• Journal of The Korean Society of Agricultural Engineers
• /
• v.46 no.3
• /
• pp.93-105
• /
• 2004

The Shihwa wetland, a newly developed constructed wetland prototype in Korea with an area of approximately 104 ha, was established to improve the water quality severely polluted inflow streams into Lake Shihwa. Because this wetland could play a role as an ecological park in addition to improving the water quality, an ecological impact of the Shihwa constructed wetland has been a national concern. This paper focused on reporting the survey results for fauna among the entire investigation results for 3 years. A total of 129 terrestrial insect species have been observed from August 2001 to June 2002. Among them, Ischnura asiatica (Brauer) (order Odonata), Scymnus species (order Coleoptera) and Orthopteran species were frequently found in the reed bushes. A total of 77 bird species were recorded in a seasonal count, the maximum number of species was 34 in winter and the maximum number of individuals was 4,599 in summer. For the freshwater fish, only 4 species were found in 2000, however in 2001 and 2002, 12 species and 459 individuals were collected at four survey points. Among these 12 species, the dominant species were Mugil cephalus(36%), followed by Carassius auratus (25%) and Rhinogobius brunneus (22%). Meanwhile,12 individuals of Oryzias latipes were observed nearby, mostly downstream of the wetland. For the Herpetofauna at four survey areas, 3 species of amphibians and 3 species of reptiles were recorded. Because of remaining salinity in the soil of the Shiwha constructed wetland, Herpetofauna inflow to the wetland was scanty and mainly inhabited the upstream area. A total of 8 mammal species were recorded. Small-sized species were the striped field mouse, the Ussurian harvest-mouse, the Manchurian reed vole and the brown rat. Middle- and large-sized species were Korean water-deer, Korean raccoon dogs, Korean yellow weasels and feral cats.

• Journal of the Korean earth science society
• /
• v.21 no.5
• /
• pp.541-552
• /
• 2000

The variations of physical properties due to inflow of seawater by sluice gates operation were observed in Shihwa Lake. The distributions of salinity and temperature were investigated at 11 stations during February, 1997 to July, 1998. The salinity of water mass in Shihwa Lake before gate operation was ranged below 15psu and strong stratification due to inflow of seawater was observed at the depth of 11 m. In July 1997, temperature difference of 10^{\circ}C$ was occurred between the surface and bottom water due to strong solar radiation. During October 1997 to February 1998, inversion of temperature distribution, which the temperature of bottom water was higher than that of surface water, was observed. In July 1997, temperature, salinity, current speed and current direction were investigated by RCM-7 at St.3 for 56 days. When sea water was intruded in Shihwa Lake, the symmetric distribution of temperature and salinity was observed and it seems to be resulted from inflow of seawater with low temperature and high salinity. After January 1998, salinity of Shihwa Lake was increased over 30psu due to continuous gate operation and the stratification was weakened.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.2 no.2
• /
• pp.101-109
• /
• 1997

The present study was carried out to investigate the temporal and spatial changes in species composition and abundance of polychaetes in Lake Shihwa. Macrobenthic fauna were collected from eight sampling surveys performed in March, June, September and December of 1994, March and October of 1995, February and August of 1996, using a modified van Veen grab with 0.1 $m^2$ coverage area. Polychaete worms, the most abundant macrofaunal group, comprised of 1~22 species at each investigation; number of species continuously decreased during the survey period. The mean density of polychaete was $794{\pm}1,275\;indiv.{\cdot}m^{-2}$ and showed a large fluctuation over time. The variation in abundance was mainly coupled with the domination of Polydora ligni occupying 83% in total density. The next dominant species were Pseudopolydora kempi (mean density of 31 $indiv.{\cdot}m^{-2}$) and Capitella capitata (mean density of 23 $indiv.{\cdot}m^{-2}$). Abundant polychaetes in Lake Shihwa are known to be tolerant to sediment pollution. Ecological indices such as diversity (H') and dominance (D) also indicated that the number of species significantly decreased and a few species predominated in Lake Shihwa after the dike construction. The azoic zone were extended from the upper reach of Lake Shihwa to the vicinity of the dike over time. The reduced number of species, predominance of pollution indicator species and development of an azoic zone reflect severe deterioration of benthic environments in Lake Shihwa.

• Proceedings of KOSOMES biannual meeting
• /
• 2017.11a
• /
• pp.244-244
• /
• 2017

• Ocean Science Journal
• /
• v.42 no.4
• /
• pp.223-230
• /
• 2007

To understand the origin and biogeochemistry of the organic matter in surface sediments of Lake Shihwa and Lake Hwaong, organic nitrogen, inorganic nitrogen, labile organic carbon, and residual organic carbon contents as well as stable isotope ratios for carbon and nitrogen were determined by KOBr-KOH treatment. Ratios of organic carbon to organic nitrogen $(C_{org}/N_{org})$ (mean = 24) were much higher than ratios of organic carbon to total nitrogen $(C_{org}/N_{tot})$ (mean= 12), indicating the presence of significant amounts of inorganic nitrogen in the surface sediments of both lakes. Stable isotope ratios for organic nitrogen were, on average, $5.2\%_{\circ}$ heavier than ratios of inorganic nitrogen in Lake Shihwa, but those same ratios were comparable in Lake Hwaong. This might be due to differences in the origin or the degree of degradation of sedimentary organic matter between the two lakes. In addition, stable isotope ratios for labile organic carbon were, on average, $1.4\%_{\circ}$ heavier than those for residual organic carbon, reflecting the preferential oxidation of $^{13}C$-enriched organic matter. The present study demonstrates that KOBr-KOH treatment of sedimentary organic matter can provide valuable information for understanding the origin and degradation state of organic matter in marine and brackish sediments. This also suggests that the ratio of $(C_{org}/N_{org})$ and stable isotope ratios for organic nitrogen can be used as indexes of the degree of degradation of organic matter.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.2 no.2
• /
• pp.87-91
• /
• 1997

Ecological stability of the Lake Shihwa, artificially made by the construction of the Shihwa Dike, was evaluated by the species composition and variation in biomass of zooplankton. Species composition and seasonal variation in biomass in the seaside stations were similar to those observed in nearby bays and coastal zone. However, those in the lake sites showed very different patterns. The brackish water copepod, Sinocaianus tenellus, held the first rank in every season (with more than 66% in spring, 98% in summer and fall, and 80% in winter). The species composition was very simple and the biomass (in terms of total individuals $m^{-3}$) varied markedly with season up to the order of $10^4$ magnitude. These results imply that the lake ecosystem made by the construction of Sihwa dike is in very unstable stage probably due to the input of industrial wastes as well as unpredictable variation in salt content caused by irregular control of the watergate of the dike and resultant irregular flow direction of the water through the gate.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.2 no.2
• /
• pp.49-52
• /
• 1997

The man-made lake, Shihwa, was constructed in January, 1994 as a part of the 'development project of the Shihwa area'. The lake area was a typical coastal ocean environment before the construction, but after constructing the dikes to block the sea water inflow, the lake is in the process of becoming a freshwater lake, and faces various ecological changes. Due to the polluted water inflow from the neighboring industrial complex and Ansan city, many negative effects appear. In this group study we conducted integrated ecosystem investigations of the lake Shihwa and the adjacent coastal area in order to find out how the ecosystem is controlled by artificial changes of the lake environment. The results are compiled in the following several articles of this issue: Park et ai. (1997), Han et al. (1997). Choi et ai. (1997), Park and Huh (1997), Ryu et at. (1997), Lee et al. (1997).

• Ocean and Polar Research
• /
• v.25 no.4
• /
• pp.447-457
• /
• 2003

In order to understand the distribution of changes of geochemical characteristics in surface sediments according to various environmental changes around the artificial Lake Shihwa, surface sediments were sampled at $13{\sim}15$ sites form 1997 to 1999 and analyzed by C/S analyzer, ICP/MS and AAS. The average $S/C_{org}$ ratio was 0.35 in the surface sediments, which is similar to 0.36, the characteristic ratio of marine sediments. Heavy metal contents and enrichment factors in the surface sediments tended to be decreasing from the head to the mouth of the Lake Shihwa. With the deposition of fine-grained sediments in the central part of lake, anoxic water column induced the sulfides compounds with Cu, Cd and Zn. Metals such as Al, Fe, Cr, Co, Ni, Cu, Zn and Cd except for Mn and Pb showed relatively high correlation coefficients among them. The contents of Cr, Co, Ni, Cu, Zn and Cd in the surface sediments of the lake were two to five times higher than those in the lake before dike construction and also in outer part of the dike. These are mainly due to the Input of untreated industrial and municipal waste-waters into the lake, and the accumulation of heavy metals by limitation of physical mixing. Although metal contents of the surface sediments at the sites near the water-gate due to outer seawater inflow tended to be lower than those during the desalination, heavy metals were deposited in areas around the new industrial complex in the evidence of spatial distribution of heavy metals in the sediments. This is mainly due to the input of untreated waste-waters from tributaries.

• Ocean and Polar Research
• /
• v.25 no.4
• /
• pp.459-468
• /
• 2003

Annual variation of water qualities in the Shihwa Lake were observed 18 times from June 1996 to October 2001. We studied at the station of the upper streams and near the water gate of lake. After the flow of the outer seawater through the water gate, the surface salinity in Shihwa Lake increased to the range of 25-30 psu in both stations after October 1998. Due to the declination of the salinity differences between the surface and the bottom water, the pycnocline in which had existed until 1997 has weakened, and made the water column mix vertically. This led to the improvement of anoxic/hypoxic environment at bottom waters after April 1998. However, despite the continuous flow of the outer seawater, the concentrations of chlorophyll-a at surface layer were varied from $2{\mu}g/l\;to\;60{\mu}g/l$, and these values indicated the eutrophication. The following organic matter load was greatly influencing the surface layer's COD concentration. During the rainy season, the salinity at the surface layer to the below 15 psu resulting in stratification between the surface and bottom layer. Organic matters that were provided from the surface layer to the bottom layer due to active primary production in the year exhausted dissolved oxygen at the bottom layer, and the bulks of organic matters at bottom gave rise to hypoxic or anoxic environment. It was observed that the enrichment of ammonia and phosphate were main factors to worsen the water quality of the Shihwa Lake. The results of examining the annual variations in Shiwha Lake through principal component analysis shown that water characteristics in the rainy season were similar with those before input of outer sea water.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.7
• /
• pp.2213-2218
• /
• 2012

Efficient synthetic routes were developed to prepare a sizable amount (4-15 grams) of the chiral epoxides 4-6 as versatile intermediates for the synthesis of aspartyl protease inhibitors of therapeutic interest such as HIV protease and ${\beta}$-secretase. Oxidative cleavage of the C(2)-C(3) double bond of L-ascorbic acid followed by functional group manipulation led to the preparation of the epoxide 10, which was opened with an azide to yield a common aziridine intermediate 12. Through opening of the aziridine ring of 12 with either a carbon or a sulfur nucleophile, chiral epoxide precursors 4-6 could be prepared for various HIV protease inhibitors. Except for the final low melting epoxides 5 and 6, all intermediates were obtained as crystalline solids, thus the synthetic pathway can be easily applied to a large-scale synthesis of the chiral epoxides.