• 제목/요약/키워드: Si infiltration

검색결과 176건 처리시간 0.028초

A study of improving filtration efficiency through SiC whisker synthesis on carbon felt by CVD VS method

  • 김광주;최두진
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.150-150
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    • 2016
  • Mankind is enjoying a great convenience of their life by the rapid growth of secondary industry since the Industrial Revolution and it is possible due to the invention of huge power such as engine. The automobile which plays the important role of industrial development and human movement is powered by the Engine Module, and especially Diesel engine is widely used because of mechanical durability and energy efficiency. The main work mechanism of the Diesel engine is composed of inhalation of the organic material (coal, oil, etc.), combustion, explosion and exhaust Cycle process then the carbon compound emissions during the last exhaust process are essential which is known as the major causes of air pollution issues in recent years. In particular, COx, called carbon oxide compound which is composed of a very small size of the particles from several ten to hundred nano meter and they exist as a suspension in the atmosphere. These Diesel particles can be accumulated at the respiratory organs and cause many serious diseases. In order to compensate for the weak point of such a Diesel Engine, the DPF(Diesel Particulate Filter) post-cleaning equipment has been used and it mainly consists of ceramic materials(SiC, Cordierite etc) because of the necessity for the engine system durability on the exposure of high temperature, high pressure and chemical harsh environmental. Ceramic Material filter, but it remains a lot of problems yet, such as limitations of collecting very small particles below micro size, high cost due to difficulties of manufacturing process and low fuel consumption efficiency due to back pressure increase by the small pore structure. This study is to test the possibility of new structure by direct infiltration of SiC Whisker on Carbon felt as the next generation filter and this new filter is expected to improve the above various problems of the Ceramic DPF currently in use and reduction of the cost simultaneously. In this experiment, non-catalytic VS CVD (Vapor-Solid Chemical Vaporized Deposition) system was adopted to keep high mechanical properties of SiC and MTS (Methyl-Trichloro-Silane) gas used as source and H2 gas used as dilute gas. From this, the suitable whisker growth for high performance filter was observed depending on each deposition conditions change (input gas ratio, temperature, mass flow rate etc.).

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전로용 MgO-C질 내화벽돌의 손상요인 (Wear Mechanisum of Carbon Bearing BOF Refreactories)

  • 김의훈;오영우;이철수;김종성;김종희
    • 한국세라믹학회지
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    • 제23권1호
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    • pp.51-59
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    • 1986
  • It was the first time the MgO-C brick was developed for the lining materials in the hot spots in electric are furnace in 1972. MgO-C brick is high registant to thermal and structural spalling. Futhermore for the reason that carbon is hard to react with slag and MgO is high fireproof MgO-C brick shows a high corrosion registance to slag attack compared with conventional basic refractories. Owing to their excellent properties the use of MgO-C refractories are being developed widely in the field of shaped refractories and even in that of monolithic refractories. In this paper the oxidation of carbon the infiltration of slag into the brick texture and effects of additions were investigated. The results obtained were as follows : 1) The use of fused MgO-clinker and high purity carbon as raw materials increased the corosion registance and hot modulus of rupture of MgO-C brick. 2) As the oxidation reaction of the carbon proceeded the slag infiltrated into the brick texture. And then the slag components reacted with the MgO grains and formed low melting point compounds particulary CaO.MgO.$SiO_2$ and 3CaO.MgO.$2SiO_2$ that resulted in the wear of the brick. 3) It is recongnized the Al, Si, $B_3C$ effects on the oxidation registant properties of MgO-C brick by contribu-ting to the decrease of permeability according to the formation of $Al_4C_3$, SiC, $B_2O_3$ and the decrease of open pores relating to the formation of MgO.Al2O3, $SiO_2$, 3MgO.$B_2O_3$ at the decarbonized layer.

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로켓 노즐목 소재 C/SiC 복합재 고온 파괴 특성 (Fracture Characteristics of C/SiC Composites for Rocket Nozzle at Elevated Temperature)

  • 윤동현;이정원;김재훈;신인철;임병주
    • 대한기계학회논문집A
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    • 제40권11호
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    • pp.927-933
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    • 2016
  • 고체 추진 기관에서 로켓 노즐은 고온 연소가스에 노출된다. 따라서 고온에서 기능을 발휘할 수 있는 적절한 재료의 선택이 중요하다. 탄소 섬유 강화 실리콘 카바이드 복합재(C/SiC)가 로켓 노즉목에 적용을 위해 연구되어 왔다. 그러나 전형적인 구조 재료들과 비교할 때 C/SiC 복합재는 준취성 거동을 가지고 고온에서 산화의 영향으로 인해 강도와 인성 관점에서 상대적으로 취약한 점이 있다. 그러므로 실제 적용을 위해 C/SiC 복합재의 열, 기계적인 특성을 평가하는 것은 중요하다. 본 논문에서는 액화 실리콘 용침(LSI) 공정을 통해 만들어진 C/SiC 복합재의 고온에서의 파괴 거동을 조사하는 실험적인 방법을 설명한다. 특히 온도와 하중, 산화 조건 그리고 탄소 섬유의 방향을 주요 변수로 설정하여 파괴 특성을 조사하였다. 파단면 분석은 SEM 촬영을 통하여 수행하였다.

SiOC 매트(Mat)를 이용한 열전지용 전해질 격리판 제조 및 특성 (Properties of the Electrolyte Separators for Thermal Batteries Using SiOC Mat)

  • 임경훈;조광연;류도형;신동근;진은주;김현이;정해원;이홍림
    • 한국세라믹학회지
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    • 제46권6호
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    • pp.648-652
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    • 2009
  • Ceramic fiber separator is the promising material for thermal battery system because it reduces the production cost and offers the potential to a new application compared to a pellet type electrolyte. The electrolyte separator for thermal battery should be easily handled and loaded a large amount of the molten lithium salt. Ceramic fibers were used as an electrolyte separator and the lithium based molten salts were infiltrated into the ceramic filters. Leakage of molten salt (several lithium salts) leads to short-circuit during the thermal battery operation. In this study, a uniform and fine SiOC mat with fibers ranging from 1 to 3 ${\mu}m$ was obtained by electrospinning of polycarbosilane and pyrolysis. The optimum spinning conditions for obtaining fine diameters of SiOC fiber were controlled by the solution composition and concentration, applied voltage and spinning rate, release rate by porosity. The pore structures of the ceramic filter and the melting properties of the lithium salts affected to the electrolyte loading and leakage. The importance of the fiber size and porosity and their control was discussed and the mechanical properties were also discussed.

튜브형상 반응소결 탄화규소 부품의 시편크기에 따른 강도평가 유용성 고찰 (Mechanical Strength Values of Reaction-Bonded-Silicon-Carbide Tubes with Different Sample Size)

  • 김성원;이소율;오윤석;이성민;한윤수;신현익;김영석
    • 한국분말재료학회지
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    • 제24권6호
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    • pp.450-456
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    • 2017
  • Reaction-bonded silicon carbide (RBSC) is a SiC-based composite ceramic fabricated by the infiltration of molten silicon into a skeleton of SiC particles and carbon, in order to manufacture a ceramic body with full density. RBSC has been widely used and studied for many years in the SiC field, because of its relatively low processing temperature for fabrication, easy use in forming components with a near-net shape, and high density, compared with other sintering methods for SiC. A radiant tube is one of the most commonly employed ceramics components when using RBSC materials in industrial fields. In this study, the mechanical strengths of commercial RBSC tubes with different sizes are evaluated using 3-point flexural and C-ring tests. The size scaling law is applied to the obtained mechanical strength values for specimens with different sizes. The discrepancy between the flexural and C-ring strengths is also discussed.

세라믹 디스크의 표면 개질에 따른 마찰 마모 특성 (Tribological Properties of C-SiC Brake Discs with Surface Modifications)

  • 장호;김기정;황희정;김성진;박홍식
    • Tribology and Lubricants
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    • 제24권4호
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    • pp.163-169
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    • 2008
  • Tribological properties of ceramic brake discs were investigated using a commercial friction material. The discs were manufactured by liquid silicon infiltration (LSI) into a C-C preform. The disc surface was modified by two different methods, producing sliding surfaces with chopped carbon fibers and carbon felt. In addition, the composition of the surface was also changed. Friction characteristics of the discs were examined using a 1/5 scale dynamometer. Results showed that the type and composition of the disc surface significantly affected the level of braking effectiveness and high temperature brake performance. The discs with felt surfaces showed higher friction levels than those with chopped fiber surfaces and SiC tended to increase the friction level while C lowered the friction coefficient. The ceramic disc was more sensitive to the deceleration rate than gray iron, showing high speed sensitivity.

Improvement of Pneumonia in a Patient with Non-Small Cell Lung Cancer Treated with Herbal Medicine after Cessation of Antibiotics - a Case Report

  • Song, Si Yeon;Jeon, Hyeonjin;Lee, Sookyung
    • 대한한의학회지
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    • 제38권2호
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    • pp.78-84
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    • 2017
  • A 73-year-old non-small cell lung cancer (NSCLC) patient admitted due to cough, sputum, and dyspnea, aggravated a week ago. She was diagnosed as pneumonia based on the assessment of inflammation markers, chest X-ray and sputum culture. Computed tomography (CT) scan was conducted to exclude malignant tumor metastasis. At the initiation of treatment, considering underlying disease and inflammation marker level, herbal medicine and antibiotics were concurrently used and antibiotics had been discontinued after 10days. Using the monotherapy of herbal medicine in the next 6 days, chest X-ray showed remarkably decreased infiltration in right middle lung and right lower lung. This case represented additional improvement of chest X-ray when treated only with herb medicine after termination of antibiotic therapy and demonstrated the possibility of applying herbal medicine in patients with limited use of antibiotics.

자카스펭귄에서 Aeromonas hydrophilia 감염증 (Aeromonas hydrophilia infection in Jackass Penguins (Spheniscus demersus))

  • 김규태;조성환;손화영;류시윤
    • 대한수의학회지
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    • 제45권3호
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    • pp.381-385
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    • 2005
  • Aeromonas hydrophilia infection was diagnosed in captive Jackass penguins (Spheniscus demersus). Seven Jackass penguins showed clinical signs including depression and anorexia with greenish vomiting, but four penguins were died although extensive treatment was carried out. At necropsy, the penguins appeared to have hemorrhage and catarrhal inflammation of the small and large intestines and severe enlargement of the right hepatic lobe, elongation of the gall bladder and pyloric ulceration of the stomach. The ovaries observed atrophy and congestion. Microscopically, there were congestion, fat droplet within the cytoplasm of the hepatic cell, infiltration of lymphocytes in the stomach, vilous detachment and destroyed glandular epithelium in the small and large intestines. Aeromonas hydrophilia was isolated from the liver and small intestines. This case is the first report of an occurrence of Aeromonas hydrophilia infection at Jackass penguins in Korea.

고주파수 초음파 검출장에서 SiC 세라믹 내부의 미세결함 검출 (Detection of Small Flaws in SiC Structural Ceramic in High Frequency Detection Field)

  • 김병극;이승석
    • 비파괴검사학회지
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    • 제17권2호
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    • pp.100-107
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    • 1997
  • 파괴역학적 고려에 의하여 구조용 세라믹에서 $100{\mu}m$보다 작은 크기의 결함을 검출하는 것이 요구되고 있다. 미세결함이 삽입된 세라믹 시편을 준비하여 고주파수 검출장에서 C-scan을 수행하였다. 두께 4m의 SiC 세라믹 시편들을 입도가 $100{\mu}m$에서 $200{\mu}m$ 범위의 Fe, 입도 $36{\mu}m$에서 $50{\mu}m$ 범위의 Fe와 $50{\mu}m$ 크기의 pore를 용침법(infiltration)으로 삽입하여 준비하였고 또 입도 $100{\mu}m$에서 $200{\mu}m$ 범위의 WC, 입도 $36{\mu}m$에서 $50{\mu}m$ 범위의 WC, 입도 $100{\mu}m$에서 $200{\mu}m$ 범위의 Si, 입도 $36{\mu}m$에서 $50{\mu}m$ 범위의 Si 입자들을 소결법(sintering)으로 삽입하여 준비하였다. 준비된 시편에 대해 중심주파수 80MHz의 polyvinylidene fluoride(PVDF) 초음파탐촉자를 사용하여 C-scan을 수행한 결과 100MHz 범위까지의 고주파수 성분을 지닌 검출장에서는 $36{\mu}m$에서 $200{\mu}m$ 범위의 미세결함들이 검출되었으나 60MHz 이하의 주파수 성분만으로 구성된 저주파수 검출장에서는 검출되지 않았다. 중심 주파수에서의 파장에 대하여 검출된 최소 결함의 비는 약 0.25로 Rayleigh 산란 영역이었다.

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액상 실리콘 침투법으로 제작된 대구경 위성 망원경용 SiC 반사경의 결함 검사와 물성 계수 측정 (Defect Inspection and Physical-parameter Measurement for Silicon Carbide Large-aperture Optical Satellite Telescope Mirrors Made by the Liquid-silicon Infiltration Method)

  • 배종인;김정원;이행복;김명훈
    • 한국광학회지
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    • 제33권5호
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    • pp.218-229
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    • 2022
  • 실리콘 카바이드(SiC) 소재를 이용해서 위성용 대구경 망원경의 경량 반사경을 제작하는 과정에서 발생할 수 있는 결함과 SiC 소재의 기계 및 열적 특성을 조사했다. SiC 반사경 제작에는 advanced ceramic material (ACM) 공법이라고 불리는 탄소성형체를 이용한 액상 실리콘 침투 소결법 및 화학기상 증착법이 사용되었으며, 크기와 형상이 다른 네 가지 SiC 반사경을 개발했다. 반사경의 크기 및 형상에 따라 구분하여 광학 소재의 결함을 검사하는 기준과 방법을 체계적으로 제시했고, 경면 표면검사 및 소재 내부 결함 탐지를 위한 비파괴 검사법과 결과에 대해 분석했다. 또한, 반사경을 설계하고, 최종 완성품의 기계적 열적 안정성을 계산하고 예측하기 위해 필요한 밀도, 탄성계수, 비열, 열전달 계수 등을 포함한 14종의 물성 계수 측정값을 공인시험을 통해 추출했으며, 특히 측정 신뢰도 향상을 위해 주요 물성인 탄성계수, 열팽창 계수, 굽힘 강도 측정 방법과 결과에 대해 자세히 연구했다.