• Title/Summary/Keyword: Si Content

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Microstructure and Strength Property of Reaction Sintered SiC Materials (반응소결 SiC 재료의 미세조직 및 강도 특성)

  • LEE SANG-PILL;SHIN YUN-SEOK;LEE JIN-KYUNG
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.380-385
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    • 2004
  • The efficiency of complex slurry preparation route for developing the high performance SiC matrix of RS-SiCf/SiC composites has been investigated. The green bodies for RS-SiC materials prior to the infiltration of nw/ten silicon were prepared with various C/SiC complex matrix slurries, which associated with both different sizes of starting SiC particles and blending ratios of starting SiC and carbon particles. The characterization of RS-SiC materials was examined by means of SEM, TEM, EDS and three point bending test. Based on the mechanical property-microstructure correlation, process optimization methodology is also discussed. The flexural strength of RS-SiC materials greatly depended on the content of residual Si. The decrease of starting SiC particle size in the C/SiC complex slurry was effective for improving the flexural strength of RS-SiC materials.

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The Effects of SiO Gas Barrier Film on the Depositing IZO/Glass Thin Film (IZO/Glass 성막 시 SiO가스배리어막의 영향)

  • Kim, Do-Hyoung;Yoon, Han-Ki;Qiu, Zhiyong;Murakami, Ri-ichi
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.215-219
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    • 2007
  • In this work, the indium zinc oxide (IZO) films had been deposited on the glass substrate coated with the SiO film. Based on a comparative investigation of the IZO monolayer and IZO/SiO multilayer, it is shown that the thickness of SiO film has a great effect on the mechanical properties of the thin films. The AFM images of the IZO thin film included the SiO film were shown smoother surfaces than monolayer. Resistivity was in inverse proportion to Mobility. If it deposited the SiO film on the substrate, the layer of change was generated between two layer(SiO and substrate). The layer of change influenced resistance because of oxygen content was more than the IZO monolayer.

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A study on the wear resistance of Ni-SiC composite plating (Ni-SiC 복합도금층의 내마모성에 관한 연구)

  • 김성호;한혜원;장현구
    • Journal of Surface Science and Engineering
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    • v.29 no.1
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    • pp.26-35
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    • 1996
  • The Ni-SiC composite plating was performed in a Watt nickel solution and the wear resistance of the composite layer was studied on a pin-on-flat type wear tester. The volume losses and friction coefficients were measured. It was found that the quantity of SiC powder in the composite layers was affected by SiC concentration, pH, temperature, and agitation speed in the Watt nickel solution. The hardness and wear resistance of the coatings increased with SiC content. The quantity of SiC powder in the coating from a nickel sulfamate solution is larger than that of the Watt nickel solution, because the amount of nickel ions absorbed on the SiC powder in the nickel sulfamate solution is greater than that in the Watt's solution.

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Mechanical and Tribological Properties of $\beta-Sialon/SiC$ Whisker Composite ($\beta-Sialon/SiC$ Whisker 복합재료의 기계적 물성 및 마찰 마모 특성 연구)

  • 김호균;소유영;김인섭;이병하
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1259-1264
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    • 1994
  • $\beta$-Sialon has been regarded as one of promising materials showing high strength, fracture toughness, corrosion resistence and wear resistence. The improvement of the fracture toughness and tribological properties of $\beta$-Sialon (Z=1) has been attempeted by fabricating the $\beta$-Sialon/ SiC whisker composite. Each of green body composed of following ingredients, i.e., Si3N4, AlN, Y2O3 nd SiC, respectively, was first fired at 178$0^{\circ}C$ for 3hrs in N2 atmosphere and then post-HIPed at 173$0^{\circ}C$ for 1 hr under 170 MPa for N2 gas pressure. The fracture toughness, flexural strength and tribological properties increased with increasing SiC whisker content, despite the reduction of the relative density and hardness. $\beta$-Sialon/15 vol% SiC whisker showed a significant enhancement of wear resistance compared to the monolithic $\beta$-Sialon. The addition of SiC whisker caused the reduction of the density and hardness, but induced the increment of wear resistance.

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Synthesis of SiC by Self-Propagating High Temperature Synthesis Chemical Furnace (SHS화학로에 의한 SiC의 합성)

  • Kim, Do-Kyung;Park, Sung;Cho, Kurn;Lee, Hyung-Bock
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1283-1292
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    • 1994
  • Ultra-fine $\beta$-SiC powders were fabricated by self-propagating high temperature synthesis process (SHS) using chemical furnace. The dependences of the C powders with different surface areas, the molar ratios of C/Si, the weight ratios of chemical fuel content, and pellet diameter-size on synthesis were investigated. Compositional and structural characterization of these powders was carried out by scanning electron micrograph and X-ray diffraction. The $\beta$-SiC powders which had C/Si mole ratio=1.05, 3 times chemical fuel contents, and pellet diameter=20 mm were optimum for synthesis efficiency. By optimizing process-variables, it is possible to fabricate $\beta$-SiC powders which have little secondary phases ($\alpha$-SiC).

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Synthesis and Properties of $Al_2O_3-SiC$ Composites from Alkoxides (알콕사이드로부터 $Al_2O_3-SiC$ 복합재료의 제조 및 특성)

  • 이홍림;김규영
    • Journal of the Korean Ceramic Society
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    • v.30 no.2
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    • pp.123-130
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    • 1993
  • Dispersed type Al2O3-SiC composite powders were synthesized from Al-isopropoxide (Al(i-OC3H7)3) and Si(OC2H5)4 precursors by hydrolysis of mixed alkoxides and carbothermal reaction method. The characteristics of the synthesized (dispersed type) Al2O3-SiC composite powders were investigated using XRD, SEM, TEM, BET and particle size analyzer. Carbothermal reaction to produce Al2O3-SiC composite was completed in 10h at 135$0^{\circ}C$ on 3~4㎤/s (0.21~0.28cm/s) of H2 flow rate and about 1/1 of carbon/oxides(=SiO2+Al2O3) molar ratio. The synthesized powders were observed to have the mean particle size range of 0.4~1.26${\mu}{\textrm}{m}$ and showed finer particle size with increasing SiC content.

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Powder Chracteristics and Sintering Behavior of $SiO_2$ Coated $BaTiO_3$

  • Park, Jae-Sung;Han, Young-Ho
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1097-1098
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    • 2006
  • The Powder characteristics and sintering behavior of $SiO_2$ coated $BaTiO_3$ were studied. Silica coated $BaTiO_3$ powders were prepared by sol-gel method. The particle size of the $BaTiO_3$ powders were $\sim35$ nm and the thickness of the $SiO_2$ coating layer was $\sim5$ nm. As the $SiO_2$ content increased, the $SiO_2$ layers improved the powder dispersion. The Zeta potential of $SiO_2$ coated $BaTiO_3$ was getting close to that of pure silica with a more negative charge, compared with that of the uncoated $BaTiO_3$. The onset temperature of shrinkage curves shifted to higher temperatures with increasing $SiO_2$ contents

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Effect of Water Soluble Silicate on Zoysiagrass Growth (수용성 규산염 시용에 따른 한국잔디의 생육효과)

  • Han, Jeong-Ji;Lee, Kwang-Soo;Park, Yong-Bae;Choi, Su-Min;Yang, Geun-Mo;Bae, Eun-Ji
    • Weed & Turfgrass Science
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    • v.4 no.2
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    • pp.144-150
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    • 2015
  • Silicate fertilizers known to be effective in improving the growth and density of zoysiagrass. Most silicate fertilizers being used in Korea are slag-originated silicate fertilizer, but some water soluble silicate fertilizers are commercially available recently. This study was conducted to know the effect of water soluble silicate fertilizer, on the growth of zoysiagrass and the change of soil chemical properties in Wagner pot and field experiment. Root length, fresh and dry weight of shoots and stolons, the number of shoots and stolons, total of stolons length and the $SiO_2$ content of internal plant were significantly increased by the $SiO_2$ content but chemical properties of the soil were not significantly changed by the $SiO_2$ content. The $SiO_2$ contents of 18 and $36{\mu}lml^{-1}$ did not show significance difference, and therefore a reasonable application the content of $SiO_2$ was thought to be $18{\mu}lml^{-1}$. Foliar spray of water soluble silicate fertilizer is believed to enhance the growth and density of zoysiagrass than soil application.

The Effects of Oxygen Content on Microstructure and Mechanical Properties of Ti-Al-Fe-Si-O alloy (산소함량에 따른 Ti-Al-Fe-Si-O 합금의 기계적 특성 및 미세조직 변화)

  • Bae, Jin Joo;Yeom, Jong Taek;Park, Chan Hee;Hong, Jae Keun;Kim, Senog Woong;Yoon, Seog Young;Lee, Sang Won
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.6
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    • pp.264-271
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    • 2016
  • The effect of the oxygen content and the annealing temperature on the tensile behavior of the Ti-1.5Al-3Fe-0.25Si-(0.1~0.5)O alloy was investigated. The tensile properties were dependent on the volume fraction of the microstructure constituents, i.e. the equixed ${\alpha}$, equixed ${\beta}$ and lamellar ${\alpha}$. The results showed that the O-partitioned equixed ${\alpha}$ had a much higher strength compared to the equixed ${\beta}$. The strength of the lamellar ${\alpha}$ increased with increasing the annealing temperature because the O content of the lamellar ${\alpha}$ increased. Ti-1.5Al-3Fe-0.25Si-0.3O alloy annealed to $900^{\circ}C$ where the volume fraction of lamellar ${\alpha}$ was the highest exhibited an excellent combination of the strength (1198.5 MPa) and ductility (27.5%). The effect of the lamellar ${\alpha}$ on the ductility was discussed.

Effect of Lead Content on Atomic Structures of Pb-bearing Sodium Silicate Glasses: A View from 29Si NMR Spectroscopy (납 함량에 따른 비정질 Pb-Na 규산염의 원자 구조에 대한 고상 핵자기 공명 분광분석 연구)

  • Lee, Seoyoung;Lee, Sung Keun
    • Korean Journal of Mineralogy and Petrology
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    • v.34 no.3
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    • pp.157-167
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    • 2021
  • Lead (Pb) is one of the key trace elements, exhibiting a peculiar partitioning behavior into silicate melts in contact with minerals. Partitioning behaviors of Pb between silicate mineral and melt have been known to depend on melt composition and thus, the atomic structures of corresponding silicate liquids. Despite the importance, detailed structural studies of Pb-bearing silicate melts are still lacking due to experimental difficulties. Here, we explored the effect of lead content on the atomic structures, particularly the evolution of silicate networks in Pb-bearing sodium metasilicate ([(PbO)x(Na2O)1-x]·SiO2) glasses as a model system for trace metal bearing natural silicate melts, using 29Si solid-state nuclear magnetic resonance (NMR) spectroscopy. As the PbO content increases, the 29Si peak widths increase, and the maximum peak positions shift from -76.2, -77.8, -80.3, -81.5, -84.6, to -87.7 ppm with increasing PbO contents of 0, 0.25, 0.5, 0.67, 0.86, and 1, respectively. The 29Si MAS NMR spectra for the glasses were simulated with Gaussian functions for Qn species (SiO4 tetrahedra with n BOs) for providing quantitative resolution. The simulation results reveal the evolution of each Qn species with varying PbO content. Na-endmember Na2SiO3 glass consists of predominant Q2 species together with equal proportions of Q1 and Q3. As Pb replaces Na, the fraction of Q2 species tends to decrease, while those for Q1 and Q3 species increase indicating an increase in disproportionation among Qn species. Simulation results on the 29Si NMR spectrum showed increases in structural disorder and chemical disorder as evidenced by an increase in disproportionation factor with an increase in average cation field strengths of the network modifying cations. Changes in the topological and configurational disorder of the model silicate melt by Pb imply an intrinsic origin of macroscopic properties such as element partitioning behavior.