• Title/Summary/Keyword: Silicon-Based

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A polymer pH-Selectrode Based on Tribenzylamine as Neutral Carrier (Tribenzylamine 중성운반체를 이용한 pH-선택성 고분자 막전극)

  • Park, Myon-Young;Chung, Koo-Chun;Cho, Dong-Hoe;Lee, Kyeong-Jae;Jeong, Seong-Suk;Park, Sun-Young;Kim, Tae-Hun
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.63-68
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    • 1995
  • For the preparation of pH-selectrode, tribenzylamine, polyvinylchloride, dioctylphthalate, sodium tetraphenylborate and tetrahydrofuran were mixed with 0.02, 0.62, 1.34, 0.02g and 10ml respectively, and added 1g of acetylene black, graphite, silicon carbide or tungsten carbide respectively to improve electric conductivity. The selectrodes of seven kinds were shown linear to hydrogen ion in the range of pH 2 and 9. The best electric conductor for preparation of pH-selectrode based on tribenzylamine as neutral carrier was acetylene black and responded potential of the selectrode to hydrogen ion was shown the values near to theoretical Nernstian slope at $20^{\circ}C$. The interfering effects of the selectrode on hydrogen ion in the presence of alkali and alkaline earth metal ions were shown the better results with less error than glass electrode. The reproducibility and stability were good for use as a selectrode, especially in the presence of fluoride ion.

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Evaluation of Contrast-detail Characteristics of an A-Se Based Digital X-ray Imaging System (A-Se 기반 디지털 X-선 영상장치의 Contrast-detail 특성 평가)

  • Hyun, Hye-Kyung;Park, So-Hyun;Kim, Keun-Young;Cho, Hee-Moon;Cho, Hyo-Sung
    • Journal of the Korean Society of Radiology
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    • v.1 no.1
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    • pp.11-16
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    • 2007
  • In this study, we have performed contrast-detail analysis for an amorphous selenium(a-Se) based digital X-ray imaging system by using a contrast-detail phantom(CDRAD 2.0) to test its low contrast performance. The X-ray imaging system utilizes an 500-mm-thick a-Se semiconductor X-ray absorber coated over an amorphous silicon(a-Si) TFT(thin-film transistor) detector matrix with a $139mm{\times}139mm$ pixel size and a $46.7cm{\times}46.7cm$ active area. In the measurement of contrast-detail curves we first acquired X-ray images of the CDRAD 2.0 phantom at given test conditions(i.e., 40, 50, 60, 70, 80 kVp, and 16 mA.s), and then evaluated the contrast-detail characteristics of the imaging system from each phantom image by using an image quality factor called the image-quality-figure-inverse(IQFinv). The IQFinv values for the imaging system gradually improved with the photon fluence, indicating the improvement of image visibility: 24.4, 35.3, 39.2, 41.5, and 43.4 at photon fluences of $1.8{\times}105$, $5.9{\times}105$, $11.3{\times}105$, $19.4{\times}105$, and $29.4{\times}105$ photons/$mm^2$, respectively.

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Design and Fabrication of the 0.1${\mu}{\textrm}{m}$ Г-Shaped Gate PHEMT`s for Millimeter-Waves

  • Lee, Seong-Dae;Kim, Sung-Chan;Lee, Bok-Hyoung;Sul, Woo-Suk;Lim, Byeong-Ok;Dan-An;Yoon, yong-soon;kim, Sam-Dong;Shin, Dong-Hoon;Rhee, Jin-koo
    • Journal of electromagnetic engineering and science
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    • v.1 no.1
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    • pp.73-77
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    • 2001
  • We studied the fabrication of GaAs-based pseudomorphic high electron mobility transistors(PHEMT`s) for the purpose of millimeter- wave applications. To fabricate the high performance GaAs-based PHEMT`s, we performed the simulation to analyze the designed epitaxial-structures. Each unit processes, such as 0.1 m$\mu$$\Gamma$-gate lithography, silicon nitride passivation and air-bridge process were developed to achieve high performance device characteristics. The DC characteristics of the PHEMT`s were measured at a 70 $\mu$m unit gate width of 2 gate fingers, and showed a good pinch-off property ($V_p$= -1.75 V) and a drain-source saturation current density ($I_{dss}$) of 450 mA/mm. Maximum extrinsic transconductance $(g_m)$ was 363.6 mS/mm at $V_{gs}$ = -0.7 V, $V_{ds}$ = 1.5 V, and $I_{ds}$ =0.5 $I_{dss}$. The RF measurements were performed in the frequency range of 1.0~50 GHz. For this measurement, the drain and gate voltage were 1.5 V and -0.7 V, respectively. At 50 GHz, 9.2 dB of maximum stable gain (MSG) and 3.2 dB of $S_{21}$ gain were obtained, respectively. A current gain cut-off frequency $(f_T)$ of 106 GHz and a maximum frequency of oscillation $(f_{max})$ of 160 GHz were achieved from the fabricated PHEMT\\`s of 0.1 m$\mu$ gate length.h.

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Effect of the Whisker Amount and Orientation on Mechanical Properties of the Si$_3$N$_4$ based Composites (Si$_3$N$_4$ Whisker의 첨가량과 배열방향이 Si$_3$N$_4$ 복합 소결체의 기계적 특성에 미치는 영향)

  • Kim, Chang-Won;Park, Dong-Soo;Park, Chan
    • Journal of the Korean Ceramic Society
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    • v.36 no.1
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    • pp.43-49
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    • 1999
  • Gas pressure sintered silicon nitride based composites with 0~5wt% $\beta$-Si3N4 whiskers were prepared. The whiskers were unidirectionally oriented by a modified tape casting technqiue and green bodies with various microstructure were formed by changing stacking sequences of sheets cut from the tape. Orientations of the large elongated grains of the sample after gas pressure sintering were the same as the those of the whiskers of green body, and the sintering shrinkage and mechanical properties of sintered sample were consistent with the microstructural characteristics. In case of unidirectional samples, the sintering shrinkage normal to whisker alignment direction was larger than that parallel to the direction. The shrinkage difference inceaed as the whiskercontent increaed. As whisker content increaed, the crack length normal to and parallel to tape casting direction became shorter and larger, respectively. Although the grain size increased by th whisker addition, the flexural strength of unidirectional samples was not lower than that of smaple without the whisker. In case of crossplied and 45$^{\circ}$rotated samples, the anisotropy of mechanical preoperties disappeared.

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Polymer-based Large Core Optical Splitter for Multimode Optical Networks (멀티모드 광네트워크용 폴리머기반 대구경 광분배기)

  • An, Jong Bae;Lee, Woo-Jin;Hwang, Sung Hwan;Kim, Gye Won;Kim, Myoung Jin;Jung, Eun Joo;Moon, Jong Ha;Kim, Jin Hyeok;Rho, Byung Sup
    • Korean Journal of Optics and Photonics
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    • v.24 no.4
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    • pp.184-188
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    • 2013
  • Two types of polymer-based optical splitters with $200{\mu}m$ large core are presented for optical multimode networks, such as smart home networks, intelligent automotive networks, etc. Optical splitters that have 1:1 symmetric and 9:1 asymmetric structure were fabricated by a ultra violet(UV)-imprint technology using a deep etched Si(silicon) master by the Bosch process. In this paper, we successfully fabricated the symmetric and asymmetric optical splitters with suitable optical network applications.

Effect of Alkaline Activator and Curing Condition on the Compressive Strength of Cementless Fly Ash Based Alkali-Activated Mortar (시멘트를 사용(使用)하지 않은 플라이애시 알칼리 활성(活性) 모르타르의 압축강도(壓縮强度)에 미치는 알칼리 활성제(活性劑) 및 양생조건(養生條件)의 영향(影響))

  • Kang, Hyun-Jin;Ryu, Gum-Sung;Koh, Kyung-Taek;Kang, Su-Tae;Park, Jung-Jun;Kim, Sung-Wook;Lee, Jang-Hwa
    • Resources Recycling
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    • v.18 no.2
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    • pp.39-50
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    • 2009
  • Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of fly ash, a by-products from thermal power plant to partially replace the cement in concrete are gathering momentum. But most of fly ash is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effective in the reduction of $CO_2$ gas. In this study, we investigated the influence of the compressive strength of mortar on alkaline activator and curing condition in order to develop cementless fly ash based alkali-activated concrete. In view of the results, we found out that it was possible for us to make alkali-activated mortar with 70MPa at the age of 28days by using alkaline activator manufactured as 1:1 the mass ratio of 9M NaOH and sodium silicate and applying the atmospheric curing after high temperature at $60^{\circ}C$ for 48hours.

Micro-Spot Atmospheric Pressure Plasma Production for the Biomedical Applications

  • Hirata, T.;Tsutsui, C.;Yokoi, Y.;Sakatani, Y.;Mori, A.;Horii, A.;Yamamoto, T.;Taguchi, A.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.44-45
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    • 2010
  • We are currently conducting studies on culturing and biocompatibility assessment of various cells such as neural stem cells and induced pluripotent stem cells(IPS cells) on carbon nanotube (CNT), on nerve regeneration electrodes, and on silicon wafers with a focus on developing nerve integrated CNT based bio devices for interfacing with living organisms, in order to develop brain-machine interfaces (BMI). In addition, we are carried out the chemical modification of carbon nanotube (mainly SWCNTs)-based bio-nanosensors by the plasma ion irradiation (plasma activation) method, and provide a characteristic evaluation of a bio-nanosensor using bovine serum albumin (BSA)/anti-BSA binding and oligonucleotide hybridization. On the other hand, the researches in the case of "novel plasma" have been widely conducted in the fields of chemistry, solid physics, and nanomaterial science. From the above-mentioned background, we are conducting basic experiments on direct irradiation of body tissues and cells using a micro-spot atmospheric pressure plasma source. The device is a coaxial structure having a tungsten wire installed inside a glass capillary, and a grounded ring electrode wrapped on the outside. The conditions of plasma generation are as follows: applied voltage: 5-9 kV, frequency: 1-3 kHz, helium (He) gas flow: 1-1.5 L/min, and plasma irradiation time: 1-300 sec. The experiment was conducted by preparing a culture medium containing mouse fibroblasts (NIH3T3) on a culture dish. A culture dish irradiated with plasma was introduced into a $CO_2$-incubator. The small animals used in the experiment involving plasma irradiation into living tissue were rat, rabbit, and pick and are deeply anesthetized with the gas anesthesia. According to the dependency of cell numbers against the plasma irradiation time, when only He gas was flowed, the growth of cells was inhibited as the floatation of cells caused by gas agitation inside the culture was promoted. On the other hand, there was no floatation of cells and healthy growth was observed when plasma was irradiated. Furthermore, in an experiment testing the effects of plasma irradiation on rats that were artificially given burn wounds, no evidence of electric shock injuries was found in the irradiated areas. In fact, the observed evidence of healing and improvements of the burn wounds suggested the presence of healing effects due to the growth factors in the tissues. Therefore, it appears that the interaction due to ion/radicalcollisions causes a substantial effect on the proliferation of growth factors such as epidermal growth factor (EGF), nerve growth factor (NGF), and transforming growth factor (TGF) that are present in the cells.

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High Energy Density Germanium Anodes for Next Generation Lithium Ion Batteries (다음세대 리튬이온 배터리용 고에너지 밀도 게르마늄 음극)

  • Ocon, Joey D.;Lee, Jae Kwang;Lee, Jaeyoung
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.1-13
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    • 2014
  • Lithium ion batteries (LIBs) are the state-of-the-art technology among electrochemical energy storage and conversion cells, and are still considered the most attractive class of battery in the future due to their high specific energy density, high efficiency, and long cycle life. Rapid development of power-hungry commercial electronics and large-scale energy storage applications (e.g. off-peak electrical energy storage), however, requires novel anode materials that have higher energy densities to replace conventional graphite electrodes. Germanium (Ge) and silicon (Si) are thought to be ideal prospect candidates for next generation LIB anodes due to their extremely high theoretical energy capacities. For instance, Ge offers relatively lower volume change during cycling, better Li insertion/extraction kinetics, and higher electronic conductivity than Si. In this focused review, we briefly describe the basic concepts of LIBs and then look at the characteristics of ideal anode materials that can provide greatly improved electrochemical performance, including high capacity, better cycling behavior, and rate capability. We then discuss how, in the future, Ge anode materials (Ge and Ge oxides, Ge-carbon composites, and other Ge-based composites) could increase the capacity of today's Li batteries. In recent years, considerable efforts have been made to fulfill the requirements of excellent anode materials, especially using these materials at the nanoscale. This article shall serve as a handy reference, as well as starting point, for future research related to high capacity LIB anodes, especially based on semiconductor Ge and Si.

Distributional characteristics of phytoplankton and nutrient limitation during spring season in Jinhae Bay (춘계 진해만에서 식물플랑크톤 증식과 제한영양염 분포특성)

  • Son, Moonho;Kim, Dongseon;Baek, Seung Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3345-3350
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    • 2014
  • We investigated to assess the relationships between the major nutrients and phytoplankton dynamics during the spring season in 2010 and 2011 at 23 stations in Jinhae Bay, Korea. The bay is divided into four different zones based on pollutant sources and geographical characteristics. Nutrient limitation (>80%) was significant in Zone II, which is located in central bay and is influenced by the water well mixed from outer bay. The limited nutrient was followed in Zone III and IV that was occupying between 17% and 83%. However, the low levels are being kept below 35% in Zone I, which is characterized by the semi-enclosed eutrophic area of Masan and Haegam bays. Based on the PCA (principle component analysis) analysis, the nitrogen (N) sources in 2010 were particularly dominant and it may be due to the water mixing and wastewater formed from bottom layers and sewage. In 2011, major nutrients including nitrogen, silicon and phosphorus were dominant in the bay and are supplied by the river discharge after rainfalls with low salinity conditions. In particular, the N nutrients being supplied in 2010 are correlated with pennate diatoms Pseudo-nitzchia spp. and is not related to the phytoplankton population densities in 2011. The present study suggests that N sources play an important role in the proliferation of diatom, and the rapid nutrient uptakes by them are potential nutrient limitation factors in the bay.

Comparison of Antifungal Activity, Plant Growth Promoting Activity, and Mineral-Solubilizing Ability of Bacillus sp. Isolated from Rhizosphere Soil and Root (근권 토양과 뿌리로부터 분리된 Bacillus sp.의 항진균 활성, 식물 생장 촉진 활성 및 미네랄 가용화능 비교)

  • Kim, Hee Sook;Oh, Ka-Yoon;Lee, Song Min;Kim, Ji-Youn;Lee, Kwang Hui;Lee, Sang-Hyeon;Jang, Jeong Su
    • Microbiology and Biotechnology Letters
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    • v.49 no.4
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    • pp.576-586
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    • 2021
  • The purpose of this study was to evaluate the antifungal activity, plant-growth-promoting activity, and mineral solubilization ability of 10 species of phytopathogenic fungi to select a Bacillus sp. from rhizosphere soils and roots that can be used as a microbial agent. The antifungal activity for phytopathogenic fungi varied based on the Bacillus sp. Among the selected strains, DDP4, DDP16, DDP148, SN56, and SN95 exhibited antifungal activity for nine or more species of phytopathogenic fungi. Regarding nitrogen-fixation ability, all Bacillus sp. showed similar levels of activity, and siderophore production ability was relatively high in ANG42 and DDP427. The indole-3-acetic acid production abilities were in the range of 1.83-67.91 ㎍/ml, with variations in activity based on the Bacillus sp. One strain with a high activity was selected from each species, and their mineral solubilization abilities were examined. Most Bacillus sp. could solubilize phosphoric acid and calcium carbonate, and DDP148 and SN56 could solubilize silicon and zinc, respectively. These results suggested that Bacillus sp. can be considered potential multi-purpose microbial agents for plant growth promotion and disease prevention.