• Title/Summary/Keyword: Si Content

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The Effect of Plasma Power on the Composition and Microhardness of a-SiC:H Films Grown by PECVD

  • Lee, Young-Ku-K;Kim, Yunsoo
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.123-123
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    • 1999
  • Amorphous hydrogenated silicon carbide (a-SiC:H) films were deposited at the temperature of 40$0^{\circ}C$ using plasma enhanced chemical vapor deposition. The a-SiC:H films were characterized by x-ray photoelectron spectroscopy (XPS) and nanoindentation method. By increasing the plasma power from 20W to 160W, the oxygen content of the a-SiC:H films were observed to decrease from 12.1% to 4.4%. On the other hand, the plasma power did not affect the ratio of carbon to silicon in our experiment where the 1, 3-disilabutane was used as the precursor. Microhardness of the films was observed to increase as the plasma power increased, while the elastic modulus was observed to gave a maximum value at the plasma power of 80W. Microhardness of the film is thought to be strongly affected by the content of adventitious oxygen in the film and it is concluded that the hardness of the film can be improved by increasing the plasma power.

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Effect of Vanadium Addition on the Cavitation Erosion Resistance of Fe-Cr-Ni-Si-C Hardfacing Alloy (Fe-Cr-Ni-Si-C계 경면처리 합금의 Cavitaon Erosion 저항성에 미치는 Vanadium 첨가의 영향)

  • 김경오;김준기;장세기;김선진;강성군
    • Journal of the Korean institute of surface engineering
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    • v.31 no.5
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    • pp.297-303
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    • 1998
  • The influences of vanadium addition on the cavitation erosion resistance pf Fe-Cr-Ni-Si-C hardfacing alloy were investigated using a vibratory apparatus up to 30 hrs. It was shown that 1wt.%V additioned alloy improved the resistance to cavitation damage. However, further increase in V content up to 2wt.% reduced the cavitation erosion resistance. It was considered that the addition of V developed the cavitation erosion resistance by reducing the stacking fault energy of Fe-Cr-Ni-Si-C alloy. However, the further increase in V content seemed to reduce the cavitation erosion resistance by increasing the matrix/carbide interfacial area, which was the preferential sites of the cavitation damage.

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Effect of Subsurface Drip Pipes Spacing on the Yield of Lettuce, Irrigation Efficiency, and Soil Chemical Properties in Greenhouse Cultivation (지중 점적관수 호스 설치 간격이 상추 수량, 관수량 및 토양 화학성에 미치는 영향)

  • Park, Jin Myeon;Lim, Tae Jun;Lee, Seong Eun
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.683-689
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    • 2012
  • This research was carried out to investigate the effect of installation spacing of subsurface drip irrigation pipe on the mineral content, nutrient uptake, yield of lettuce, water requirement for irrigation, and soil chemical properties in greenhouse cultivation. Semi-forcing and retarding culture were implemented in this experiment, with four treatments containing overhead spray irrigation and three subsurface irrigation lateral spacing intervals of 30, 40, 50 cm at a depth of 30 cm from soil surface, respectively. Each mineral content of lettuce grown under subirrigation system did not show significant difference between treatments, however the uptake of nutrients was lower at 50 cm-distance. The yield was largest in 30 cm-subirrigation (SI), followed by 40 cm-SI, overhead spray, and 50 cm-treatment. Water requirement for irrigation was highest in overhead spray, and it was in reverse proportion to the distance of irrigation pipes. $NO_3$-N content in the soil, at a depth of 10 cm, showed a higher value in 50 cm-SI, followed by 40 cm-SI, overhead spray and 30 cm-SI. Exchangeable K content was highest in 50 cm-SI, Mg was highest in 40 cm-SI, and Ca was lowest in 30 cm-SI. In conclusion, the lettuce yield was not different between 30 and 40 cm-SI, but water requirement for irrigation was lower as the distance of irrigation pipes was further. And it seems to be needed more precise research on this theme, because crop yield and the dynamics of soil minerals in subsurface irrigation can vary with the depth and distance of irrigation pipes, dripper, water flow depending on the soil texture, and plant response to soil minerals.

Effect of Sintering Time and Composition on Cutting Characteristics of $SiC-Si_3N_4$ Ceramic Tool ($SiC-Si_3N_4$ 세라믹공구의 소결시간과 조성변화가 절삭특성에 미치는 영향)

  • 박준석;김경재;이성구;권원태;김영욱
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2001.04a
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    • pp.321-326
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    • 2001
  • In the present study, $Si_3N_4-SiC$ ceramic composites that contained up to 20 wt% of dispersed SiC particles were fabricated via hot-pressing with an oxynitride glass. The microstructure, the mechanical properties, and the cutting performance of resulting ceramic composites were investigated. By fixing the composition as $Si_3N_4-20$ wt% SiC, the effect of sintering time on the microstructure, the mechanical properties, and the cutting performance were also investigated. For machining of gray cast i개n, the tool life increases with increasing the amount of SiC content in the composites; The tool life also increased with increasing the sintering time. The tool life of the home-made cutting tools was very close to that of commercial $Si_3N_4$ cutting tool. The superior cutting performance of $Si_3N_4-SiC$ ceramic cutting tools suggests the possibility to be a new ceramic tool material.

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Properties of $SiC/MoSi_2$ Composites Prepared by Reaction Sintering Method (반응소결에 의한 $SiC/MoSi_2$ 복합체의 특성)

  • 한인섭;양준환;서동수
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.399-406
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    • 1994
  • The SiC/MoSi2 composite material was prepared by infiltration with the mixture of metal Si and MoSi2 into the preform of $\alpha$-SiC and graphite under the vacuum atmosphere of 10-1 torr. The mechanical properties, phases and microstructural characteristics have been investigated by employing an universal testing machine, scanning electron microscope and X-ray diffractometer. With the increase of MoSi2/Si mixing content, the quantity of the residual silicon phase was decreased and the hardness and fracture toughness of composite materials were increased. Also, as the infiltration temperature increased, a lot of fine-grained $\beta$-SiC phases, which were produced from the reaction of graphite and liquid silicon melt, were transformed to $\alpha$-SiC phases.

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Effect of Template Content on Microstructure and Flexural Strength of Porous Mullite-Bonded Silicon Carbide Ceramics (기공형성제 함량이 다공질 Mullite-Bonded SiC 세라믹스의 미세구조와 강도에 미치는 영향)

  • Choi, Young-Hoon;Kim, Young-Wook;Woo, Sang-Kuk;Han, In-Sub
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.509-514
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    • 2010
  • Porous mullite-bonded SiC (MBSC) ceramics were fabricated at temperatures ranging from 1400 to $1500^{\circ}C$ for 2 h using silicon carbide (SiC), alumina ($Al_2O_3$), strontium oxide (SrO), and poly (methyl methacrylate-coethylene glycol dimethacrylate) (PMMA) microbeads. The effect of template content on porosity, pore morphology, and flexural strength were investigated. The porosity increased with increasing the template content at the same sintering temperature. The flexural strength showed maximum after sintering at $1450^{\circ}C$/2 h for all specimens due to small pores and dense strut. By controlling the template content and sintering temperature, it was possible to produce porous MBSC ceramics with porosities ranging from 30% to 54%. A maximum flexural strength of ~51MPa was obtained at 30% porosity when no template were used and specimens sintered at $1450^{\circ}C$/2 h.

Effects of Processing Parameters on the Mechanical Properties of Aluminium Matrix Composites (알루미늄 기지 금속복합재료의 기계적 성질에 미치는 제조변수의 영향)

  • Kim, J.D.;Koh, S.W.;Kim, H.J.
    • Journal of Power System Engineering
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    • v.9 no.4
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    • pp.130-136
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    • 2005
  • The effects of additional Mg content, the size and volume fraction of reinforcement phase on the mechanical properties of ceramic particle reinforced aluminium matrix composites fabricated by pressureless metal infiltration process were investigated. The hardness of $SiC_p/AC8A$ composites increased gradually with an increase in the additive Mg content, while the bending strength of $SiC_p/AC8A$ composites increased with an increase in additive Mg content up to 5%. However, this decreased when the level of additive Mg content was greater than 5% due to the formation of coarse precipitates by excessive Mg reaction and an increase in the porosity level. The hardness and strength of the composites increased with decreasing the size of SiC particle. It was found that the composites with smaller particles enhanced the interfacial bonding than those with bigger particles from fractography of the composites. The hardness of $Al_2O_{3p}/AC8A$ composites increased gradually with an increase in the volume fraction, however, the bending strength of $Al_2O_{3p}/AC8A$ composites decreased when the volume fraction of alumina particle was greater than 40% owing to the high porosity level.

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Purification of Iron Oxides and Application to Magnetic Hard Ferrite

  • Kim, Jeong-Seog;Chou, Kyoung-Ho;Kim, Jai-Young
    • The Korean Journal of Ceramics
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    • v.2 no.3
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    • pp.125-130
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    • 1996
  • Hematite iron ore and waste iron oxide sludge containing about 3-5 wt% $SiO_2$ were purified by three types of method developed on the basis of the Bayer process which is known as the purification process of bauxite ore. The basic principle of the developed methods lies in the fact that the impurities contained in the iron oxides, such as $SiO_2$ and $Al_2O_3$ are soluble in the alkaline reagents. Reaction of the raw materials with KOH was done in pressure vessel, at atmospheric pressure, and by both of these two. By the pressure vessel method $SiO_2$ content was reduced to below 0.5 wt% in the waste iron oxide sludge, while, in iron ore, $SiO_2$ remained at 2-3 wt%. The atmospheric pressure reaction rendered the waste iron oxide sludge $SiO_2$ content below 0.5wt% when the reaction temperature increased to above 90$0^{\circ}C$. The combined method of two previous methods was the most effective process and rendered the refined iron oxide about 300-400ppm of $SiO_2$. Using some refined iron oxides, Ba-ferrite was produced and magnetic properties were measured. The highest quality of magnetic properties obtained in this study were Br=2.09 G, bHc=1.99 KOe, iHc=4.54 KOe, $(BH)_{max}$=1.06 MGOe. Effect of sintering condition and chemical composition will be discussed.

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Microstructure, Mechanical and Wear Properties of Hot-pressed $Si_3N_4-TiC$ Composites

  • Hyun Jin Kim;Soo Whon Lee;Tadachika Nakayama;Koichi Niihara
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.317-323
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    • 1999
  • Si3N4-TiC composites have been known as electrically conductive ceramics. $Si_3N_4-TiC$ composites with 2 wt% $Al_2O_3$ and 4 wt% $Y_2O_3$ were hot pressed in $N_2$ environment. The mechanical properties including hardness, fracture toughness, and flexural strength and tribological properties were investigated as a function of TiC content. $Si_3N_4-40$ vol% TiC composite was hot pressed at $1,750^{\circ}C$, $1,800^{\circ}C$, and $1,850^{\circ}C$ for 1, 3 and 5 hours in $N_2$ gas. Mechanical and tribolgical properties depended on microstructures, which were controlled by hte TiC content, hot press temperature, and hot press holding time. However, mechanical properties and tribological behaviors were degraded by the chemical reaction between TiC and N. The chemically reacted products such as TiCN, SiC, and $SiO_2$ were detered by the X-ray diffraction analysis.

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Influence of Si Contents on the Mechanical Properties of Austempered Ductile Iron (오스템퍼드 구상흑연주철의 기계적 성질에 미치는 Si의 영향)

  • Lee, Sang-In;Oh, Young-Kun;Jun, Ghi-Chan
    • Journal of Korea Foundry Society
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    • v.17 no.3
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    • pp.286-291
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    • 1997
  • Influence of Si contents on the mechanical properties and microstructure of austempered ductile iron was investigated. Four different Si contents between 2.0 and 2.9% were used. Austenitizing was performed at $890^{\circ}C$ for 2 hrs and austempering temperatures were both 340 and $380^{\circ}C$ for 0.5, 1, and 2 hrs. Nodule content was more than $300/mm^2$ and nodularity was more than 90%. Microstructure was revealed using nital and retained austenite was measured by x-ray diffractometer. Tensile test, no-notch Charpy impact test and wear test were performed. Tensile strength was improved as Si content increased and both elongation and impact toughness had peak at 2.6%Si. The specimen austempered at $380^{\circ}C$ showed lower tensile strength than that of $340^{\circ}C$, but showed higher elongation. However, austempering temperature of $380^{\circ}C$ was desirable because that of $340^{\circ}C$ was close to lower bainite transformation. As austempering time increased, tensile strength and elongation were improved and optimum condition was obtained for 2 hrs heat treatment.

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