• Title/Summary/Keyword: Silica-alumina

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Durability of Nozzle Materials for Strip Casting of Amorphous Alloys (비정질합금 박판 제조용 노즐 재료의 내구성평가)

  • Kang, Bok-Hyun;Kim, Ki-Young
    • Journal of Korea Foundry Society
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    • v.31 no.5
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    • pp.267-273
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    • 2011
  • Erosion and thermal shock resistance of several refractory materials have been investigated, which are expected to be used as nozzles in a planar flow casting equipment for amorphous alloys. The test was conducted on five materials; graphite, boron nitride, fused silica, alumina and zirconia. Test specimens were preheated and dipped into the melt of carbon steel and amorphous alloys. Some test specimens were rotated to develop high erosion and to shorten the test periods. Fused silica and boron nitride specimens showed the excellent erosion and thermal shock resistance irrespective of the kind of melt and melting atmosphere.

Synthesis and Characterization of Titanoalumino Silicalite (티타노알루미노 실리카라이트의 합성 및 특성연구)

  • Ko, Yong-Sig;Kim, Sang-Min
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.11 no.1
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    • pp.53-58
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    • 2005
  • Titanoalumino silicalite (TAS) was prepared hydrothermally, and the effects of synthesis parameters such as silica/alumina sources, $SiO_2/TiO_2$ ratio, and aging treatment were investigated. The structure, crystal size, and shape were examined by XRD and SEM, and the extent of titanium incorporation into the zeolite framework was examined using UV-vis DRS spectroscopy. For TAS preparation, aging of ca. 24h was essential, and the faster crystallization rates were achieved with Cab-O-Sil than with Ludox or TEOS as a silica source. In addition, the higher crystallinity and faster crystallization rate were obtained using sodium aluminate as an aluminum source.

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Preparation of the Mullite Fiber from Alkoxide by Sol-Gel Process (알콕사이드로부터 졸겔법에 의한 물라이트 섬유의 제조)

  • 김구대;정형진;이해욱
    • Journal of the Korean Ceramic Society
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    • v.28 no.2
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    • pp.153-159
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    • 1991
  • Polymeric alumina sol and polymeric silica sol were synthesized from aluminum sec-butoxide and tetraethyl orthosilicate, respectively as starting materials. A clear mullite sol was obtained by mixing these sols. When the mullite sol had a proper viscosity which was dependent on drying time, the fibers were fabricated by spinning. The optimum viscosity for fabrication of mullite fibers was 103-104 cps, and the fibers with various sizeswere made using the sols. The mullite was a major phase of the calcined fibers and the diameters of the fibers were about 50$\mu\textrm{m}$.

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난연 및 다기능성 복합성형체 제조 및 그 특성

  • 김정훈;강영구;김동현
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2002.05a
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    • pp.65-70
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    • 2002
  • 난연$\cdot$다기능성 복합성형체는 기계부품, 구조물, 차량, 선박, 항공기 및 산업 분야에 널리 사용되고 있다. 안전성이 확보된 신소재 개발의 일환으로서 본 연구진은 난연특성, 정전기 방지특성, 내식특성의 기능성 복합성형체 개발을 수행해 왔으며, 본 연구에서는 Recycled PE, Phenolic resin 및 PPS resin과 같은 재활용 제품에 고기능성을 부여하기 위하여 용도에 따라 alumina, silica, flyash 등의 무기질 filler를 최대 70wt(%) 이상으로 고충진한 복합 폴리머 성형체를 개발하고자 하였다.(중략)

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Chromatographic Techniques for the Isolation and Purification of Metalloporphyrins from Crude Asphalts (크로마토그래피를 이용한 아스팔트로 부터 금속 포르피린의 분리및 정제)

  • Woo Ki Chae
    • Journal of the Korean Chemical Society
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    • v.28 no.6
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    • pp.393-398
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    • 1984
  • Porphyrin-rich materials were obtained from some crude asphalts by gel permeation chromatography and silica gel chromatography. After extraction of each chromatographic fractions through alumina with pyridine, more concentrated metalloporphyrins were obtained. Demetallation of metalloporphyrins was possible without destroying porphyrin ring to provide different type of metal free porphyrins.

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Preparation of Silica Membrane by CVD of Phenyl-Substituted Methoxysilane and $CO_2$ Separation (페닐기로 치환된 Methoxysilane의 CVD에 의한 실리카 분리막의 제조 및 $CO_2$ 분리)

  • Kim, Seong-Su;Seo, Bong-Guk;Lee, Yun-Bok;Park, Hong-Chae;Kim, Tae-Ok
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.622-624
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    • 2001
  • The CVD film of methoxysilane derived from diphenyldimethoxysilane(DPDMS) was formed on the outer surface of a porous ${\alpha}-alumina$ support tube coated(via dipping-drying-calcining) with a boehmite sol(0.3 mol-Al/L). The resulting silica membrane($500^{\circ}C,\;P_{fe}\;=\;130\;Pa$) showed a permeance of $5.18{\times}10^{-8}\;mol\;{\cdot}\;m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}\;for\;CO_2$ and a permselectivity of 13.35 for $CO_2/N_2\;at\;30^{\circ}C$.

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Effect of Fine Alumina Filler Addition on the Thermal Conductivity of Non-conductive Paste (NCP) for Multi Flip Chip Bonding (멀티 플립칩 본딩용 비전도성 접착제(NCP)의 열전도도에 미치는 미세 알루미나 필러의 첨가 영향)

  • Jung, Da-Hoon;Lim, Da-Eun;Lee, So-Jeong;Ko, Yong-Ho;Kim, Jun-Ki
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.2
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    • pp.11-15
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    • 2017
  • As the heat dissipation problem is increased in 3D multi flip chip packages, an improvement of thermal conductivity in bonding interfaces is required. In this study, the effect of alumina filler addition was investigated in non-conductive paste(NCP). The fine alumina filler having average particles size of 400 nm for the fine pitch interconnection was used. As the alumina filler content was increased from 0 to 60 wt%, the thermal conductivity of the cured product was increased up to 0.654 W/mK at 60 wt%. It was higher value than 0.501 W/mK which was reported for the same amount of silica. It was also found out that the addition of fine sized alumina filler resulted in the smaller decrease in thermal conductivity than the larger sized particles. The viscosity of NCP with alumina addition was increased sharply at the level of 40 wt%. It was due to the increase of the interaction between the filler particles according to the finer particle size. In order to achieve the appropriate viscosity and excellent thermal conductivity with fine alumina fillers, the highly efficient dispersion process was considered to be important.

Electrical properties of n-type $WO_{3}$ based gas sensors (N-형 $WO_{3}$계 가스센서의 전기적 특성)

  • Yang, Jong-In;Kim, Il-Jin;Lim, Han-Jo;Han, Sang-Do;Chung, Kwan-Soo
    • Journal of Sensor Science and Technology
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    • v.7 no.3
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    • pp.188-196
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    • 1998
  • The sensing and electrical characteristics of $WO_{3}$-based n-type semiconductor gas sensors are investigated. In normal air condition, $TiO_{2}$(4 wt. %)-doped $WO_{3}$-based sensor fabricated without any binder shows the grain boundary ( GB ) potential barrier height of 0.26 V. Sensors fabricated with alumina, PVA and silica sol binders show 0.17, 0.22 and 0.26 V of GB potential barrier height, respectively. In the ambience of 120 ppm $NO_{x}$ concentration, the GB potential barrier height of the sensor fablicated without binder is increased to 0.59 V. The sensors were fabricated with alumina, PVA, silica sol binders show 0.43, 0.66 and 0.52 V of potential barrier, respectively. Thus the variation of the potential barrier at GB is largest in the sensor fabricated with the PVA binder. This is found to be the main reason why the sensor fabricated with the PVA binder shows the best sensitivity. It is also found that the decrease of sensitivity at a temperature higher than the optimum operation temperature is due to the temperature dependence of the sensor resistance in normal air condition rather than the desorption of the adsorbed $NO_{x}$ gas particles. In the ambience of 250 ppm CO concentration, the GB potential barrier heights of the sensors fabricated without binder and with PVA binder are about 0.2 V showing negligible change compared to the case of normal air ambience. This fact indicates that these sensors are good candidates for the selective detection of $NO_{x}$ gas in the mixture of CO and $NO_{x}$ gases.

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Synthesis of Kaolinitic Clay Mineral from Amorphous Alumino-Silicate by Hydrothermal Process (비정질 Alumino-Silicate로부터 수열반응에 의한 Kaolinite질 인공점토의 합성에 관한 연구)

  • 김남일;박계혁;정창주
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.1076-1086
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    • 1994
  • This study covers synthetic effect of the various hydrothermal treatments on formation of artificially made kaolinite mineral. The hydrothermal treatment includes the temperature treatment with time duration, addition of seeds, particle size of the starting material used, pH variation and the different types of organic acids. A colloidal silica and alumina sol which are commercially available are used for this study. A colloidal silica and alumina sol are mixed by the atomic ratio of Al/Si = 1, based on the theoretical kaolinite composition and calcined at $600^{\circ}C$ for 8 hours duration. It was found that the kaolinitic clay mineral was well developed; thereby, the different patterns of crystalline mineral are appeared. Spherical type as a crystal form was distinctively formed at the temperature of 20$0^{\circ}C$ to 25$0^{\circ}C$ with short duration time, while platy type as a crystal was highly yielded at 300~35$0^{\circ}C$. Moreover, by adding more than 20 wt% of seed as the natural kaolinitic clay to the starting material is widely distributed and developed when 2 ${\mu}{\textrm}{m}$ or less particle size of the starting material is used; also, when they are heat-treated at the temperature of 25$0^{\circ}C$ with 5 hours duration. With respect of the effect of pH variation on formation of the synthetic kaolinite minerals, the crystalline minerals are highly yielded at less than pH 2 and gradually diminished at more than pH9. Regarding to the effect of different acids on development of the kaolinite mineral, the organic acids with high chelating capacity produces good formation of crystalline minerals; whereas, amine radical-(NH2) is not an effective agent to generate the crystalline minerals.

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