with a silicon rubber gutter layer, yielding composite membranes with high flux but lower selectivity. The effect of th glutaraldehyde cross-linking of sodium alginate (SA) membranes on the mobility of water and ethanol has been studied with pfg nmr. Crosslinking reduces water self-diffusion, and does not seem to be stable on the timescale of weeks.

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Removal/Recovery of VOCs Using a Rubbery Polymeric Membrane (Rubbery 고분가 막을 이용한 휘발성 유기화학물의 제거 및 회수)

  • Cha, Jun-Seok
    • Membrane Journal
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    • v.6 no.3
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    • pp.173-181
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    • 1996
  • Common volatile organic compounds(VOCs) such as toluene and methanol were removed successfully from N$_{2}$ using a novel silicone-coated hollow fiber membrane module. This novel membrane is a thin film composite(TFC) and was highly efficient in removing VOCs selectively from a N$_{2}$ stream. This membrane had some innate advantages over other silicone-based membrane in that the selective barrier was ultrathin(~1 $\mu$m) and the porosity of the polypropylene substrate was high which leads to a low permeation resistance. The substram was very strongly bonded to the coating layer by plasma polymerization and can withstand a very high pressure. A small hollow fiber module having a length of 25cm and 50 fibers could remove 96~99% of toluene as well as methanol vapors when the feed flow rate was up to 60cc/min. The percent removal of VOCs were even higher when the feed inlet concentration was higher. This process is especially suitable for treating streams having a low flow rate and high VOCs concentration. The permeances of VOCs through this membrane was in the range of $4~30 \times 10^{-9}gmol/sec \cdot cm^{2}\cdot cmHg$ for both toluene and methanol, and nitrogen permeance was between $3~9 \times 10^{-10}gmol/sec \cdot cm^{2} \cdot cmHg$. High separation factor between 10~55 for toluene/N$_{2}$ and 15~125 for methanol/N$_{2}$ were obtained depending on the feed flow rate ranges and feed VOCs concentration levels.

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Modeling and Characteristics of Ethanol Fermentation Process Combined with Pervaporation (투과증발과 결합된 에탄올 발효 공정의 모델링 및 특성)

  • 최은수;김진현;유영제
    • Microbiology and Biotechnology Letters
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    • v.20 no.4
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    • pp.451-458
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    • 1992
  • Pervaporation which is capable of removing ethanol selectively was adopted to reduce the ethanol inhibition and in situ recovery of ethanol in ethanol fermentation, The composite membrane made of silicone and polysulfone was used to separate the ethanol selectively. The ethanol selectivity of the membrane was about 4 and the total flux was 300 g/m2 h at 301:: and 10 mmHg for 25 g/l of feed concentration. Saccharomyces cerevisiae entrapped within Ca-alginate gels was employed for ethanol fermentations in a fluidized-bed bioreactor. The pervaporation membrane unit and fluidized-bed bioreactor were combined into one system. The proposed model equations for the combined system showed good accordances with the experimental results. It was found from the simulation results that the ethanol concentration in the broth for the combined system was lower than that for the continuous fermentation system without a membrane unit. Ethanol productivity can be thus increased by employing the combined system.

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Study on Water Resistance of Environmentally Friendly Magnesium Oxychloride Cement for Waste Wood Solidification

  • Zhang, Feng-Jun;Sun, Xian-Yang;Li, Xuan;Zhang, Dan;Xie, Wen- Jie;Liu, Jin;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.446-451
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    • 2018
  • In this study, different formulations of magnesium oxide and various modifiers (phosphoric acid, ferrous sulfate, pure acrylic emulsion, silicone acrylic emulsion, glass fiber, and polypropylene fiber) were used to prepare magnesium oxychloride cement composites. The compressive strength of the magnesium oxychloride cement was tested, and the softening coefficients of the composites after soaking in water were also calculated. The results showed that a magnesium oxychloride cement sample could not be coagulated when the MgO activity was 24.3%, but the coagulation effect of the magnesium oxide cement sample was excellent when the MgO activity was 69.5%. While pure acrylic emulsion, silicon-acrylic emulsion, and glass fiber showed insignificant modification effects on the magnesium oxychloride cement, ferrous sulfate heptahydrate, phosphoric acid, and polypropylene fiber could effectively improve its water resistance and compressive strength. When the phosphoric acid, ferrous sulfate heptahydrate, and polypropylene fiber contents were 0.47%, 0.73%, and 0.25%, respectively, the softening coefficient of a composite soaked in water reached 0.93 after 7 days, and the compressive strength reached 64.3 MPa.

Design Study on a Variable Intake and a Variable Nozzle for Hypersonic Engines

  • Taguchi, Hideyuki;Futamura, Hisao;Shimodaira, Kazuo;Morimoto, Tetsuya;Kojima, Takayuki;Okai, Keiichi
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.713-721
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    • 2004
  • Variable air intake and variable exhaust nozzle of hypersonic engines are designed and tested in this study. Dimensions for variable geometry air intake, ram combustor and variable geometry exhaust nozzle are defined based on the requirements of a pre-cooled turbojet engine. Hypersonic Ramjet Engine is designed as a scaled test bed for each component. Actuation forces of moving parts for variable intake and variable nozzle are reduced by balancing the other force in the opposite direction. A demonstrator engine which includes variable intake and variable nozzle is designed and the components are fabricated. Composite material with silicone carbide is applied for high temperature parts under oxidation environment such as leading edge of the variable intake and combustor liner. Internal cooling structure is adopted for both moving and static parts of the variable nozzle. Pressure recovery and mass capture ratio of the variable intake at Mach 5 is obtained by a hypersonic wind tunnel test. Flow characteristics of the variable nozzle are obtained by a low temperature flow test. Wall temperature and heat flux of the nozzle at Mach 3 is obtained by a firing test. As results, the intake and the nozzle are proved to be used at designed pressure and temperature environment.

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