• Title/Summary/Keyword: Silicon and Manganese contents

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Thermodynamic Interactions Among Carbon, Silicon and Iron in Carbon Saturated Manganese Melts (탄소 포화 Mn 합금 용액내 C, Si 및 Fe 사이의 열역학적 상호작용)

  • Paek, Min-Kyu;Lee, Won-Kyu;Jin, Jinan;Jang, Jung-Mock;Pak, Jong-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.1
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    • pp.45-51
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    • 2012
  • Thermodynamics of carbon in manganese alloy melts is important in manufacturing low carbon ferromanganese and silico-manganese alloys. In order to predict the carbon solubility in liquid $Mn-Si-Fe-C_{sat}$ alloys as a function of melt composition and temperature, thermodynamic interactions among carbon, silicon and iron in carbon saturated liquid manganese should be known. In the present study, the effects of silicon and iron on the carbon solubility in Mn-Si, Mn-Fe and Mn-Si-Fe melts were measured in the temperature range from 1673 to 1773 K. The carbon solubility decreases significantly as silicon and iron contents increase in liquid manganese alloy. The interaction parameters among carbon, silicon and iron in carbon saturated liquid manganese were determined from the carbon solubility data and the Lupis' relation for the interaction coefficient at constant activity.

Effects of Thickness, Si and Mn Contents on the Mechanical Properties of 3.3 wt%C-0.1 wt%S Thin-Section Gray Cast Iron (3.3 wt%C-0.1 wt%S 박육 주철의 기계적 성질에 미치는 두께, 규소 및 망간의 영향)

  • Lee, Woo-Jong;Kim, Tae-Hyeong;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.32 no.5
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    • pp.211-218
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    • 2012
  • The effects of thickness, silicon and manganese contents on the mechanical properties of 3.3 wt%C-0.1 wt%S thin-section gray cast iron plates were investigated. The eutectic cell counts and volume fraction of pearlite in the matrix decreased with increased thickness and therefore the strength and hardness decreased with it. Even though the eutectic cell count increased with increased silicon content, the volume fraction of pearlite decreased and the strength and hardness decreased with it. The pearlite was refined more with increased manganese content and therefore the strength and hardness increased with it.

Chemical composition of SAW weld metal welded with metal cored composite wire (메탈코어드 콤포지트 와이어를 사용한 SAW 용접금속 성분변화)

  • Jeong, Dong-Hui;Bang, Guk-Su;Jeong, Hong-Cheol;Lee, Jong-Bong;Park, Cheol-Gyu
    • Proceedings of the KWS Conference
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    • 2007.11a
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    • pp.310-312
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    • 2007
  • Two metal cored composite wires were manufactured to satisfy AWS F7A4-EC-G specification. They were used to weld EH36 grade steels with three different fluxes. Variation of carbon, manganese, silicon, titanium, and boron contents which affect the weld metal strength in weld metal was investigated.

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A Development of Connection Piece Steel Casting for the Offshore Structures Using High Impact Value with Low Temperature & High Strength Casting Steel Material (고강도 및 저온 고충격 주강소재를 이용한 해양플렌트용 커넥트 주강부품 개발)

  • Kim, Tae-Eon;Park, Sang-Sik;Kang, Chung-Gil
    • Journal of Korea Foundry Society
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    • v.30 no.4
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    • pp.151-156
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    • 2010
  • The high-strength low-alloy (HSLA) steels have low carbon contents (0.05~0.25% C) in order to produce adequate formability and weldability, and they have manganese contents up to 1.7%. Small quantities of silicon, chromium, nickel, copper, aluminum, molybdenum are used in various combinations. The results contained in this paper can provide the valuable information on the development of $-40^{\circ}C$ low temperature HSLA. Furthermore, the present experimental data will provide important database for casting steel materials of the offshore structure.

Effects of Thickness, Base Element and Additive to Inoculant on the Number of Eutectic Cells and Chill Depth of Thin-Section Gray Cast Iron (박육주철의 공정 셀 수와 칠 깊이에 미치는 두께, 기본 원소 및 접종제 첨가 원소의 영향)

  • Kim, Tae-Hyeong;Lee, Woo-Jong;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.32 no.6
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    • pp.261-268
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    • 2012
  • The effects of thickness, base element and additive to inoculant on the number of eutectic cells and chill depth of thin-section gray cast iron were investigated. Meanwhile the number of eutectic cells increased by inoculation, chill depth decreased. The former decreased and the latter increased by holding the melt at the temperature range between 1,450 and $1,500^{\circ}C$. The former was more for the thinner casting with the thickness of 5 mm than the other. The result of thermal analysis coincided well with the change of macrostructure. The former increased and the latter decreased with the increased contents of carbon, silicon and the silicon content by inoculation. The former decreased and the latter increased with increased manganese content. The number of eutectic cells decreased as the amounts of rare earth and the bismuth added to this inoculant increased. With the addition of sulfur of 0.10 wt% of the weight of this inoculant, the maximum number of eutectic cells was obtained.

Effects of Thickness, Base Element and Inoculants on the Number of Eutectic Cells and Chill Depth of Gray Cast Iron Plate Casting (회주철 판형 주조품의 공정 셀 수와 칠 깊이에 미치는 두께, 기본 원소 및 접종제의 영향)

  • Kim, Tae-Hyeong;Oh, Jung-Hyuck;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.31 no.3
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    • pp.137-144
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    • 2011
  • The effects of thickness, base element and inoculants on the number of eutectic cells and chill depth of gray cast iron plate casting were investigated. Meanwhile the number of eutectic cells increased by inoculation, chill depth decreased. The former decreased and the latter increased by holding the melt at the temperature range between 1,450 and $1,500^{\circ}C$. The former was more for the thinner casting with the thickness of 5 mm than the other. The result of thermal analysis coincided well with the change of macrostructure. The former increased and the latter decreased with the increased contents of carbon, silicon and the silicon content by inoculation. The former decreased and the latter increased with increased manganese content. The performance of the Superseed Extra was the best among 5 inoculants.

A Study on the Low Temperature & High-strength Low-alloy Material for Casting Steel of the Offshore Structures (해양구조물용 저온 고강도 Casting Steel 소재 개발)

  • Lee, Soo-Ho;Han, Ki-Hyoung;Bae, Jae-Ryu;Kim, Tae-Won;Park, Sang-Sik;Kang, Chung-Gil
    • Journal of the Society of Naval Architects of Korea
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    • v.45 no.4
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    • pp.426-431
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    • 2008
  • The high-strength low-alloy(HSLA) steels have low carbon contents($0.05{\sim}0.25%$ C) in order to produce adequate formability and weldability, and they have manganese contents up to 1.7%. Small quantities of silicon, chromium, nickel, copper, aluminum, molybdenum are used in various combinations. The results contained in this paper can provide the valuable information on the development of $-40^{\circ}C$ low temperature HSLA. Furthermore, the present experimental data will provide important database for casting steel materials of the offshore structure.

Effects of Amount of Second Cold-Reduction on Secondary Recrystallization and Texture Development in Grain-Oriented Silicon Steel

  • Yoon, Young-Ku;Lee, Taek-Dong
    • Nuclear Engineering and Technology
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    • v.3 no.3
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    • pp.129-140
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    • 1971
  • Two laboratory-melt heats of 3.25 silicon-iron were made and processed according to a normal commercial practice. Some of the important processing variables that were studied in relation to secondary recrystallization and texture development were contents of manganese and sulfur, heat-treatments after hot-rolling that were used to achieve different hot-rolled microstructures, and amounts of second cold-reduction. The main effort of the present study was directed toward elucidating the relationships among the amount of second cold-reduction, activation energies associated with secondary recrystallization and texture development. The specimens that had been cold-reduced 10% exhibited only grain growth by strain-induced grain boundary migration and did not exhibit secondary recrystallization. Secondary recrystallization did rot appear to completely occur in the 30% cold-reduced specimens, although the nucleation for secondary recrystallization was observed. The second cold-reduction in an amount of 50% was shown to be the optimun for secondary recrystallization and texture development by subsequent processing.

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Analysis of Physiological Activity and Cytotoxicity of Residue Extracts after Pepper Harvest (고추 수확 후 잔재물 추출물의 생리활성과 세포독성 분석)

  • Kim, Tae-Won;Jeon, Byeong-Gyun;Lee, Sung-Ho
    • Journal of Life Science
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    • v.30 no.12
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    • pp.1085-1091
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    • 2020
  • The purpose of this study was to investigate the value of residue discarded after harvesting a species of pepper (Capsicum annuum L.). This study analyzed the physiological activity and cytotoxicity of a fermented extract and a hot water extract gathered from the residues of the Cheongyang pepper and the Nokkwang pepper. The total nitrogen, phosphoric acid, potassium, calcium, and magnesium contents of the fermented extract of the Nokkwang pepper were approximately twice as high as those of the Cheongyang pepper, while the hot water extracts had similar levels of these components across both peppers. Among the microelements, only boric acid, iron, and silicon components were detected, whereas zinc, manganese, molybdenum, and copper components were not detected in either extract. The total polyphenol and flavonoid contents of the fermented extracts were more than two times higher than those of the hot water extracts for both peppers. The DPPH radical scavenging ability (indicating antioxidant activity) of the fermented extract was higher than that of the hot water extract, while the ABTS radical scavenging ability (indicating antioxidant activity) of the hot water extract was higher than that of the fermented extract. A cytotoxicity test was conducted on the extracts using an MTT assay. Both extracts exhibited weak cytotoxicity at all concentrations for both peppers. These results suggest that the extract of residue discarded after harvesting these peppers could be suitable for functional feed or agricultural materials.

Studies on Nutrio-physiology of Low Productive Rice Plants (수도저위생산력(水稻低位生産力)의 원인구명(原因究明)에 관(關)한 영양생리적연구(營養生理的硏究))

  • Park, Jun-Kyu
    • Applied Biological Chemistry
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    • v.17 no.1
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    • pp.1-30
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    • 1974
  • Present study was undertaken to elucidate the relationship between uptake of nutrients and photosynthetic activities, and the translocation of several mineral nutrients in rice plants which were grown under different cultural conditions, utilizing radioactive tracer technique. Particular emphasis was placed on the analysis of patterns of nutrient uptake, the relationship between nutritional conditions and yield components. For this, rice plants grown on either low or high yielding fields at different growth stage were subjected to this study. The results are summarized as follows; 1. Varietal difference was observed in the uptake of potassium and phosphorus. Kusabue and Jinheung had good capacity but Paldal had rather poor capacity for the uptake of the both nutrients. 2. For rice plants, a high positive correlation was found between the oxidation of alpha plaus-naphthylamine by root and uptake of phosphorus. 3. Carbon assimilation rate repended on rice varieties. It was high in Noindo, Gutaenajuok #3 Suweon #82 and Jinheung but low in Taegujo, Kwanok, Yugu #132 etc. 4. Heavy application of nitrogen increased carbon assimilation in rice plants but this also depressed translocation of certain carbohydrates to ears. 5. Carbon assimilation wan greatly hampered in rice plants deficient in magnesium, phosphorus or potassium. 6. Total dry matter after ear formation stage, was much higher in rice plants grown in high yielding fields than those grown in low yielding fields. 7. Leaf area index(LAI) reached maximum at heading stage and decreased thereafter in high yielding fields. But in low yielding fields, it reached maximum before heading and sharply decreased thereafter due to early senescence of lower leaves. 8. In general, light transmission ratio (LTR) of leaves was higher in the early growth stage and lower in later stages. Higher ratio of LTR to leaf area index, was found in the rice grown in high yielding fields than those in low yielding fields. 9. Net photosynthetic activity decreased with the increase in leaf area index but was higher in high yielding fields than in low yielding fields. 10. After the ear formation stage, nitrogen, potassium and silicon as weil as $K_2O/N$ in straw were higher in high yielding fields than those in low yielding fields. 11. Nitrogen, phosphorus, potassium and magnesium taken up by rice plants in low yielding fields before heading stage were readily translocated to ears than those in high yielding fields. This suggests greater redistribution of nutrients in straw occurs due to lower uptake, in later growth stages, by rice plants grown in low yielding fields and hence results in early senescence due to nutrient deprivation. 12. In the high yielding fields nitrogen uptake by rice was slow but continuous throughout the life of the plants resulting in a large uptake even after heading. But, in low yielding fields the uptake was fast before heading and slow after heading. 13. A high positive correlation was found between the contents of nitrogen and potassium in the straw at heading stage and grain yield. Positive correlation was also found to hold between the contents of potassium, silicon, $K_2O/N$, $SiO_2/N$ in the straw at harvesting stage, and grain yield. 14. Carbon assimilation was greately hampered in rice plants deficient in magensium, phosphorus or potassium. 15. Uptake of nitrogen, phosphorus, potassium, silicon and manganese by rice was considerably higher in high yielding fields and reached maximum at ear formation stage. 16. In rice, a high positive correlation was discovered between total uptake of nitrogen, phosphorus, potassium, calcium, magnesium, silicon, manganese at harvesting stage and grain yield. 17. In rice, a high positive correlation was found between the total uptake of nitrogen, phosphorus, potassium, calcium, magnesium, silicon at harvesting stage, and number of spikelets per $3.3\;m^2$. In addition, a correlation was found between the total uptake of nitrogen and potassium and number of panicles per hill.

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