• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.49 no.2
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• pp.106-115
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• 2013

A series of fishing experiments were carried out in the western coastal waters of Korea from May, 2006 to September, 2007, using gill nets of different mesh sizes (m=101, 121.8, 152.5, 176.8, and 191 mm) to determine the mesh selectivity of gill net for swimming crab, Potunus trituberculatus. The catch species was composed of swimming crab (87%), Thomas's rapa whelk Rapana venosa (5%), arthritic neptune Neptunea cumingi (2%), Japanese swimming crab Charybdis japonica (2%), marbled sole Pleuronectes yokohamae (1%), pen shell Atrina pectinata, ocellate spot skate Okamejei kenojei, and so on. The carapace length (CL) of each swimming crab caught in the experimental nets was measured. Sponge crab (egg-bearing female crab) was appeared from the end of June to August in the coastal waters. The master selection curve was estimated by applying the extended Kitahara's method. The selection curve showed that the gill nets of larger mesh size allowed more crabs of small carapace size to escape. The optimum value (CL/m) was 0.645 and the CL/m was estimated to be 0.301, 0.354, 0.391, 0.422, and 0.450 when the retention probabilities were 0.1, 0.2, 0.3, 0.4 and 0.5, respectively.

• Polymer(Korea)
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• v.33 no.4
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• pp.353-357
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• 2009

Spray drying is an effective and stable process, which has been widely used to produce pharmaceutical powders. In the traditional spray drying process, it was not quite easy to control the aggregation and the size of particles. Particularly, the preparation of polymeric particles was relatively hard compared to the preparation of food and pharmaceutical ingredients, typically organic materials of small molecular weights. In this study, modification of a conventional spray dryer was tried to use electrical charge and co-axial nozzles to prepare polymeric particles. Poly(ethylene glycol) and poly (D,L-lactide-co-glycolide) were used as the inner polymeric materials, and lactose as the outer shell materials. The results showed that electrohydrodynamic spray-dried particles had a relatively uniform size and particle morphology, and the aggregation of particles could be suppressed compared to the conventional spray-dried particles. The electrohydrodynamic spray-dried powders consisted of spherical particles of $2{\sim}5{\mu}m$ diameters.

• Journal of Pharmaceutical Investigation
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• v.38 no.2
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• pp.99-104
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• 2008

PLGA micro/nano particles encapsulating ranitidine as a hydrophilic model drug were prepared by the double-emulsion solvent evaporation method. Surface morphology investigation by scanning electron microscope (SEM) showed that the emulsification by sonication could produce nanoparticles, whereas microparticles were prepared using high speed homogenizer. Moreover, while nanohalf-shell structure instead of spherical nanoparticle could be produced by adding poloxamer into oil phase (MC) with PLGA 504H, the addition of poloxamer didn't change particle shape in case of PLGA 502H. On the other hand, microparticle with poloxamer had more surface pores than those without poloxamer. The size and polydispersity (PDI) of particles were determined by particle size analyzer. Effective diameters of particles were in the range of $400{\sim}800\;nm$ and $1200{\sim}3300\;nm$ in case of nanoparticles and microparticles, respectively. Encapsulation efficiencies were in the range of $1.2{\sim}2.9%$. The addition of poloxamer produced the particles with higher encapsulation efficiency. In vitro release study in phosphate buffer (pH 7.4) at $37^{\circ}C$ showed common large initial burst release. However, the relative slower release profile could be observed in case of microparticles. Poloxamer addition increased the release rate, which was thought to be related to the increased surface area of particles.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.304-304
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• 2010

The study on the catalytic oxidation of carbon monoxide (CO) to carbon dioxide ($CO_2$) using the noble metals has long been the interest subject and the recent progress in nanoscience provides the opportunity to develop new model systems of catalysts in this field. Of the noble metal catalysts, we selected ruthenium (Ru) as metal catalyst due to its unusual catalytic behavior. The size of colloid Ru NPs was controlled by the concentration of Ru precursor and the final reduction temperatures. For catalytic activity of CO oxidation, it was found that the trend is dependent on the size of Ru NPs. In order to explain this trend, the surface oxide layer surrounding the metal core has been suggested as the catalytically active species through several studies. In this poster, we show the influence of surface oxide on Ru NPs on the catalytic activity of CO oxidation using chemical treatments including oxidation, reduction and UV-Ozone surface treatment. The changes occurring to UV-Ozone surface treatment will be characterized with XPS and SEM. The catalytic activity before and after the chemical modification were measured. We discuss the trend of catalytic activity in light of the formation of core-shell type oxide on nanoparticles surfaces.

• Advances in nano research
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• v.4 no.1
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• pp.1-14
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• 2016

Superparamagnetic iron oxide nanoparticles (Nps), composed of magnetite, $Fe_3O_4$, or maghemite, ${\gamma}-Fe_2O_3$, core and biocompatible polymer shell, such as dextran or chitozan, have recently found wide applications in magnetic resonance imaging, contrast enhancement and hyperthermia therapy. For different diagnostic and therapeutic applications, current attempt is focusing on the synthesis and biomedical applications of various ferrite Nps, such as $CoFe_2O_4$ and $MnFe_2O_4$, differing from iron oxide Nps in charge, surface chemistry and magnetic properties. This study is focused on the synthesis of manganese ferrite, $MnFe_2O_4$, Nps by most commonly used chemical way pursuing better control of their size, purity and magnetic properties. Co-precipitation syntheses were performed using aqueous alkaline solutions of Mn(II) and Fe(III) salts and NaOH within a wide pH range using various hydrothermal treatment regimes. Different additives, such as citric acid, cysteine, glicine, polyetylene glycol, triethanolamine, chitosan, etc., were tested on purpose to obtain good yield of pure phase and monodispersed Nps with average size of ${\leq}20nm$. Transmission electron microscopy (TEM), X-ray diffraction, energy dispersive X-ray spectroscopy (EDX), $M\ddot{o}ssbauer$ spectroscopy down to cryogenic temperatures, magnetic measurements and inductively coupled plasma mass spectrometry were employed in this study.

• The Bulletin of The Korean Astronomical Society
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• v.46 no.1
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• pp.55.2-56
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• 2021

The progenitor of Type Ia supernovae (SNe Ia) is mainly believed to be a close binary system of acarbon-oxygen white dwarf (CO WD) and non-degenerate companion (single degenerate) or another WD (double degenerate). However, it is unclear which system is more prevalent. Here, we present a high cadence optical/Near-IR light curve of normal but slightly faint type Ia SN 2019ein from IMSNG project. We fit the early light curve (t <+8.3 days from the first detection) with various models to find the shock-heated cooling emission from SN ejecta-companion interaction. No significant shock-heated cooling emission is found, from which we constrain the progenitor star size as the following. The upper limit (R_upper,*) of the companion size in R-band is ~0.2R_⊙ when forcing the first light time (t_fl) to have one value and ~0.9R_⊙ when using the mean value of tfl from the fitting in each band. Assuming the source of the I-band curve is almost powered from the radioactive decay, we obtained R_upper,*~1.2R_⊙. The early B-V color curve is in agreement with the model color curve of the 2M_⊙ main sequence companion. These results allow us to at least rule out large stars like red giants as a companion star of the binary progenitor system of this supernova. B-R and V-R color do not show any significant signs of a red bump, which shows a thin helium shell (MHe<0.1M_⊙) for the sub-Mch WD (double detonation model). In addition, we estimated the distance to NGC 5353 as 37.098±0.028Mpc.

• Advances in nano research
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• v.15 no.1
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• pp.35-48
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• 2023

Nanoparticles are known for their outstanding properties such as particle size, surface area, optical and electrical properties. These properties have significantly boasted their applications in various surface phenomena. In this work, calcium oxide nanoparticles were synthesized from periwinkle shells as an approach towards waste management through resource recovery. The sol gel method was used for the synthesis. The nanoparticles were characterized using X-Ray diffractometer (XRD), Fourier Transformed Infra-Red Spectrophotometer (FTIR), Brunauer Emmett Teller (BET), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and ultra violet visible spectrophotometer (UV-visible). While DLS and SEM underestimate the particle diameter, the BET analysis reveals surface area of 138.998 m²/g, pore volume = 0.167 m³/g and pore diameter of 2.47 nm. The nanoparticles were also employed as an adsorbent for the purification of dye (methyl orange) contaminated water. The adsorbent showed excellent removal efficiency (up to 97 %) for the dye through the mechanism of physical adsorption. The adsorption of the dye fitted the Langmuir and Temkin models. Analysis of FTIR spectrum after adsorption complemented with computational chemistry modelling to reveal the imine nitrogen group as the site for the adsorption of the dye unto the nanomaterials. The synthesized nanomaterials have an average particle size of 24 nm, showed a unique XRD peak and is thermally and mechanically stable within the investigated temperature range (30 to 70 ℃).

• Journal of the Society of Naval Architects of Korea
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• v.49 no.4
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• pp.304-311
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• 2012

One of the main features of Drillship or FPSO is a moonpool structure. The moonpool structures have various accuracy tolerances according to their functions and targets. This study is mainly interested in roundness of a circular moonpool structure in FPSO. Because this structure needs abrasion-resistance at which bearing of machine touches on inner wall of moonpool, we should do over-lay welding widely and deeply by using Inconel weld material. But a general over-lay can cause a severe distortion at ship block structure. If we can analyze the roundness by thermal distortion under Inconel over-lay, we can establish a special erection policy by the results. In this study, we designed stress-strain curve for strain-boundary condition analysis by an elasto-plastic material property. The results made us to decide an appropriate ship-block size and policy of crane manipulation will follow for its capacity. If a structure that needs over-lay is not large, solid elements also are not a bad choice for FEM modeling. Therefore we also developed a standard of using strain-boundary method that shell elements are used as over-lay on solid element modeling.

• Structural Engineering and Mechanics
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• v.2 no.4
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• pp.359-367
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• 1994

The stability behaviour of symmetrically laminated rectangular composite plates with loaded ends clamped and unloaded edges simply-supported, and subjected to uniform in-plane compression is investigated. A numerical and experimental investigation is presented in this contribution. The stacking sequence of the laminated glass/epoxy composite plates is symmetric about the middle surface and consists of 8-ply [0, 90, +45, -45]s lamination. Numerical predictions were obtained through the use of the finite element method. The above plates were modelled with 8-noded isoparametric layered shell elements. The effect of the input parameters such as the degree and forms of prescribed initial imperfection and the incremental step size required for incremental loading, on the convergence of the solution is thoroughly examined. Experimental results are presented for 10 test panels. All test panels were made from glass/epoxy unidirectional prepregs and have aspect ratio of 5.088. The laminate thicknesses were found to vary from 1.054 mm to 1.066 mm. Comparison of experimental data with predicted results show good correlation and give confidence in the finite element model.

• Bulletin of the Korean Chemical Society
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• v.29 no.8
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• pp.1539-1544
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• 2008

A polymeric micelle, based on the poly(benzyl-L-histidine)-b-poly(ethylene glycol) (polyBz-His-b-PEG) diblock copolymer, was designed as a tumor-specific targeting carrier. The micelles (particle size: 67-80 nm, critical micelle concentration (CMC); 2-3 $\mu$g/mL) were formed from the diafilteration method at pH 7.4, as a result of self-assembly of the polyBz-His block at the core and PEG block on the shell. Removing benzyl (Bz) group from polyBz-His block provided pH-sensitivity of the micellar core; the micelles were physically destabilized in the pH range of pH 7.4-5.5, depending on the content of the His group free from Bz group. The ionization of His group at a slightly acidic pH promoted the deformation of the interior core. These pHdependent physical changes of the micelles provide the mechanism for pH-triggering anticancer drug (e.g., doxorubicin: DOX) release from the micelle in response to the tumor’s extracellular pH range (pH 7.2-6.5).