• 한국분말재료학회지
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• 제21권3호
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• pp.196-201
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• 2014

In this study, nanocrystalline Cu-Ni bulk materials with various compositions were cold compacted by a shock compaction method using a single-stage gas gun system. Since the oxide layers on powder surface disturbs bonding between powder particles during the shock compaction process, each nanopowder was hydrogen-reduced to remove the oxide layers. X-ray peak analysis shows that hydrogen reduction successfully removed the oxide layers from the nano powders. For the shock compaction process, mixed powder samples with various compositions were prepared using a roller mixer. After the shock compaction process, the density of specimens increased up to 95% of the relative density. Longitudinal cross-sections of the shock compacted specimen demonstrates that a boundary between two powders are clearly distinguished and agglomerated powder particles remained in the compacted bulk. Internal crack tended to decrease with an increase in volumetric ratio of nano Cu powders in compacted bulk, showing that nano Cu powders has a higher coherency than nano Ni powders. On the other hand, hardness results are dominated by volume fraction of the nano Ni powder. The crystalline size of the shock compacted bulk materials was greatly reduced from the initial powder crystalline size since the shock wave severely deformed the powders.

• 소성∙가공
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• 제26권4호
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• pp.216-221
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• 2017

Recently, interest in multifunctional energetic structural materials (MESMs) has grown due to their multifunctional potential, especially in military applications. However, there are few studies about extrinsic factors that govern the reactivity of MESMs. In this paper, a shock compaction process was performed on the nano Ni/Al-mixed powder to investigate the effect of particle size on the shock reaction condition. Additionally, heating the statically compacted specimen was also performed to compare the mechanical properties and microstructure between reacted and unreacted material. The results show that the agglomerated structure of nanopowders interrupts the reaction by reducing the elemental boundary. X-ray diffraction analysis shows that the NiAl and $Ni_3Al$ intermetallics are formed on the reacted specimen. The microhardness results show that the $Ni_3Al$ phase has a higher hardness than NiAl, but the portion of $Ni_3Al$ in the reacted specimen is minor. In conclusion, using Ni/Al composites as a reactive material should focus on energetic use.