• Korean Chemical Engineering Research
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• v.59 no.4
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• pp.487-492
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• 2021

In this study, the electrochemical properties of pitch coated silicon sheets/graphite anode materials were investigated. Using NaCl as a template, silicon sheets were prepared through the stöber method and the magnesiothermic reduction methode. In order to synthesize the anode composite, the silicon sheets and graphite were combined with SDBS. The pitch coated silicon sheets/graphite was synthesized using THF as a solvent for the anode material composite. The physical properties of the prepared anode composites were analysed by XRD, SEM, EDS and TGA. The electrochemical performances of the prepared anode composites were performed by the current charge/discharge, rate performance, cyclic voltammetry and EIS tests in the electrolyte LiPF₆ dissolved solvents (EC:DMC:EMC=1:1:1 vol%). As the silicon composition of silicon sheets/graphite composite material increased, the discharge capacity also increased, but the cycle stability tended to decrease. The anode material of pitch coated silicon sheets/graphite composite (silicon sheets:graphite=3:7 weight ratio) showed the initial discharge capacity of 1228.8 mAh/g and the capacity retention ratio of 77% after 50 cycles. From these results, it was found that the cycle stability of pitch coated silicon sheets/graphite was improved.

• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.446-451
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• 2022

In this study, to improve capacity and cycle stability, the pitch coated nano silicon sheets/CNT composites were prepared through electrostatic bonding of nano silicon sheets and CNT. Silica sheets were synthesized by hydrolyzing TEOS on the crystal planes of NaCl, and then nano silicon sheets were prepared by using magnesiothermic reduction method. To fabricate the nano silicon sheets/CNT composites, the negatively charged CNT after the acid treatment was used to assemble the positively charged nano silicon sheets modified with APTES. THF as a solvent was used in the coating process of PFO pitch. The physical properties of the prepared anode composites were analysed by FE-SEM, XRD and EDS. The electrochemical performances of the synthesized anode composites were performed by current charge/discharge, rate performances, differential capacity and EIS tests in the electrolyte LiPF₆ dissolve solvent (EC:DMC:EMC = 1:1:1 vol%). It was found that the anode material with high capacity and stability could be synthesized when high composition of silicon and conductivity of CNT were used. The pitch coated nano silicon sheets/CNT anode composites showed initial discharge capacity of 2344.9 mAh/g and the capacity retention ratio of 81% after 50 cycles. The electrochemical property of pitch coated anode material was more improved than that of the nano silicon sheets/CNT composites.

• Journal of the Korean Society for Precision Engineering
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• v.14 no.6
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• pp.37-43
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• 1997

The technology of Laser lamination joining of silicon steel sheets has been studied in this paper. Conventional sheets lamination process does not meet the requirments for the improvement electric parts performance. In response to this, a new Laser spot joining method has been developed. This study performs the Laser spot lamination joining while synchronizing the sillicon steel sheets in the dies with the press movement. Several conclusions have been drawn in this paper. Effects of beam focus, power, atmosphere gas and press oil etc.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.58 no.2
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• pp.190-195
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• 2009

Thin-gauged 3% silicon steel sheets having a highly grain-oriented texture have been developed as a core material for applications of middle-frequency (400 Hz ${\sim}$ 10 kHz) devices. The newly developed sheets with a tension coating showed an excellent reduction in iron loss at 400 Hz (iron loss at 1.0 T and 400 Hz = 4.677 W/kg, iron loss at 1.5 T and 400 Hz = 9.742 W/kg) due to high magnetic induction, $B_{10}$(measured induction at 1000 A/m), of over 1.9 T. In cases of frequencies below 400 Hz, magnetic induction, $B_{10}$, of the sample plays a major role to reduce its iron loss as excitation induction increases, whereas, in case of frequency of 1 kHz, thickness dependence becomes dominant due to a lower iron loss at relatively thinner sample. The sheets with a high magnetic induction, therefore, are favorable for high excitation induction (over 1.0 T) and low excitation frequency (below 400 Hz) applications, whereas the sheets that can reduce eddy current loss by reducing thickness or domain wall width are advantageous for low excitation induction (below 1.0 T) and high excitation frequency (around 1 kHz) applications.

• Journal of Integrative Natural Science
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• v.2 no.4
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• pp.280-284
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• 2009

The unique electronic property of graphene sheets provides potential applications in nanocomposites and fabricating various nicroelectrical devices, such as field-effect transistors, ultrasensitive sensors, and electromechanical resonators. Several effective techniques have been developed for preparing graphene sheets. Among these technique, mechanical exfoliation can produce pure graphene and epitaxial graphene sheets have been prepared by treatment of silicon carbide wafers at high temperature. Recently, graphene sheets have been developed by chemical reduction method from graphene oxide. In this work, we have synthesized graphene sheets based on mechanical exfoliation and chemical reduction methods. Graphene sheets were characterized by field-effect scanning electron microscope (FE-SEM). The size of graphene sheets was from few hundreds nanometer to decades micrometer.

• Journal of the Korean institute of surface engineering
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• v.32 no.2
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• pp.134-143
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• 1999

The effects of silicon on galvannealing behavior of interstitial-free (IF) steels were studied. The growth rate of the Fe-Zn alloy layer was retarded as silicon in the steel added. Titanium in steel strongly favors Fe-Zn reaction, in particular outburst structures, whereas silicon inhibit them. Cross-sectional and planar views of galvannealed coatings were investigated to characterize alloy phase development. A possible mechanism to explain the retardation effect of silicon is discussed in terms of concentration on surface and inhibition layer.

• Journal of Industrial and Engineering Chemistry
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• v.67
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• pp.417-428
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• 2018

In this study, we fabricated hierarchically self-assembled thin films composed of graphene oxide (GO) sheets and gold nanoparticles (Au NPs) using the Langmuir-Blodgett (LB) and Langmuir-Schaefer (LS) techniques and investigated their gas-sensing performance. First, a thermally oxidized silicon wafer ($Si/SiO_2$) was hydrophobized by depositing the LB films of cadmium arachidate. Thin films of ligand-capped Au NPs and GO sheets of the appropriate size were then sequentially transferred onto the hydrophobic silicon wafer using the LB and the LS techniques, respectively. Several different films were prepared by varying the ligand type, film composition, and surface pressure of the spread monolayer at the air/water interface. Their structures were observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM), and their gas-sensing performance for $NH_3$ and $CO_2$ was assessed. The thin films of dodecanethiol-capped Au NPs and medium-sized GO sheets had a better hierarchical structure with higher uniformity and exhibited better gas-sensing performance.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1998.11a
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• pp.71-71
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• 1998

• Journal of the Korean Vacuum Society
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• v.12 no.4
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• pp.281-287
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• 2003

We have performed classical molecular dynamics simulations for hypothetical silicon nanotubes using the Tersoff potential. Our investigation presented a systematic study about the thermal behavior of hypothetical silicon nanotubes and showed the difficulty in Producing silicon nanotubes or graphitelike sheets. Through the investigations on the structure and properties of a double-wall silicon nanotube, we concluded that quasi-one dimensional structures consisting of silicon atoms become nanowires or multi wall nanotubes rather than single wall nanotubes in order to minimize the number of $sp^2$ bonds.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.6
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• pp.141-147
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• 2008

Hot-dip galvannealed sheet (GA) with high strength of 590MPa grade in tensile strength, has developed for automotive applications. However, for a successful application, the microstructure and galvannealing behavior of galvannealed TRIP steel sheets must be strictly controlled. High silicon contents steel has problems with weld-ability, zinc coating and reduction of retained austenite volume fraction after galvannealing process. The main purpose of this study is to solve the problem as indicated above.