• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.781-786
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• 2001

The Salt attack is one of the primary factors that cause the deterioration of durability in steel reinforced concrete structure. And to depreciate the deterioration from the Salt attack in concrete structure, pozzolanic materials are used widely in recent years. In this study, experiments about the resistance of chloride infiltration of concrete according to the replacement rations of Activated Hwangtoh and various pozzolanic materials(silica fume, fly ash, blast furnace slag and non Activated/Activated Hwangtoh) are performed and the results of this study were shown as follows; 1) As the replacement ratios of Activated Hwangtoh were getting higher, the strength of concrete was increased and in case of various pozzolanic materials, strength of Activated Hwangtoh in specimen was better than that of fly ash, blast furnace slag and non Activated Hwangtoh. 2) As the replacement ratios of Activated Hwangtoh were getting higher, the resistance of chloride infiltration of concrete was increased and in case of various pozzolanic materials, silica fume is better than any other pozzolanic materials and Activated Hwangtoh was better than that of fly ash, blast furnace slag and non Activated Hwangtoh.

• International Journal of Concrete Structures and Materials
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• v.8 no.4
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• pp.301-307
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• 2014

Rice husk ash (RHA) is classified as a highly reactive pozzolan. It has a very high silica content similar to that of silica fume (SF). Using less-expensive and locally available RHA as a mineral admixture in concrete brings ample benefits to the costs, the technical properties of concrete as well as to the environment. An experimental study of the effect of RHA blending on workability, strength and durability of high performance fine-grained concrete (HPFGC) is presented. The results show that the addition of RHA to HPFGC improved significantly compressive strength, splitting tensile strength and chloride penetration resistance. Interestingly, the ratio of compressive strength to splitting tensile strength of HPFGC was lower than that of ordinary concrete, especially for the concrete made with 20 % RHA. Compressive strength and splitting tensile strength of HPFGC containing RHA was similar and slightly higher, respectively, than for HPFGC containing SF. Chloride penetration resistance of HPFGC containing 10-15 % RHA was comparable with that of HPFGC containing 10 % SF.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2003.11a
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• pp.43-48
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• 2003

This paper investigate that the effect of the concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for 3~4 replacement ratios under W/B ratios ranged from 0.40 to 0.55. For the electrical migration test, Tang and Nilsson's method was used to estimate the migration coefficient of chloride ion. As a results, the W/B ratios, kinds of admixture and replacement ratios, water curing periods had a great effect on the migration coefficient of chloride ion, and the optimal replacement ratios of admixture had a limitation for each admixtures. Also, the addition of mineral admixtures by mass(replacement of OPC) enhanced the resistance of the mixture to chloride penetration compared with the plain concrete. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures. The compressive strength was shown related to the migration coefficient of chloride ion, the compressive strength increased with the decreasing migration coefficient of chloride ion. Below the 50MPa, the variation of migration coefficient of concrete added mineral admixtures was bigger than plain concrete.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2003.05a
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• pp.43-48
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• 2003

This paper investigate that the effect of the concrete containing mineral admixtures(pozzaolanic materials such as fly-ash, ground granulated blast-furnace slag, silica fume and meta kaolin) on the resistance properties to chloride ion invasion. The purposed testing procedure was applied to the concrete added mineral admixtures for 3∼4 replacement ratios under W/B ratios ranged from 0.40 to 0.55. For the electrical migration test, Tang and Nilsson's method was used to estimate the migration coefficient of chloride ion. As a results, the W/B ratios, kinds of admixture and replacement ratios, water curing periods had a great effect on the migration coefficient of chloride ion, and the optimal replacement ratios of admixture had a limitation for each admixtures. Also, the addition of mineral admixtures by mass(replacement of OPC) enhanced the resistance of the mixture to chloride penetration compared with the plain concrete. The amount of acid soluble chloride ions and water soluble chloride ions were varied with the kinds of mineral admixtures. The compressive strength was shown related to the migration coefficient of chloride ion, the compressive strength increased with the decreasing migration coefficient of chloride ion. Below the 50MPa, the variation of migration coefficient of concrete added mineral admixtures was bigger than plain concrete.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.89-96
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• 2023

In this paper, a ferrosilicon by-product was evaluated to confirm the feasibility of recycling it as supplementary cementitious material of ordinary Portland cement in concrete. Three different levels of replacement ratio (10 %, 20 % and 30 % of total binder) were applied to find which is the most beneficial to be used as a binder. Ferrosilicon concrete was initially assessed at setting time and compressive strength. Durability was evaluated by the resistance to chloride penetration test(RCPT) and alkali-silica reaction(ASR) with a comparison to silica fume concrete due to their similarity in chemical composition. The porosimetry and X-ray diffraction analysis along with energy dispersive X-ray spectroscopy give information on the microstructural characteristics of the ferrosilicon concrete. It was found that 10 % ferrosilicon concrete has higher strength while 20 %, 30 % have lower strength than OPC concrete. However, chemical resistance to chloride attack is higher when replacement is increased. Compared to silica fume, the durability of ferrosilicon might be less efficient however, it is obviously beneficial than OPC. High SiO₂ content in ferrosilicon results in producing more C-S-H gel which could make denser pore structure. Most of the risk of alkali silica reaction to silicate binders through length change tests was less than 0.2 %, and both mortar using ferrosilicon and silica fume showed better resistance to alkali silica reaction as the substitution rate increased.Reuse of industrial waste rather than producing highly refined additives might reduce environmental load during manufacture and save costs.

• Advances in concrete construction
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• v.6 no.2
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• pp.145-157
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• 2018

This paper presents a review on the use of Silica Fume (SF) as a mineral admixture in the concrete. Distinctive outcome from several researches have been demonstrated here, particularly emphasizing on the fresh and hardened properties of concrete when blended with Silica Fume (Micro-silica or Nano-silica). The results showed a substantial enhancement in the mechanical properties of concrete when replaced with SF. The review also presented a brief idea of percentage replacement of SF in case of normal and high-strength concrete. A decreasing trend in workability (slump value) has been identified when there is a increase in percentage replacement of SF. It can be concluded that the optimize percentage of replacement with SF lies in the range of 8-10% particularly for compressive strength. However the variation of blending goes up to 12-15% in case of split tensile and flexure strength of concrete. The study also demonstrates the effect of silica fume on durability parameters like water absorption, permeability, sulphate attack and chloride attack.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.531-536
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• 2002

Silica fume influences concrete diffusivity and permeability as well as strength by densifying the microstructure of the interfacial transition zone (ITZ) of high strength concrete, by reducing the capillary porosity of cement paste and by producing less diffusible and permeable pozzolanic CSH gel than CSH gel of conventional cement hydration. This paper presents a procedure to predict the chloride ion diffusivity and water permeability of the high strength concrete containing silica fume. Water binder ratio, silica fume addition, degree of hydration and volume fraction of aggregates are considered as the major factors influencing concrete diffusivity and permeability in the procedure. Analytical results using the procedure are shown and verified with other data.

• Elastomers and Composites
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• v.55 no.4
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• pp.277-280
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• 2020

In this study, mesoporous hollow silica spheres were synthesized using a polystyrene core and cetyltriammonium chloride (CTACl) as a pore template, and a low-cost water glass instead of expensive tetraethyl orthosilicate (TEOS) as a precursor. In addition, the material was synthesized by varying the concentration of polystyrene. Later, the polystyrene core and CTACl were removed by firing in a high-temperature heat-treatment process. The synthesized product was analyzed by various methods, such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffractometry (XRD), and N2-sorption analysis. It was confirmed that the hollow silica sphere had a hexagonal structure with a Brunauer-Emmett-Teller (BET) specific area of 1623 ㎡/g.

• Advances in concrete construction
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• v.7 no.3
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• pp.143-150
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• 2019

This study presents the fracture properties of nano modified medium strength concrete (MSC). The nano particle used in this study is nano silica which replaces cement about 1 and 2% by weight, and the micro steel fibers are added about 0.4% volume of concrete. In addition to fracture properties, mechanical properties, namely, compressive strength, split tensile strength, and flexural strength of nano modified MSC are studied. To ensure the durability of the MSC, durability studies such as rapid chloride penetration test, sorptivity test, and water absorption test have been carried out for the nano modified MSC. From the study, it is observed that significant performance improvement in nano modified MSC in terms of strength and durability which could be attributed due to the addition pozzolanic reaction and the filler effect of nano silica. The incorporation of nano silica increases the fracture energy about 30% for mix without nano silica. Also, size independent fracture energy is arrived using two popular methods, namely, RILEM work of fracture method with $P-{\delta}$ tail correction and boundary effect method. Both the methods resulted in nearly the same size-independent $G_F$ irrespective of the notch to depth ratio of the same specimen. This shows evidence that either of the two procedures could be used in practice for analysis of cracked concrete structures.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.58-61
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• 2003

This paper investigated the chloride invasion resistance properties of concrete containing mineral admixtures(pozzolanic materials such as fly-ash, ground granulated blast-furnace slage, silica fume and meta kaolin) for each replacement ratios under W/B ratios ranged from 40% to 55%. For the electrical migration test, Tang and Nilsson's method was used to estimate the migration coefficient of chloride ion. As a result, the migration coefficients of chloride ion of concrete containing mineral admixtures were shown reducing with the use of mineral admixtures, and the compressive strength was shown related to the migration coefficient. From the correlation between compressive strengths and migration coefficients, the kind and replacement ratio of mineral admixtures have a great effect on migration coefficients below 50㎫.