• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.707-710
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• 2005

This experimental study investigate temperature dependency affecting setting and strength development of concrete using mineral admixtures such as CKD, FA and BS. For the properties of setting at $5^{\circ}C$, setting time of concrete with mineral admixture was delayed about $3\~14$ hour compared with that of plain concrete. Use of CKD had a desirable effect on reducing setting retard under $5^{\circ}C$ because of $CaCO_3$ of CKD while use of FA and BS retarded setting time greatly. For compressive strength under $5^{\circ}C$, concrete with CKD had the most compressive strength in early age compared with the other mineral admixtures but exhibited slight strength loss in $-5^{\circ}C$ at 28days. Especially, concrete with FA and BS was observed in early stage at low curing temperature because of strength loss remarkably in $-5^{\circ}C$.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2008.11a
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• pp.37-41
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• 2008

According to the recent rapidly increasing that construction works are gradually Manhattanized mainly the grand scaled residential buildings, the foundation of the building that is related to safety is increasing for building as a grand scaled mat concrete. Because mat concrete can not be simultaneously placing of concrete in a great quantity due to the circumstance at the field, the inequal deformation of the tensile stress that according to the time lag of hydration heat between the upper layer and the lower layer is affecting as a cause that is the possibility of crack occurrence by increasing. Accordingly, this research checked the efficiency of super retard concrete in applying real structures, and we implemented the preparatory experiment to settle up the inequal deformation of the tensile stress substantially that is according to the time lag of placement between the upper layer and the lower layer by controlling the setting time using the super retarding agent. As the result of test, the more target of delay time lengthened, the more fluidity increased and air content indicated a little differences. There was from 2 to 10 hours between the standard curing and the outside curing at the setting time and in case of calculating the rate of mixing at real structure is required that mix promotion, increasing the amount of mixing, by setting up the curing temperature. The super retard concrete showed the result that in compressive strength, early-age strength was smaller than normal concrete whereas it was same or more figures from at the aging 28days because of the super retarding agent.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.245-250
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• 2001

Ultrasonic pulse velocity(UPV) is a useful tool for examining the property of early-age mortar or concrete. Thus, UPV has been used for a long time to characterize setting and hardening of cementitious materials. In this study, in order to investigate the characteristics of setting for mortar, UPV was measured using automatic monitoring system up to 3 days after casting. Test results show that UPV of high water to binder ratio(w/b) mortar remained constant at the beginning of hydration and then abruptly began to increase. However, UPV of low w/b mortar gradually increase due to setting retard caused by use of superplasticizer. Furthermore, the development of UPV for mortar with fly ash is slower than that of mortar without fly ash. It was concluded that the property change of mortar or concrete, such as setting and hardening can be assessed by monitoring of UPV.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.85-88
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• 2005

This study investigates influence on concrete adding beverage or detergent, by work man's mistakes during concrete placement in field. Overall, concrete adding beverage or detergent does not affect slump and air content, compared with control concrete. However concrete adding detergent resulted in significantly higher air content, due to inter facial activation ingredient. For the properties of setting time, concrete adding lactic acid beverage indicated the longest retarding properties, next was coffee and soft drink in order. Compressive strength of concrete, which retarded setting time. exhibited slightly improved value at 7 and 28 days respectively, while that of concrete adding detergent significantly decreased, due to higher air content.

• Restorative Dentistry and Endodontics
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• v.10 no.1
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• pp.71-83
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• 1984

The purpose of this study was to evaluate the transmission spectrum of the set calcium hydroxide dental cement (Dycal, L.D. Caulk Co. Milford, Del.) Cement was prepared for A T R spectra at a low powder-to-liquid ratio of 3.0gm/ml in order to retard the reaction and facilitate the manipulation of loading the cement into the cell. Spectra were recorded on an I R Spectrophotometer (MX-1, FT) at an agle of incidence of 55. The A T R cell was a RIIc Model TR5 with a hemisperical KRS-5 (Thallium-Bromide-Iodide). A spectrum was recorded within 3 minutes. Further spectra were recorded after 5,10,30 minutes and 1,5,24, 72 hours. The results were as follows; 1. The setting reaction between acid paste and base past would take place fastly within 10 minutes after mix, and that would be slow until 72 hours after mix. 2. In the set cements, some methyl salicylate and calcium hydroxide remained unreacted until 72 hours after mix. 3. The setting reaction and the reaction rate occuring at the surface and in the bulk cements were similar. 4. The chelates were bound together between calcium hydroxide and methyl salicylate.

• Journal of the Korea Concrete Institute
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• v.18 no.6 s.96
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• pp.759-767
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• 2006

This paper presents a method to estimate the setting time of concrete using super retarding agent(SRA) and fly ash(FA) under various curing temperature conditions by applying maturity based on equivalent age. To estimate setting time, the equivalent age using apparent activation energy($E_a$) was applied. Increasing SRA content and decreasing curing temperature leads to retard initial and final set markedly. $E_a$ at the initial set and final set obtained by Arrhenius function showed differences in response to mixture type. It is estimated to be from $24{\sim}35KJ/mol$ in all mixtures, which is smaller than that of conventional mixture ranging from $30{\sim}50KJ/mol$. Based on the application of $E_a$ to Freisleben-Hansen and Pederson's equivalent age function, equivalent age is nearly constant, regardless of curing temperature and SRA contents. This implies that the concept of maturity is applicable in estimating the setting time of concrete containing SRA. A high correlation between estimated setting time and measured setting time is observed. Multi-regression model to determine appropriate dosage of SRA reflecting FA contents and equivalent age was provided. Thus, the setting time estimation method studied herein can be applicable to the concrete containing SRA and FA in construction fields.

• Restorative Dentistry and Endodontics
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• v.37 no.4
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• pp.188-193
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• 2012

Mineral trioxide aggregate (MTA) was developed in early 1990s and has been successfully used for root perforation repair, root end filling, and one-visit apexification. MTA is composed mainly of tricalcium silicate and dicalcium silicate. When MTA is hydrated, calcium silicate hydrate (CSH) and calcium hydroxide is formed. Formed calcium hydroxide interacts with the phosphate ion in body fluid and form amorphous calcium phosphate (ACP) which finally transforms into calcium deficient hydroxyapatite (CDHA). These mineral precipitate were reported to form the MTA-dentin interfacial layer which enhances the sealing ability of MTA. Clinically, the use of zinc oxide euginol (ZOE) based materials may retard the setting of MTA. Also, the use of acids or contact with excessive blood should be avoided before complete set of MTA, because these conditions could adversely affect the hydration reaction of MTA. Further studies on the chemical nature of MTA hydration reaction are needed.

• Journal of the Korea Concrete Institute
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• v.17 no.1 s.85
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• pp.105-112
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• 2005

Stabilizing and rousing sludge water generated from washing truck mixer and batcher plant can resolve inconsistency in quality and improve strength, therefore it is essential to review how to utilize it. This research conducted experiments and studied on solids of sludge water to find out the types of stabilizing agents available in conditions of producing ready mixed concretes in Korea. The result showed that oxy carboxylic acid retarder dedicated for stabilizing sludge water was most effective in decreasing solid. However, the setting time of cement paste was retarded due to surplus reactants, but it did not impede application of ready mixed concretes. When we left the sludge water mixed with stabilizing agent, it has been noted that initial retard effect recovered to the level using just service water in 7${\~}$8 days and that it is effective to use stabilized sludge water in 2${\~}$3 days. On the other hand, saccharic type super retarding agent was also outstanding in applicability by showing similar effect. The sludge water stabilizing agents currently marketed depend on imports, therefore it is necessary to locally manufacture usable stabilizing agents and to review its usability with multi-dimensional view.

• Journal of the Korean Ceramic Society
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• v.44 no.9
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• pp.471-476
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• 2007

The hydration mechanism of the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system in the presence of alkali sulfates has been investigated. The early hydration rate of $3CaO{\cdot}Al_2O_3$ was accelerated by the addition of $Na_2SO_4$ and $K_2SO_4$. This is closely related to the formation of syngenite $(CaSO_4{\cdot}K_2SO_4{\cdot}H_2O)$, and the U-phase added $K_2SO_4$ and $Na_SO_4$ in the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, respectively. The formation of the rigid syngenite and U-phase structure led to rapid setting and decreases the sulfate content in the liquid phase of the hydrating cement to the extent that it cannot adequately retard the hydration of $3CaO{\cdot}Al_2O_3$. In case of the alkali sulfate not added to the $3CaO{\cdot}Al_2O_3-CaSO_4{\cdot}2H_2O$ system, the ettringite was transformed to monosulfoaluminate immediately after the consumption of gypsum. However, when the alkali sulfates were added to this system, the ettringite did not transform to monosulfoaluminate immediately even though the gypsum was completely consumed. There was a stagnation period to transform to the monosufoaluminate after the consumption of gypsum because the syngenite and U-phase remained as the sulfate source.