• Macromolecular Research
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• v.17 no.12
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• pp.943-949
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• 2009

A highly dispersed W/O emulsion of silicone oil (cyclomethicone)/water system was prepared with a nonionic surfactant. The surface and interfacial tension between the oil and water were characterized in terms of the droplet size distribution and viscosity change of the emulsion. When the dispersed phase concentration was relatively high, the viscosity of the emulsion was rapidly increased and the droplet size of the emulsion was decreased. The rheological behavior of the emulsion system showed non-Newtonian and shear thinning phenomena depending upon the content of the dispersed phase. The droplet size of the emulsion was decreased with increasing surfactant content and water concentration. The relative viscosity of the emulsion was better predicted with the Choi-Schowalter model than with the Taylor model. The value of the complex modulus increased with increasing surfactant concentration. The linear viscoelastic region was expanded with a dispersed phase concentration. According to the change in the viscosity, the behavior was classified into three distinct regions: [I] linear viscoelastic, [II] partially viscoelastic, and [III] viscous. The creep/recovery behaviors in each region were characterized.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.3 no.3
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• pp.86-92
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• 2004

This paper describes the properties of temperature-viscosity characteristics of hydrous and anhydrous electro-rheological fluids containing starch and titanium particle in silicone oil ER effects arise from electrostatic forces between the starch particles and titanium particles dispersed to the electrically insulating silicone oil induced when electric field is applied ER fluids under electric field control have been found to provide resonable estimates of ER fluid viscosity variation characteristics. Yield shear stress of the ER fluids were measured the couette cell type rheometer as a function of electrlc fields. The outer cup is connected to positive electrode(+) and bob becomes ground(-). The electrie field is applied by high voltage DC power supply. In this experiment shear rates were increased from 0 to 200 $s^{-1}$ in 2 minutes. The ER fluid's viscosity change is very small and stable at the temperature range of $40^{\circ}C$ to $60^{\circ}C$. Therefore, applications of a new ER fluid to control systems application are suitable.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.3
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• pp.169-176
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• 2021

This study aimed to fundamentally understand structural changes of zeolite under pressure and in the presence of different pressure-transmitting media (PTM) for application studies such as immobilization of heavy metal cation or CO₂ storage using pressure. High-pressure X-ray powder diffraction study was conducted on the zeolite-W (K_6.4Al_6.5Si_25.8O₆₄× 15.3H₂O, K-MER) to understand linear compressibility and the bulk moduli in different PTM conditions. Zeolite-w is a synthetic material having the same framework as natural zeolite merlinoite ((K, Ca_0.5, Ba_0.5, Na)₁₀ Al₁₀Si₂₂O₆₄× 22H₂O). The space group of the sample was identified as I4/mmm belonging to the tetragonal crystal system. Water, carbon dioxide, and silicone-oil were used as pressure-transmitting media. The mixture of sample and each PTM was mounted in a diamond anvil cell (DAC) and then pressurized up to 3 GPa with an increment of ca. 0.5 GPa. Pressure-induced changes of powder diffraction patterns were measured using a synchrotron X-ray light source. Lattice constants, and bulk moduli were calculated using the Le-Bail method and the Birch-Murnaghan equation. In all PTM conditions, linear compressibility of c-axis (𝛽^c) was 0.006(1) GPa^-1 or 0.007(1) GPa^-1. On the other hand, the linear compressibility of a(b)-axis (𝛽^a) was 0.013(1) GPa^-1 in silicone-oil run, which is twice more compressible than the a(b)-axis in water and carbon dioxide runs, 𝛽^a = 0.006(1) GPa^-1. The bulk moduli were measured as 50(3) GPa, 52(3) GPa, and 29(2) GPa in water, carbon dioxide, and silicone-oil run, respectively. The orthorhombicities of ac-plane in the water, and carbon dioxide runs were comparatively constant, near 0.350~0.353, whereas the value decreased abruptly in the silicone-oil run following formula, y = -0.005(1)x + 0.351(1) by non-penetrating pressure fluid condition.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.33 no.5
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• pp.405-410
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• 2020

In this study, the following results were obtained by analysis of electric properties with FT-IR, DSC, XRD, and SEM, in the range of temperature 30~160℃ and frequency 0.1~200 kHz, when filling agent (0~100 phr) and silicone oil (0~12 phr) were added to raw silicone rubber. In the case of 100 phr mixed samples, the relative dielectric constant εr gradually decreased from 4.3 to 3.96 as frequency increased, and the dielectric loss tan δ decreased to 0.01 at 300 Hz, then increased to 0.022 at 30 kHz, then decreased to 200 kHz. The FT-IR analysis identified the same binding structure according to the chemical composition of added silica (SiO₂). Through DSC analysis, we could determine the change of heat quantity and the glass transition temperature of each specimen. In the XRD analysis, it was found that the images SiO₂, TiO₂, and Fe₂O₃ appeared for specimens with 0%, 50% and 100% filling agent. Finally, the SEM analysis confirmed that particles of 0.5 to 1.5 ㎛ size with silica (SiO₂) mixing were dispersed evenly.

• Design & Manufacturing
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• v.17 no.2
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• pp.27-32
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• 2023

Liquid silicon rubber (LSR) has fine thermal compatibility and is widely used in various fields such as medical care and automobiles because it is easy to implement products with good fluidity. With the recent development of flexible sensors, the focus has been on manufacturing conductive elastomers, such as silicone as elastic materials, and carbon black, CNT, and graphene are mainly used as nanomaterials that impart conductive phases. In this study, mechanical behavior and curing behavior were measured and analyzed to manufacture a CB-LSR complex by adding Carbon Black to LSR and to identify properties. As a result of the compression test, the elastic modulus tended to increase as carbon black was added. When the swelling test and the compression set test were conducted, the swelling rate tended to decrease as the content of carbon black increased, and the compression set tended to increase. In addition, DSC measurements showed that the total amount of reaction heat increased slightly as the carbon black content increased. It is considered that carbon black was involved in the crosslinking of LSR to increase the crosslinking density and have a positive effect on oil resistance reinforcement.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2011.04a
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• pp.113-118
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• 2011

Many kinds of dynamic absorbers have been used to reduce the vibration of machineries and structures. In the typical ones, however low damping capacity, durability and limited install condition restrict their application. In this study, high damped dynamic absorber was proposed for diesel generator set. Developed absorber is composed with mass and coil springs. Silicone oil was filled inside the narrow gap between mass and casing. Viscous damping of silicon oil act as additional damping so that proposed dynamic absorber is suitable for D/G set which have adjacent resonance frequency to operation speed. The performance of the dynamic absorber was confirmed through the actual test on diesel engine generator set.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.11a
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• pp.211-214
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• 1998

DC breakdown characteristics and formation of space charge at the interfaces of crosslinked polyethylene (XLPE) /ethylene propylene diene terpolymer (EPDM) laminates were studied. Effects of silicone grease and some chemicals such as crosslinking coagent on the interfacial charge were also studied. Interfacial charge develops at the interface of XLPE/EPDM laminates, which changes depending on heat treatment conditions and types of chemicals coated at the interface. Some chemicals such as maleic anhydride reduce the accumulation of interfacial charge in the XLPE/EPDM laminates. Breakdown strength of EPDM/XLPE laminate through the interface was highest when silicone oil was pasted in the interfaces. Interfacial breakdown strength decreased with the increase of MAH content.

• Proceedings of the KIEE Conference
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• 2001.11b
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• pp.374-376
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• 2001

In this paper, we developed the fault diagnostic expert system of silicone-immersed transformer using dissolved gas analysis. The knowledge base module consists of the knowledge using the rule: if Then . The inference engine uses the fuzzy rule for the management of uncertainty of the boundary and rule and derivate the Belief and Plausibility of the normality and fault using Dempster-Shafer theory. The expert system is connected to the database and it can manages the history of gas-data of the transformer.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.18 no.2
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• pp.55-62
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• 2004

In this paper, the diagnostic expert system for silicone oil-filled transformer is developed using dissolved gas analysis(DGA). There are many diagnostic methods for diagnostic oil-immersed transformer. But DGA is used to the proposed expert system since it has been verified that DGA is very efficient diagnostic method for transformer. In addition, it is resonable that fuzzy rule, degree of inclusion and fuzzy measure must be considered to handle the uncertainty nature of gas boundary and rules. The proposed expert system consists of knowledge base module, inference engine module and human-machine interface(HMI) module. The knowledge base module consists of the knowledge using the rule. The inference engine module is used to the fuzzy rule. The history of the transformer gas data is managed by the database. the effect of the proposed expert system is verified by case studies.

• KSTLE International Journal
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• v.2 no.2
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• pp.142-145
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• 2001

The electrorheology of the chitosan adipnate suspension in silicone oil was investigated. Chitosan adipnate suspension showed a typical ER response (Bingham flow behavior) upon application of an electric field. The shear stress for the chitosan adipnate suspension exhibited a linear dependence on the volume fraction of particles and an electric field power of 1.88. The experimental results for the chitosan adipnate suspension correlated with the conduction models and this suspension was found to be an anhydrous ER fluid.