• Journal of the Korea Concrete Institute
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• v.24 no.4
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• pp.481-490
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• 2012

Evaluation of chloride penetration is very important, because induced chloride ion causes corrosion in embedded steel. Diffusion coefficient obtained from rapid chloride penetration test is currently used, however this method cannot provide a correct prediction of chloride content since it shows only ion migration velocity in electrical field. Apparent diffusion coefficient of chloride ion based on simple Fick's Law can provide a total chloride penetration magnitude to engineers. This study proposes an analysis technique to predict chloride penetration using apparent diffusion coefficient of chloride ion from neural network (NN) algorithm and time-dependent diffusion phenomena. For this work, thirty mix proportions with the related diffusion coefficients are studied. The components of mix proportions such as w/b ratio, unit content of cement, slag, fly ash, silica fume, and fine/coarse aggregate are selected as neurons, then learning for apparent diffusion coefficient is trained. Considering time-dependent diffusion coefficient based on Fick's Law, the technique for chloride penetration analysis is proposed. The applicability of the technique is verified through test results from short, long term submerged test, and field investigations. The proposed technique can be improved through NN learning-training based on the acquisition of various mix proportions and the related diffusion coefficients of chloride ion.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.7
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• pp.4960-4968
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• 2015

In this study to improve the chloride durability of the shotcrete structure depending on types and contents of mineral admixture chloride resistance was evaluated by NT BUILD 492 of european test standards. It was also evaluated with the mechanical properties such as static strength and chloride penetration resistance. For shotcrete mixed crushed stone aggregate of the maximum size 10mm of coarse aggregates was produced. Based on 28days compression strength the variable mixed with 15% silica fume showed the highest strength in 67.55MPa. As the content of fly ash and blast furnace slag increased, the strength lowered. In the chloride penetration resistance test, OPC showed "high grade" and In the case of admixture, the penetration resistance tended to increase in all variables except the fly ash. In order to evaluate the service life, the accelerated chloride penetration test was conducted by the standards of KCL, ACI, FIB. Test results were obtained with the lowest spreading factor in a variable mixed with silica fume of 15%. At the KCI standards, It was found to have a service life of about 65 years and at the FIB standards, It was found to have a service life of 131 years. Among standards, the service life of KCI standard in all of the variables was evaluated as the lowest.

• Journal of the Korea Concrete Institute
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• v.19 no.4
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• pp.499-506
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• 2007

According to the high demand of concrete structures with high performance, various studies have examined on the high performance concrete, especially high strength concrete. Various admixtures are required to produce high strength concrete and silica fume has been the most popular admixture. Recently, however, metakaolin, which is similar to silica fume in properties but cheaper, has been introduced to high strength concrete. In this study, high-strength concrete using metakaolin were studied of capillary pore structure by mercury intrusion porosimetry technique and the accelerated chloride diffusivity by electrical difference. In result, it was found that the pore structure improved and compressive strength increased and chloride diffusivity reduced as more metakaolin content was added. In addition, a regression analysis of $5{\sim}2,000nm$ pore volume and both compression strength and chloride diffusivity revealed that each these had a high correlation of about 0.76 and 0.68.

• Korean Journal of Veterinary Research
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• v.32 no.3
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• pp.413-419
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• 1992

Deoxynivalenol producing isolates of Fusarium Graminearum R 6576 was grown on rice for 25 days at 19,25 and $28^{\circ}C$. Maximum production of deoxynivalenol(DON) by Fusarium graminearum R 6575 occurred at $28^{\circ}C$ and 20 days. Maximum concentration of 940 ppm DON were obtained after 20 days at an initial moisture content of 40%. A DON derivative, 15-acetyl-DON (15-ADON), was also found at concentrations of 150~300ppm after 5~10 days. Crude culture extracts were purified by water-saturated silica gel column chromatography which selectivity extracted DON when methylene chloride was as the mobile phase. Purity of crystallized DON was verified by thin layer and high performance liquid chromatography. Also this method was advantage method or production of DON and require little organic sorbent than the other methods.

• Journal of The Korean Society of Agricultural Engineers
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• v.47 no.3
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• pp.41-48
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• 2005

The purpose of this study is to improve the performance of jet set cement, which mixed with the mineral admixtures such as silica fume, fly ash and ground granulated blast furnace slag. First, the test of mortar according to the substitute ratio of mineral admixtures were evaluated. And then using it obtained from test results, it was conducted with experiment of mechanical, physical and permeable characteristics of concrete. Laboratory test results showed that concrete substituted for $5\%$ of silica fume didn't have an effect on prominent performance relating to compressive strength. However it was superior to concrete in case of resistance of chloride permeation.

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.1
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• pp.66-73
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• 2014

Currently many researches have been performed for enhancing durability of concrete. Rice husk ash has several advantages like early strength of concrete and dense pore structure. A calcium silicate hydrate (CSH) gel around the cement particles due to pozzolanic reaction of rice husk can increase the strength of concrete against cracking. Very limitedly a systematic and detailed investigation on the corrosion performance of rice husk ash and silica fume blended concrete is performed. A realistic approach has been made through compressive strength, bond strength, and split tensile strength etc. Corrosion performance was also evaluated rapid chloride ion penetration test (RCPT) and impressed voltage test, and the results were discussed in the paper.

• Bulletin of the Korean Chemical Society
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• v.30 no.10
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• pp.2419-2421
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• 2009

A simple and efficient method has been developed for Knoevenagel condensation between aldehydes or ketones and active methylene group by stirring in methylene chloride at 60 ${^{\circ}C}$ under heterogeneous conditions using silica supported ammonium acetate. The products are obtained in excellent yields and are in a state of high purity. The structures of the products were confirmed by IR, $^1H$ NMR and mass spectral data and comparison with authentic samples available commercially.

• Magazine of the Korea Concrete Institute
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• v.10 no.5
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• pp.129-137
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• 1998

본 연구에서는 해수 및 염화나트륨이 공급되는 환경에서 실리카 흄의 알칼리실리카 반응에 대한 억제효과를 구명한 것이다. 연구에 사용된 염화나트륨 농도는 2.8%, 10%, 20%여Tdmaum 반응성 골재는 일본산 안산암이었다. 실리카 흄은 노르웨이산으로 비표면적인 20$m^2$/g인 것을 사용했다. 실리카 흄의 치환율은 시멘트 중량에 대해 5%, 7%, 10%로 하였다. 연구결과, 20%의 염화나트륨이 공급되는 환경에서 알칼리실리카반응에 의한 유해한 팽창이 억제는 본 연구에서 사용된 실리카 흄의 경우, 치환율 % 이상에서 달성되었다.

• Bulletin of the Korean Chemical Society
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• v.16 no.6
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• pp.507-511
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• 1995

Catalytic chlorination of chlorobenzene was studied in vapor phase using various solid-acid catalysts such as silica-alumina, alumina, zeolite and a modified clay prepared by impregnating bentonite with ferric chloride. The conversions of both chlorine gas and chlorobenzene showed high over silica-alumina, alumina and modified clay catalysts. However relatively large amounts of polychlorinated benzene derivatives were also observed. The active species of catalytic activity in chlorination of chlorobenzene in vapor phase were proved to be as Lewis acid sites by in-situ IR experiments. The strength of Lewis acid sites which were effective for the vapor-phase chlorination seemed to be having Hammett acidity Ho >-3.0. The selectivity to dichlorobenzenes was proved to be high over the zeolite catalyst due to their shape-selective properties. p-Dichlorobenzene or dichlorobenzene selectivities were improved more or less by changing the reaction conditions.

• Journal of the Korea Concrete Institute
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• v.17 no.5 s.89
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• pp.743-750
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• 2005

High performance concrete containing silica fume for use in bridge deck overlay emerged as a viable type of bridge deck overlay that economic advantage in construction. They have gained acceptance in Europe, America and Canada in a relatively short time due to their low cost. In this study, high-performance concretes containing silica fume were tested and evaluated in the laboratory to assess their applicability for use in bridge deck overlay. It was conducted with experiments of mechanical and durability characteristics in compressive strength, flexural strength, chloride permeability, abrasion resistance, repeated freezing and thawing cycles and deicing salt scaling resistance. Laboratory test result describe that high-performance concrete containing silica fume for bridge deck overlay application shows most outstanding capacity.